LinearCombinationPostprocessor

Description

This post-processor computes a linear combination between an arbitrary number of post-processors $var element = document.getElementById("moose-equation-206bb4d0-deb5-4c8c-8162-b3e8eb649ab4");katex.render("x_i", element, {displayMode:false,throwOnError:false,macros:{"\\pf":"\\frac{\\partial #1}{\\partial #2}"}});$ : $var element = document.getElementById("moose-equation-ee6376c8-fa46-42ca-b0ae-76ef2481b183");katex.render(" y = \\sum\\limits_i c_i x_i + b \\,,", element, {displayMode:true,throwOnError:false,macros:{"\\pf":"\\frac{\\partial #1}{\\partial #2}"}});$ where $var element = document.getElementById("moose-equation-705b91f8-aead-4740-9eb4-62c6438e8dd7");katex.render("c_i", element, {displayMode:false,throwOnError:false,macros:{"\\pf":"\\frac{\\partial #1}{\\partial #2}"}});$ is the combination coefficient for $var element = document.getElementById("moose-equation-d7bf6261-d6fd-48b4-a67b-f7f00df5ab3c");katex.render("x_i", element, {displayMode:false,throwOnError:false,macros:{"\\pf":"\\frac{\\partial #1}{\\partial #2}"}});$ , and $var element = document.getElementById("moose-equation-c866916b-7c19-40da-ad85-7c0df5fd22be");katex.render("b", element, {displayMode:false,throwOnError:false,macros:{"\\pf":"\\frac{\\partial #1}{\\partial #2}"}});$ is an additional value to add to the sum.

Example Syntax

The following example demonstrates how this post-processor is used:

# Tests the LinearCombinationPostprocessor post-processor, which computes
# a linear combination of an arbitrary number of post-processor values.

[Mesh]
  type = GeneratedMesh
  dim = 1
  nx = 2
[]

[Problem]
  solve = false
[]

[Executioner]
  type = Steady
[]

[Postprocessors]
  [./pp1]
    # number of elements, equal to 2
    type = NumElems
  [../]
  [./pp2]
    # number of nodes, equal to 3
    type = NumNodes
  [../]

  # post-processor value being tested; value should be the following:
  #   value = c1 * pp1 + c2 * pp2 + b
  #         = 2  * 2   + -1 * 3   + 5 = 6
  [./linear_combination]
    type = LinearCombinationPostprocessor
    pp_names = 'pp1 pp2'
    pp_coefs = '2   -1'
    b = 5
  [../]
[]

[Outputs]
  show = linear_combination
  csv = true
[]

Input Parameters

pp_coefsList of linear combination coefficients for each post-processor
C++ Type:std::vector<double>
Options:
Description:List of linear combination coefficients for each post-processor
pp_namesList of post-processors
C++ Type:std::vector<PostprocessorName>
Options:
Description:List of post-processors

Required Parameters

b0Additional value to add to sum
Default:0
C++ Type:double
Options:
Description:Additional value to add to sum
execute_onTIMESTEP_ENDThe list of flag(s) indicating when this object should be executed, the available options include NONE, INITIAL, LINEAR, NONLINEAR, TIMESTEP_END, TIMESTEP_BEGIN, FINAL, CUSTOM.
Default:TIMESTEP_END
C++ Type:ExecFlagEnum
Options:NONE, INITIAL, LINEAR, NONLINEAR, TIMESTEP_END, TIMESTEP_BEGIN, FINAL, CUSTOM, TRANSFER
Description:The list of flag(s) indicating when this object should be executed, the available options include NONE, INITIAL, LINEAR, NONLINEAR, TIMESTEP_END, TIMESTEP_BEGIN, FINAL, CUSTOM.

Optional Parameters

allow_duplicate_execution_on_initialFalseIn the case where this UserObject is depended upon by an initial condition, allow it to be executed twice during the initial setup (once before the IC and again after mesh adaptivity (if applicable).
Default:False
C++ Type:bool
Options:
Description:In the case where this UserObject is depended upon by an initial condition, allow it to be executed twice during the initial setup (once before the IC and again after mesh adaptivity (if applicable).
control_tagsAdds user-defined labels for accessing object parameters via control logic.
C++ Type:std::vector<std::string>
Options:
Description:Adds user-defined labels for accessing object parameters via control logic.
enableTrueSet the enabled status of the MooseObject.
Default:True
C++ Type:bool
Options:
Description:Set the enabled status of the MooseObject.
force_preauxFalseForces the GeneralUserObject to be executed in PREAUX
Default:False
C++ Type:bool
Options:
Description:Forces the GeneralUserObject to be executed in PREAUX
force_preicFalseForces the GeneralUserObject to be executed in PREIC during initial setup
Default:False
C++ Type:bool
Options:
Description:Forces the GeneralUserObject to be executed in PREIC during initial setup
outputsVector of output names were you would like to restrict the output of variables(s) associated with this object
C++ Type:std::vector<OutputName>
Options:
Description:Vector of output names were you would like to restrict the output of variables(s) associated with this object
use_displaced_meshFalseWhether or not this object should use the displaced mesh for computation. Note that in the case this is true but no displacements are provided in the Mesh block the undisplaced mesh will still be used.
Default:False
C++ Type:bool
Options:
Description:Whether or not this object should use the displaced mesh for computation. Note that in the case this is true but no displacements are provided in the Mesh block the undisplaced mesh will still be used.

Advanced Parameters

Input Files

(modules/combined/examples/geochem-porous_flow/forge/aquifer_geochemistry.i)
(modules/combined/examples/geochem-porous_flow/forge/kinetic.i)
(test/tests/postprocessors/linear_combination/linear_combination.i)
(modules/combined/examples/geochem-porous_flow/forge/reservoir_and_water_3.i)
(test/tests/postprocessors/postprocessor_comparison/postprocessor_comparison.i)
(modules/combined/examples/geochem-porous_flow/forge/natural_reservoir.i)
(modules/combined/examples/geochem-porous_flow/forge/porous_flow.i)

(test/tests/postprocessors/linear_combination/linear_combination.i)

# Tests the LinearCombinationPostprocessor post-processor, which computes
# a linear combination of an arbitrary number of post-processor values.

[Mesh]
  type = GeneratedMesh
  dim = 1
  nx = 2
[]

[Problem]
  solve = false
[]

[Executioner]
  type = Steady
[]

[Postprocessors]
  [./pp1]
    # number of elements, equal to 2
    type = NumElems
  [../]
  [./pp2]
    # number of nodes, equal to 3
    type = NumNodes
  [../]

  # post-processor value being tested; value should be the following:
  #   value = c1 * pp1 + c2 * pp2 + b
  #         = 2  * 2   + -1 * 3   + 5 = 6
  [./linear_combination]
    type = LinearCombinationPostprocessor
    pp_names = 'pp1 pp2'
    pp_coefs = '2   -1'
    b = 5
  [../]
[]

[Outputs]
  show = linear_combination
  csv = true
[]

(modules/combined/examples/geochem-porous_flow/forge/aquifer_geochemistry.i)

# Simulates geochemistry in the aquifer.  This input file may be run in standalone fashion, which will study the natural kinetically-controlled mineral changes in the same way as natural_reservoir.i.  To simulate the FORGE injection scenario, run the porous_flow.i simulation which couples to this input file using MultiApps.
# This file receives pf_rate_H pf_rate_Na pf_rate_K pf_rate_Ca pf_rate_Mg pf_rate_SiO2 pf_rate_Al pf_rate_Cl pf_rate_SO4 pf_rate_HCO3 pf_rate_H2O and temperature as AuxVariables from porous_flow.i
# The pf_rate quantities are kg/s changes of fluid-component mass at each node, but the geochemistry module expects rates-of-changes of moles at every node.  Secondly, since this input file considers just 1 litre of aqueous solution at every node, the nodal_void_volume is used to convert pf_rate_* into rate_*_per_1l, which is measured in mol/s/1_litre_of_aqueous_solution.
# This file sends massfrac_H massfrac_Na massfrac_K massfrac_Ca massfrac_Mg massfrac_SiO2 massfrac_Al massfrac_Cl massfrac_SO4 massfrac_HCO3 to porous_flow.i.  These are computed from the corresponding transported_* quantities.
# The results depend on the kinetic rates used and these are recognised to be poorly constrained by experiment
[UserObjects]
  [rate_Albite]
    type = GeochemistryKineticRate
    kinetic_species_name = Albite
    intrinsic_rate_constant = 1E-17
    multiply_by_mass = true
    area_quantity = 10
    activation_energy = 69.8E3
    one_over_T0 = 0.003354
  []
  [rate_Anhydrite]
    type = GeochemistryKineticRate
    kinetic_species_name = Anhydrite
    intrinsic_rate_constant = 1.0E-7
    multiply_by_mass = true
    area_quantity = 10
    activation_energy = 14.3E3
    one_over_T0 = 0.003354
  []
  [rate_Anorthite]
    type = GeochemistryKineticRate
    kinetic_species_name = Anorthite
    intrinsic_rate_constant = 1.0E-13
    multiply_by_mass = true
    area_quantity = 10
    activation_energy = 17.8E3
    one_over_T0 = 0.003354
  []
  [rate_Calcite]
    type = GeochemistryKineticRate
    kinetic_species_name = Calcite
    intrinsic_rate_constant = 1.0E-10
    multiply_by_mass = true
    area_quantity = 10
    activation_energy = 23.5E3
    one_over_T0 = 0.003354
  []
  [rate_Chalcedony]
    type = GeochemistryKineticRate
    kinetic_species_name = Chalcedony
    intrinsic_rate_constant = 1.0E-18
    multiply_by_mass = true
    area_quantity = 10
    activation_energy = 90.1E3
    one_over_T0 = 0.003354
  []
  [rate_Clinochl-7A]
    type = GeochemistryKineticRate
    kinetic_species_name = Clinochl-7A
    intrinsic_rate_constant = 1.0E-17
    multiply_by_mass = true
    area_quantity = 10
    activation_energy = 88.0E3
    one_over_T0 = 0.003354
  []
  [rate_Illite]
    type = GeochemistryKineticRate
    kinetic_species_name = Illite
    intrinsic_rate_constant = 1E-17
    multiply_by_mass = true
    area_quantity = 10
    activation_energy = 29E3
    one_over_T0 = 0.003354
  []
  [rate_K-feldspar]
    type = GeochemistryKineticRate
    kinetic_species_name = K-feldspar
    intrinsic_rate_constant = 1E-17
    multiply_by_mass = true
    area_quantity = 10
    activation_energy = 38E3
    one_over_T0 = 0.003354
  []
  [rate_Kaolinite]
    type = GeochemistryKineticRate
    kinetic_species_name = Kaolinite
    intrinsic_rate_constant = 1E-18
    multiply_by_mass = true
    area_quantity = 10
    activation_energy = 22.2E3
    one_over_T0 = 0.003354
  []
  [rate_Quartz]
    type = GeochemistryKineticRate
    kinetic_species_name = Quartz
    intrinsic_rate_constant = 1E-18
    multiply_by_mass = true
    area_quantity = 10
    activation_energy = 90.1E3
    one_over_T0 = 0.003354
  []
  [rate_Paragonite]
    type = GeochemistryKineticRate
    kinetic_species_name = Paragonite
    intrinsic_rate_constant = 1E-17
    multiply_by_mass = true
    area_quantity = 10
    activation_energy = 22E3
    one_over_T0 = 0.003354
  []
  [rate_Phlogopite]
    type = GeochemistryKineticRate
    kinetic_species_name = Phlogopite
    intrinsic_rate_constant = 1E-17
    multiply_by_mass = true
    area_quantity = 10
    activation_energy = 22E3
    one_over_T0 = 0.003354
  []
  [rate_Laumontite]
    type = GeochemistryKineticRate
    kinetic_species_name = Laumontite
    intrinsic_rate_constant = 1.0E-15
    multiply_by_mass = true
    area_quantity = 10
    activation_energy = 17.8E3
    one_over_T0 = 0.003354
  []
  [rate_Zoisite]
    type = GeochemistryKineticRate
    kinetic_species_name = Zoisite
    intrinsic_rate_constant = 1E-16
    multiply_by_mass = true
    area_quantity = 10
    activation_energy = 66.1E3
    one_over_T0 = 0.003354
  []
  [definition]
    type = GeochemicalModelDefinition
    database_file = '../../../../geochemistry/database/moose_geochemdb.json'
    basis_species = 'H2O H+ Na+ K+ Ca++ Mg++ SiO2(aq) Al+++ Cl- SO4-- HCO3-'
    remove_all_extrapolated_secondary_species = true
    kinetic_minerals = 'Albite Anhydrite Anorthite Calcite Chalcedony Clinochl-7A Illite K-feldspar Kaolinite Quartz Paragonite Phlogopite Zoisite Laumontite'
    kinetic_rate_descriptions = 'rate_Albite rate_Anhydrite rate_Anorthite rate_Calcite rate_Chalcedony rate_Clinochl-7A rate_Illite rate_K-feldspar rate_Kaolinite rate_Quartz rate_Paragonite rate_Phlogopite rate_Zoisite rate_Laumontite'
  []
  [nodal_void_volume_uo]
    type = NodalVoidVolume
    porosity = porosity
    execute_on = 'initial timestep_end' # "initial" means this is evaluated properly for the first timestep
  []
[]

[SpatialReactionSolver]
  model_definition = definition
  geochemistry_reactor_name = reactor
  charge_balance_species = 'Cl-'
  constraint_species = 'H2O              H+                  Na+              K+                 Ca++              Mg++                SiO2(aq)           Al+++               Cl-                SO4--               HCO3-'
# Following numbers are from water_60_to_220degC_out.csv
  constraint_value = '  1.0006383866109  9.5165072498215e-07 0.100020379171   0.0059389061065    0.011570884507621 4.6626763057447e-06 0.0045110404925255 5.8096968688789e-17 0.13500708594394   6.6523540147676e-05 7.7361407898089e-05'
  constraint_meaning = 'kg_solvent_water free_concentration       free_concentration    free_concentration      free_concentration     free_concentration       free_concentration      free_concentration       bulk_composition free_concentration       free_concentration'
  constraint_unit = '   kg               molal               molal            molal              molal             molal               molal              molal               moles              molal               molal'
  initial_temperature = 220
  temperature = temperature
  kinetic_species_name = '         Albite             Anorthite          K-feldspar         Quartz             Phlogopite         Paragonite         Calcite            Anhydrite          Chalcedony         Illite             Kaolinite          Clinochl-7A        Zoisite            Laumontite'
  kinetic_species_initial_value = '4.324073236492E+02 4.631370307325E+01 2.685015418378E+02 7.720095013956E+02 1.235192062541E+01 7.545461404965E-01 4.234651808835E-04 4.000485907930E-04 4.407616361072E+00 1.342524904876E+01 1.004823151125E+00 4.728132387707E-01 7.326007326007E-01 4.818116116598E-01'
  kinetic_species_unit = '         moles              moles              moles              moles              moles              moles              moles              moles              moles              moles              moles              moles              moles              moles'
  evaluate_kinetic_rates_always = true # otherwise will easily "run out" of dissolving species
  source_species_names = 'H2O H+ Na+ K+ Ca++ Mg++ SiO2(aq) Al+++ Cl- SO4-- HCO3-'
  source_species_rates = 'rate_H2O_per_1l rate_H_per_1l rate_Na_per_1l rate_K_per_1l rate_Ca_per_1l rate_Mg_per_1l rate_SiO2_per_1l rate_Al_per_1l rate_Cl_per_1l rate_SO4_per_1l rate_HCO3_per_1l'
  ramp_max_ionic_strength_initial = 0 # max_ionic_strength in such a simple problem does not need ramping
  execute_console_output_on = ''
  add_aux_molal = false # save some memory and reduce variables in output exodus
  add_aux_mg_per_kg = false # save some memory and reduce variables in output exodus
  add_aux_free_mg = false # save some memory and reduce variables in output exodus
  add_aux_activity = false # save some memory and reduce variables in output exodus
  add_aux_bulk_moles = false # save some memory and reduce variables in output exodus
  adaptive_timestepping = true
[]

[Mesh]
  [gen]
    type = GeneratedMeshGenerator
    dim = 2
    nx = 15
    ny = 10
    xmin = -100
    xmax = 200
    ymin = -100
    ymax = 100
  []
  [injection_node]
    input = gen
    type = ExtraNodesetGenerator
    new_boundary = injection_node
    coord = '0 0 0'
  []
[]

[Executioner]
  type = Transient
  [TimeStepper]
    type = FunctionDT
    function = 'max(1E6, 0.3 * t)'
  []
  end_time = 4E12
[]

[AuxVariables]
  [temperature]
    initial_condition = 220.0
  []
  [porosity]
    initial_condition = 0.01
  []
  [nodal_void_volume]
  []
  [free_cm3_Kfeldspar] # necessary because of the minus sign in K-feldspar which does not parse correctly in the porosity AuxKernel
  []
  [free_cm3_Clinochl7A] # necessary because of the minus sign in Clinochl-7A which does not parse correctly in the porosity AuxKernel
  []
  [pf_rate_H] # change in H mass (kg/s) at each node provided by the porous-flow simulation
  []
  [pf_rate_Na]
  []
  [pf_rate_K]
  []
  [pf_rate_Ca]
  []
  [pf_rate_Mg]
  []
  [pf_rate_SiO2]
  []
  [pf_rate_Al]
  []
  [pf_rate_Cl]
  []
  [pf_rate_SO4]
  []
  [pf_rate_HCO3]
  []
  [pf_rate_H2O] # change in H2O mass (kg/s) at each node provided by the porous-flow simulation
  []
  [rate_H_per_1l]
  []
  [rate_Na_per_1l]
  []
  [rate_K_per_1l]
  []
  [rate_Ca_per_1l]
  []
  [rate_Mg_per_1l]
  []
  [rate_SiO2_per_1l]
  []
  [rate_Al_per_1l]
  []
  [rate_Cl_per_1l]
  []
  [rate_SO4_per_1l]
  []
  [rate_HCO3_per_1l]
  []
  [rate_H2O_per_1l]
  []
  [transported_H]
  []
  [transported_Na]
  []
  [transported_K]
  []
  [transported_Ca]
  []
  [transported_Mg]
  []
  [transported_SiO2]
  []
  [transported_Al]
  []
  [transported_Cl]
  []
  [transported_SO4]
  []
  [transported_HCO3]
  []
  [transported_H2O]
  []
  [transported_mass]
  []
  [massfrac_H]
  []
  [massfrac_Na]
  []
  [massfrac_K]
  []
  [massfrac_Ca]
  []
  [massfrac_Mg]
  []
  [massfrac_SiO2]
  []
  [massfrac_Al]
  []
  [massfrac_Cl]
  []
  [massfrac_SO4]
  []
  [massfrac_HCO3]
  []
  [massfrac_H2O]
  []
[]

[AuxKernels]
  [free_cm3_Kfeldspar]
    type = GeochemistryQuantityAux
    variable = free_cm3_Kfeldspar
    species = 'K-feldspar'
    quantity = free_cm3
    execute_on = 'timestep_begin timestep_end'
  []
  [free_cm3_Clinochl7A]
    type = GeochemistryQuantityAux
    variable = free_cm3_Clinochl7A
    species = 'Clinochl-7A'
    quantity = free_cm3
    execute_on = 'timestep_begin timestep_end'
  []
  [porosity_auxk]
    type = ParsedAux
    args = 'free_cm3_Albite free_cm3_Anhydrite free_cm3_Anorthite free_cm3_Calcite free_cm3_Chalcedony free_cm3_Clinochl7A free_cm3_Illite free_cm3_Kfeldspar free_cm3_Kaolinite free_cm3_Quartz free_cm3_Paragonite free_cm3_Phlogopite free_cm3_Zoisite free_cm3_Laumontite'
    function = '1000.0 / (1000.0 + free_cm3_Albite + free_cm3_Anhydrite + free_cm3_Anorthite + free_cm3_Calcite + free_cm3_Chalcedony + free_cm3_Clinochl7A + free_cm3_Illite + free_cm3_Kfeldspar + free_cm3_Kaolinite + free_cm3_Quartz + free_cm3_Paragonite + free_cm3_Phlogopite + free_cm3_Zoisite + free_cm3_Laumontite)'
    variable = porosity
    execute_on = 'timestep_end'
  []
  [nodal_void_volume_auxk]
    type = NodalVoidVolumeAux
    variable = nodal_void_volume
    nodal_void_volume_uo = nodal_void_volume_uo
    execute_on = 'initial timestep_end' # "initial" to ensure it is properly evaluated for the first timestep
  []
  [rate_H_per_1l_auxk]
    type = ParsedAux
    args = 'pf_rate_H nodal_void_volume'
    variable = rate_H_per_1l
    function = 'pf_rate_H / 1.0079 / nodal_void_volume'
    execute_on = 'timestep_begin'
  []
  [rate_Na_per_1l_auxk]
    type = ParsedAux
    args = 'pf_rate_Na nodal_void_volume'
    variable = rate_Na_per_1l
    function = 'pf_rate_Na / 22.9898 / nodal_void_volume'
    execute_on = 'timestep_begin'
  []
  [rate_K_per_1l_auxk]
    type = ParsedAux
    args = 'pf_rate_K nodal_void_volume'
    variable = rate_K_per_1l
    function = 'pf_rate_K / 39.0983 / nodal_void_volume'
    execute_on = 'timestep_begin'
  []
  [rate_Ca_per_1l_auxk]
    type = ParsedAux
    args = 'pf_rate_Ca nodal_void_volume'
    variable = rate_Ca_per_1l
    function = 'pf_rate_Ca / 40.08 / nodal_void_volume'
    execute_on = 'timestep_begin'
  []
  [rate_Mg_per_1l_auxk]
    type = ParsedAux
    args = 'pf_rate_Mg nodal_void_volume'
    variable = rate_Mg_per_1l
    function = 'pf_rate_Mg / 24.305 / nodal_void_volume'
    execute_on = 'timestep_begin'
  []
  [rate_SiO2_per_1l_auxk]
    type = ParsedAux
    args = 'pf_rate_SiO2 nodal_void_volume'
    variable = rate_SiO2_per_1l
    function = 'pf_rate_SiO2 / 60.0843 / nodal_void_volume'
    execute_on = 'timestep_begin'
  []
  [rate_Al_per_1l_auxk]
    type = ParsedAux
    args = 'pf_rate_Al nodal_void_volume'
    variable = rate_Al_per_1l
    function = 'pf_rate_Al / 26.9815 / nodal_void_volume'
    execute_on = 'timestep_begin'
  []
  [rate_Cl_per_1l_auxk]
    type = ParsedAux
    args = 'pf_rate_Cl nodal_void_volume'
    variable = rate_Cl_per_1l
    function = 'pf_rate_Cl / 35.453 / nodal_void_volume'
    execute_on = 'timestep_begin'
  []
  [rate_SO4_per_1l_auxk]
    type = ParsedAux
    args = 'pf_rate_SO4 nodal_void_volume'
    variable = rate_SO4_per_1l
    function = 'pf_rate_SO4 / 96.0576 / nodal_void_volume'
    execute_on = 'timestep_begin'
  []
  [rate_HCO3_per_1l_auxk]
    type = ParsedAux
    args = 'pf_rate_HCO3 nodal_void_volume'
    variable = rate_HCO3_per_1l
    function = 'pf_rate_HCO3 / 61.0171 / nodal_void_volume'
    execute_on = 'timestep_begin'
  []
  [rate_H2O_per_1l_auxk]
    type = ParsedAux
    args = 'pf_rate_H2O nodal_void_volume'
    variable = rate_H2O_per_1l
    function = 'pf_rate_H2O / 18.01801802 / nodal_void_volume'
    execute_on = 'timestep_begin'
  []
  [transported_H_auxk]
    type = GeochemistryQuantityAux
    variable = transported_H
    species = 'H+'
    quantity = transported_moles_in_original_basis
    execute_on = 'timestep_begin'
  []
  [transported_Na_auxk]
    type = GeochemistryQuantityAux
    variable = transported_Na
    species = 'Na+'
    quantity = transported_moles_in_original_basis
    execute_on = 'timestep_begin'
  []
  [transported_K_auxk]
    type = GeochemistryQuantityAux
    variable = transported_K
    species = 'K+'
    quantity = transported_moles_in_original_basis
    execute_on = 'timestep_begin'
  []
  [transported_Ca_auxk]
    type = GeochemistryQuantityAux
    variable = transported_Ca
    species = 'Ca++'
    quantity = transported_moles_in_original_basis
    execute_on = 'timestep_begin'
  []
  [transported_Mg_auxk]
    type = GeochemistryQuantityAux
    variable = transported_Mg
    species = 'Mg++'
    quantity = transported_moles_in_original_basis
    execute_on = 'timestep_begin'
  []
  [transported_SiO2_auxk]
    type = GeochemistryQuantityAux
    variable = transported_SiO2
    species = 'SiO2(aq)'
    quantity = transported_moles_in_original_basis
    execute_on = 'timestep_begin'
  []
  [transported_Al_auxk]
    type = GeochemistryQuantityAux
    variable = transported_Al
    species = 'Al+++'
    quantity = transported_moles_in_original_basis
    execute_on = 'timestep_begin'
  []
  [transported_Cl_auxk]
    type = GeochemistryQuantityAux
    variable = transported_Cl
    species = 'Cl-'
    quantity = transported_moles_in_original_basis
    execute_on = 'timestep_begin'
  []
  [transported_SO4_auxk]
    type = GeochemistryQuantityAux
    variable = transported_SO4
    species = 'SO4--'
    quantity = transported_moles_in_original_basis
    execute_on = 'timestep_begin'
  []
  [transported_HCO3_auxk]
    type = GeochemistryQuantityAux
    variable = transported_HCO3
    species = 'HCO3-'
    quantity = transported_moles_in_original_basis
    execute_on = 'timestep_begin'
  []
  [transported_H2O_auxk]
    type = GeochemistryQuantityAux
    variable = transported_H2O
    species = 'H2O'
    quantity = transported_moles_in_original_basis
    execute_on = 'timestep_begin'
  []
  [transported_mass_auxk]
    type = ParsedAux
    args = ' transported_H transported_Na transported_K transported_Ca transported_Mg transported_SiO2 transported_Al transported_Cl transported_SO4 transported_HCO3 transported_H2O'
    variable = transported_mass
    function = 'transported_H * 1.0079 + transported_Cl * 35.453 + transported_SO4 * 96.0576 + transported_HCO3 * 61.0171 + transported_SiO2 * 60.0843 + transported_Al * 26.9815 + transported_Ca * 40.08 + transported_Mg * 24.305 + transported_K * 39.0983 + transported_Na * 22.9898 + transported_H2O * 18.01801802'
    execute_on = 'timestep_end'
  []
  [massfrac_H_auxk]
    type = ParsedAux
    args = 'transported_H transported_mass'
    variable = massfrac_H
    function = 'transported_H * 1.0079 / transported_mass'
    execute_on = 'timestep_end'
  []
  [massfrac_Na_auxk]
    type = ParsedAux
    args = 'transported_Na transported_mass'
    variable = massfrac_Na
    function = 'transported_Na * 22.9898 / transported_mass'
    execute_on = 'timestep_end'
  []
  [massfrac_K_auxk]
    type = ParsedAux
    args = 'transported_K transported_mass'
    variable = massfrac_K
    function = 'transported_K * 39.0983 / transported_mass'
    execute_on = 'timestep_end'
  []
  [massfrac_Ca_auxk]
    type = ParsedAux
    args = 'transported_Ca transported_mass'
    variable = massfrac_Ca
    function = 'transported_Ca * 40.08 / transported_mass'
    execute_on = 'timestep_end'
  []
  [massfrac_Mg_auxk]
    type = ParsedAux
    args = 'transported_Mg transported_mass'
    variable = massfrac_Mg
    function = 'transported_Mg * 24.305 / transported_mass'
    execute_on = 'timestep_end'
  []
  [massfrac_SiO2_auxk]
    type = ParsedAux
    args = 'transported_SiO2 transported_mass'
    variable = massfrac_SiO2
    function = 'transported_SiO2 * 60.0843 / transported_mass'
    execute_on = 'timestep_end'
  []
  [massfrac_Al_auxk]
    type = ParsedAux
    args = 'transported_Al transported_mass'
    variable = massfrac_Al
    function = 'transported_Al * 26.9815 / transported_mass'
    execute_on = 'timestep_end'
  []
  [massfrac_Cl_auxk]
    type = ParsedAux
    args = 'transported_Cl transported_mass'
    variable = massfrac_Cl
    function = 'transported_Cl * 35.453 / transported_mass'
    execute_on = 'timestep_end'
  []
  [massfrac_SO4_auxk]
    type = ParsedAux
    args = 'transported_SO4 transported_mass'
    variable = massfrac_SO4
    function = 'transported_SO4 * 96.0576 / transported_mass'
    execute_on = 'timestep_end'
  []
  [massfrac_HCO3_auxk]
    type = ParsedAux
    args = 'transported_HCO3 transported_mass'
    variable = massfrac_HCO3
    function = 'transported_HCO3 * 61.0171 / transported_mass'
    execute_on = 'timestep_end'
  []
  [massfrac_H2O_auxk]
    type = ParsedAux
    args = 'transported_H2O transported_mass'
    variable = massfrac_H2O
    function = 'transported_H2O * 18.01801802 / transported_mass'
    execute_on = 'timestep_end'
  []
[]

[GlobalParams]
  point = '0 0 0'
  reactor = reactor
[]

[Postprocessors]
  [temperature]
    type = PointValue
    variable = 'solution_temperature'
  []
  [porosity]
    type = PointValue
    variable = porosity
  []
  [solution_temperature]
    type = PointValue
    variable = solution_temperature
  []
  [massfrac_H]
    type = PointValue
    variable = massfrac_H
  []
  [massfrac_Na]
    type = PointValue
    variable = massfrac_Na
  []
  [massfrac_K]
    type = PointValue
    variable = massfrac_K
  []
  [massfrac_Ca]
    type = PointValue
    variable = massfrac_Ca
  []
  [massfrac_Mg]
    type = PointValue
    variable = massfrac_Mg
  []
  [massfrac_SiO2]
    type = PointValue
    variable = massfrac_SiO2
  []
  [massfrac_Al]
    type = PointValue
    variable = massfrac_Al
  []
  [massfrac_Cl]
    type = PointValue
    variable = massfrac_Cl
  []
  [massfrac_SO4]
    type = PointValue
    variable = massfrac_SO4
  []
  [massfrac_HCO3]
    type = PointValue
    variable = massfrac_HCO3
  []
  [massfrac_H2O]
    type = PointValue
    variable = massfrac_H2O
  []
  [cm3_Albite]
    type = PointValue
    variable = 'free_cm3_Albite'
  []
  [cm3_Anhydrite]
    type = PointValue
    variable = 'free_cm3_Anhydrite'
  []
  [cm3_Anorthite]
    type = PointValue
    variable = 'free_cm3_Anorthite'
  []
  [cm3_Calcite]
    type = PointValue
    variable = 'free_cm3_Calcite'
  []
  [cm3_Chalcedony]
    type = PointValue
    variable = 'free_cm3_Chalcedony'
  []
  [cm3_Clinochl-7A]
    type = PointValue
    variable = 'free_cm3_Clinochl-7A'
  []
  [cm3_Illite]
    type = PointValue
    variable = 'free_cm3_Illite'
  []
  [cm3_K-feldspar]
    type = PointValue
    variable = 'free_cm3_K-feldspar'
  []
  [cm3_Kaolinite]
    type = PointValue
    variable = 'free_cm3_Kaolinite'
  []
  [cm3_Quartz]
    type = PointValue
    variable = 'free_cm3_Quartz'
  []
  [cm3_Paragonite]
    type = PointValue
    variable = 'free_cm3_Paragonite'
  []
  [cm3_Phlogopite]
    type = PointValue
    variable = 'free_cm3_Phlogopite'
  []
  [cm3_Zoisite]
    type = PointValue
    variable = 'free_cm3_Zoisite'
  []
  [cm3_Laumontite]
    type = PointValue
    variable = 'free_cm3_Laumontite'
  []
  [cm3_mineral]
    type = LinearCombinationPostprocessor
    pp_names = 'cm3_Albite cm3_Anhydrite cm3_Anorthite cm3_Calcite cm3_Chalcedony cm3_Clinochl-7A cm3_Illite cm3_K-feldspar cm3_Kaolinite cm3_Quartz cm3_Paragonite cm3_Phlogopite cm3_Zoisite cm3_Laumontite'
    pp_coefs = '1 1 1 1 1 1 1 1 1 1 1 1 1 1'
  []
  [pH]
    type = PointValue
    variable = 'pH'
  []
[]

[Outputs]
  [exo]
    type = Exodus
    execute_on = final
  []
  csv = true
[]

(modules/combined/examples/geochem-porous_flow/forge/kinetic.i)

# Simulation to check that the output of water_60_to_220degC is indeed at equilibrium with the mineral assemblage.
# The initial mole numbers of the kinetic species are unimportant for this simulation, but are chosen to be consistent with other input files.  The numerical values are such that:
# - the mass fractions are: Albite 0.44; Anorthite 0.05; K-feldspar 0.29; Quartz 0.18, Phlgoptite 0.04 with trace amounts of Calcite and Anhydrite.  These are similar to that measured in bulk X-ray diffraction results of 10 samples from well 58-32, assuming that "plagioclase feldspar" consists of Albite and Anorthite in the ratio 9:1, and that Biotite is Phlogoptite, and the 2% Illite is added to Phlogoptite.  Precisely:
# - it is assumed that water_60_to_220degC consists of 1 litre of water (there is 1kg of solvent water) and that the porosity is 0.01, so the amount of rock should be 99000cm^3
# - the cm^3 of the trace minerals Calcite and Anhydrite is exactly given by water_60_to_220degC (0.016 and 0.018 respectively)
# - the total mineral volume is 99000cm^3, so that the porosity is 0.01
# - see initial_kinetic_moles.xlsx for the remaining mole numbers
[UserObjects]
  [rate_Albite]
    type = GeochemistryKineticRate
    kinetic_species_name = Albite
    intrinsic_rate_constant = 1E-17
    multiply_by_mass = true
    area_quantity = 10
    activation_energy = 69.8E3
    one_over_T0 = 0.003354
  []
  [rate_Anhydrite]
    type = GeochemistryKineticRate
    kinetic_species_name = Anhydrite
    intrinsic_rate_constant = 1.0E-7
    multiply_by_mass = true
    area_quantity = 10
    activation_energy = 14.3E3
    one_over_T0 = 0.003354
  []
  [rate_Anorthite]
    type = GeochemistryKineticRate
    kinetic_species_name = Anorthite
    intrinsic_rate_constant = 1.0E-13
    multiply_by_mass = true
    area_quantity = 10
    activation_energy = 17.8E3
    one_over_T0 = 0.003354
  []
  [rate_Calcite]
    type = GeochemistryKineticRate
    kinetic_species_name = Calcite
    intrinsic_rate_constant = 1.0E-10
    multiply_by_mass = true
    area_quantity = 10
    activation_energy = 23.5E3
    one_over_T0 = 0.003354
  []
  [rate_Chalcedony]
    type = GeochemistryKineticRate
    kinetic_species_name = Chalcedony
    intrinsic_rate_constant = 1.0E-18
    multiply_by_mass = true
    area_quantity = 10
    activation_energy = 90.1E3
    one_over_T0 = 0.003354
  []
  [rate_Clinochl-7A]
    type = GeochemistryKineticRate
    kinetic_species_name = Clinochl-7A
    intrinsic_rate_constant = 1.0E-17
    multiply_by_mass = true
    area_quantity = 10
    activation_energy = 88.0E3
    one_over_T0 = 0.003354
  []
  [rate_Illite]
    type = GeochemistryKineticRate
    kinetic_species_name = Illite
    intrinsic_rate_constant = 1E-17
    multiply_by_mass = true
    area_quantity = 10
    activation_energy = 29E3
    one_over_T0 = 0.003354
  []
  [rate_K-feldspar]
    type = GeochemistryKineticRate
    kinetic_species_name = K-feldspar
    intrinsic_rate_constant = 1E-17
    multiply_by_mass = true
    area_quantity = 10
    activation_energy = 38E3
    one_over_T0 = 0.003354
  []
  [rate_Kaolinite]
    type = GeochemistryKineticRate
    kinetic_species_name = Kaolinite
    intrinsic_rate_constant = 1E-18
    multiply_by_mass = true
    area_quantity = 10
    activation_energy = 22.2E3
    one_over_T0 = 0.003354
  []
  [rate_Quartz]
    type = GeochemistryKineticRate
    kinetic_species_name = Quartz
    intrinsic_rate_constant = 1E-18
    multiply_by_mass = true
    area_quantity = 10
    activation_energy = 90.1E3
    one_over_T0 = 0.003354
  []
  [rate_Paragonite]
    type = GeochemistryKineticRate
    kinetic_species_name = Paragonite
    intrinsic_rate_constant = 1E-17
    multiply_by_mass = true
    area_quantity = 10
    activation_energy = 22E3
    one_over_T0 = 0.003354
  []
  [rate_Phlogopite]
    type = GeochemistryKineticRate
    kinetic_species_name = Phlogopite
    intrinsic_rate_constant = 1E-17
    multiply_by_mass = true
    area_quantity = 10
    activation_energy = 22E3
    one_over_T0 = 0.003354
  []
  [rate_Zoisite]
    type = GeochemistryKineticRate
    kinetic_species_name = Zoisite
    intrinsic_rate_constant = 1E-16
    multiply_by_mass = true
    area_quantity = 10
    activation_energy = 66.1E3
    one_over_T0 = 0.003354
  []
  [definition]
    type = GeochemicalModelDefinition
    database_file = '../../../../geochemistry/database/moose_geochemdb.json'
    basis_species = 'H2O H+ Na+ K+ Ca++ Mg++ SiO2(aq) Al+++ Cl- SO4-- HCO3-'
    remove_all_extrapolated_secondary_species = true
    kinetic_minerals = 'Albite Anhydrite Anorthite Calcite Chalcedony Clinochl-7A Illite K-feldspar Kaolinite Quartz Paragonite Phlogopite'
    kinetic_rate_descriptions = 'rate_Albite rate_Anhydrite rate_Anorthite rate_Calcite rate_Chalcedony rate_Clinochl-7A rate_Illite rate_K-feldspar rate_Kaolinite rate_Quartz rate_Paragonite rate_Phlogopite'
  []
[]

[TimeDependentReactionSolver]
  model_definition = definition
  geochemistry_reactor_name = reactor
  charge_balance_species = 'Cl-'
  constraint_species = 'H2O              H+                  Na+              K+                 Ca++              Mg++                SiO2(aq)           Al+++               Cl-                SO4--               HCO3-'
# Following numbers are from water_60_to_220degC_out.csv
  constraint_value = '  1.0006383866109  9.5165072498215e-07 0.100020379171   0.0059389061065    0.011570884507621 4.6626763057447e-06 0.0045110404925255 5.8096968688789e-17 0.13500708594394   6.6523540147676e-05 7.7361407898089e-05'
  constraint_meaning = 'kg_solvent_water free_concentration       free_concentration    free_concentration     free_concentration   free_concentration       free_concentration      free_concentration       bulk_composition free_concentration       free_concentration'
  constraint_unit = '   kg               molal               molal            molal              molal           molal              molal              molal               moles              molal               molal'
  initial_temperature = 220
  temperature = 220
  kinetic_species_name = '         Albite           Anorthite       K-feldspar      Quartz           Phlogopite         Paragonite Calcite     Anhydrite   Chalcedony Illite Kaolinite Clinochl-7A'
  kinetic_species_initial_value = '4.3511787009E+02 4.660402064E+01 2.701846444E+02 7.7684884497E+02 2.4858697344E+01   1E-10      0.000423465 0.000400049 1E-10 1E-10 1E-10 1E-10'
  kinetic_species_unit = '         moles            moles           moles           moles            moles              moles      moles       moles       moles      moles  moles     moles'
  evaluate_kinetic_rates_always = true # otherwise will easily "run out" of dissolving species
  ramp_max_ionic_strength_initial = 0 # max_ionic_strength in such a simple problem does not need ramping
  mol_cutoff = 0.1
  execute_console_output_on = ''
[]

[Executioner]
  type = Transient
  [TimeStepper]
    type = FunctionDT
    function = '1E8'
  []
  end_time = 4E8
[]

[GlobalParams]
  point = '0 0 0'
[]

[Postprocessors]
  [cm3_Albite]
    type = PointValue
    variable = 'free_cm3_Albite'
  []
  [cm3_Anhydrite]
    type = PointValue
    variable = 'free_cm3_Anhydrite'
  []
  [cm3_Anorthite]
    type = PointValue
    variable = 'free_cm3_Anorthite'
  []
  [cm3_Calcite]
    type = PointValue
    variable = 'free_cm3_Calcite'
  []
  [cm3_Chalcedony]
    type = PointValue
    variable = 'free_cm3_Chalcedony'
  []
  [cm3_Clinochl-7A]
    type = PointValue
    variable = 'free_cm3_Clinochl-7A'
  []
  [cm3_Illite]
    type = PointValue
    variable = 'free_cm3_Illite'
  []
  [cm3_K-feldspar]
    type = PointValue
    variable = 'free_cm3_K-feldspar'
  []
  [cm3_Kaolinite]
    type = PointValue
    variable = 'free_cm3_Kaolinite'
  []
  [cm3_Quartz]
    type = PointValue
    variable = 'free_cm3_Quartz'
  []
  [cm3_Paragonite]
    type = PointValue
    variable = 'free_cm3_Paragonite'
  []
  [cm3_Phlogopite]
    type = PointValue
    variable = 'free_cm3_Phlogopite'
  []
  [cm3_mineral]
    type = LinearCombinationPostprocessor
    pp_names = 'cm3_Albite cm3_Anhydrite cm3_Anorthite cm3_Calcite cm3_Chalcedony cm3_Clinochl-7A cm3_Illite cm3_K-feldspar cm3_Kaolinite cm3_Quartz cm3_Paragonite cm3_Phlogopite'
    pp_coefs = '1 1 1 1 1 1 1 1 1 1 1 1'
  []
[]

[Outputs]
  csv = true
[]

(test/tests/postprocessors/linear_combination/linear_combination.i)

# Tests the LinearCombinationPostprocessor post-processor, which computes
# a linear combination of an arbitrary number of post-processor values.

[Mesh]
  type = GeneratedMesh
  dim = 1
  nx = 2
[]

[Problem]
  solve = false
[]

[Executioner]
  type = Steady
[]

[Postprocessors]
  [./pp1]
    # number of elements, equal to 2
    type = NumElems
  [../]
  [./pp2]
    # number of nodes, equal to 3
    type = NumNodes
  [../]

  # post-processor value being tested; value should be the following:
  #   value = c1 * pp1 + c2 * pp2 + b
  #         = 2  * 2   + -1 * 3   + 5 = 6
  [./linear_combination]
    type = LinearCombinationPostprocessor
    pp_names = 'pp1 pp2'
    pp_coefs = '2   -1'
    b = 5
  [../]
[]

[Outputs]
  show = linear_combination
  csv = true
[]

(modules/combined/examples/geochem-porous_flow/forge/reservoir_and_water_3.i)

# Simulation to assess possible changes in the reservoir.  The rock composition from natural_reservoir.i is mixed with the water from water_3.i  Note that the free_concentration values are used from water_3.i and that composition is held fixed throughout this entire simulation.  This models water_3 continually flushing through the rock mineral assemblage: as soon as a mineral dissolves the aqueous components are swept away and replaced by a new batch of water_3; as soon as mineral precipitates more water_3 sweeps into the system providing a limitless source of aqueous components (in set ratios) at 70degC
# The results depend on the kinetic rates used and these are recognised to be poorly constrained by experiment
[UserObjects]
  [rate_Albite]
    type = GeochemistryKineticRate
    kinetic_species_name = Albite
    intrinsic_rate_constant = 1E-17
    multiply_by_mass = true
    area_quantity = 10
    activation_energy = 69.8E3
    one_over_T0 = 0.003354
  []
  [rate_Anhydrite]
    type = GeochemistryKineticRate
    kinetic_species_name = Anhydrite
    intrinsic_rate_constant = 1.0E-7
    multiply_by_mass = true
    area_quantity = 10
    activation_energy = 14.3E3
    one_over_T0 = 0.003354
  []
  [rate_Anorthite]
    type = GeochemistryKineticRate
    kinetic_species_name = Anorthite
    intrinsic_rate_constant = 1.0E-13
    multiply_by_mass = true
    area_quantity = 10
    activation_energy = 17.8E3
    one_over_T0 = 0.003354
  []
  [rate_Calcite]
    type = GeochemistryKineticRate
    kinetic_species_name = Calcite
    intrinsic_rate_constant = 1.0E-10
    multiply_by_mass = true
    area_quantity = 10
    activation_energy = 23.5E3
    one_over_T0 = 0.003354
  []
  [rate_Chalcedony]
    type = GeochemistryKineticRate
    kinetic_species_name = Chalcedony
    intrinsic_rate_constant = 1.0E-18
    multiply_by_mass = true
    area_quantity = 10
    activation_energy = 90.1E3
    one_over_T0 = 0.003354
  []
  [rate_Clinochl-7A]
    type = GeochemistryKineticRate
    kinetic_species_name = Clinochl-7A
    intrinsic_rate_constant = 1.0E-17
    multiply_by_mass = true
    area_quantity = 10
    activation_energy = 88.0E3
    one_over_T0 = 0.003354
  []
  [rate_Illite]
    type = GeochemistryKineticRate
    kinetic_species_name = Illite
    intrinsic_rate_constant = 1E-17
    multiply_by_mass = true
    area_quantity = 10
    activation_energy = 29E3
    one_over_T0 = 0.003354
  []
  [rate_K-feldspar]
    type = GeochemistryKineticRate
    kinetic_species_name = K-feldspar
    intrinsic_rate_constant = 1E-17
    multiply_by_mass = true
    area_quantity = 10
    activation_energy = 38E3
    one_over_T0 = 0.003354
  []
  [rate_Kaolinite]
    type = GeochemistryKineticRate
    kinetic_species_name = Kaolinite
    intrinsic_rate_constant = 1E-18
    multiply_by_mass = true
    area_quantity = 10
    activation_energy = 22.2E3
    one_over_T0 = 0.003354
  []
  [rate_Quartz]
    type = GeochemistryKineticRate
    kinetic_species_name = Quartz
    intrinsic_rate_constant = 1E-18
    multiply_by_mass = true
    area_quantity = 10
    activation_energy = 90.1E3
    one_over_T0 = 0.003354
  []
  [rate_Paragonite]
    type = GeochemistryKineticRate
    kinetic_species_name = Paragonite
    intrinsic_rate_constant = 1E-17
    multiply_by_mass = true
    area_quantity = 10
    activation_energy = 22E3
    one_over_T0 = 0.003354
  []
  [rate_Phlogopite]
    type = GeochemistryKineticRate
    kinetic_species_name = Phlogopite
    intrinsic_rate_constant = 1E-17
    multiply_by_mass = true
    area_quantity = 10
    activation_energy = 22E3
    one_over_T0 = 0.003354
  []
  [rate_Laumontite]
    type = GeochemistryKineticRate
    kinetic_species_name = Laumontite
    intrinsic_rate_constant = 1.0E-15
    multiply_by_mass = true
    area_quantity = 10
    activation_energy = 17.8E3
    one_over_T0 = 0.003354
  []
  [rate_Zoisite]
    type = GeochemistryKineticRate
    kinetic_species_name = Zoisite
    intrinsic_rate_constant = 1E-16
    multiply_by_mass = true
    area_quantity = 10
    activation_energy = 66.1E3
    one_over_T0 = 0.003354
  []
  [definition]
    type = GeochemicalModelDefinition
    database_file = '../../../../geochemistry/database/moose_geochemdb.json'
    basis_species = 'H2O H+ Na+ K+ Ca++ Mg++ SiO2(aq) Al+++ Cl- SO4-- HCO3-'
    remove_all_extrapolated_secondary_species = true
    kinetic_minerals = 'Albite Anhydrite Anorthite Calcite Chalcedony Clinochl-7A Illite K-feldspar Kaolinite Quartz Paragonite Phlogopite Zoisite Laumontite'
    kinetic_rate_descriptions = 'rate_Albite rate_Anhydrite rate_Anorthite rate_Calcite rate_Chalcedony rate_Clinochl-7A rate_Illite rate_K-feldspar rate_Kaolinite rate_Quartz rate_Paragonite rate_Phlogopite rate_Zoisite rate_Laumontite'
  []
[]

[TimeDependentReactionSolver]
  model_definition = definition
  geochemistry_reactor_name = reactor
  charge_balance_species = 'Cl-'
  constraint_species = 'H2O              H+                  Na+                K+                  Ca++                Mg++               SiO2(aq)            Al+++               Cl-                SO4--               HCO3-'
# Following numbers are from water_3_out.csv
  constraint_value = '  0.99999999549877 8.0204734722945e-07 0.0001319920398478 2.8097346859027e-05 7.7328020546464e-05 2.874602030221e-05 0.00027284654762868 4.4715524787497e-12 0.0002253530818877 1.0385772502298e-05 0.00012427759434288'
  constraint_meaning = 'kg_solvent_water free_concentration       free_concentration    free_concentration      free_concentration     free_concentration       free_concentration      free_concentration       bulk_composition free_concentration       free_concentration'
  constraint_unit = '   kg               molal               molal            molal              molal             molal               molal              molal               moles              molal               molal'
  initial_temperature = 70
  temperature = 70
  close_system_at_time = 1E20 # keep the free molalities specified above for all time
  kinetic_species_name = '         Albite             Anorthite          K-feldspar         Quartz             Phlogopite         Paragonite         Calcite            Anhydrite          Chalcedony         Illite             Kaolinite          Clinochl-7A        Zoisite            Laumontite'
  kinetic_species_initial_value = '4.324073236492E+02 4.631370307325E+01 2.685015418378E+02 7.720095013956E+02 1.235192062541E+01 7.545461404965E-01 4.234651808835E-04 4.000485907930E-04 4.407616361072E+00 1.342524904876E+01 1.004823151125E+00 4.728132387707E-01 7.326007326007E-01 4.818116116598E-01'
  kinetic_species_unit = '         moles              moles              moles              moles              moles              moles              moles              moles              moles              moles              moles              moles              moles              moles'
  evaluate_kinetic_rates_always = true # otherwise will easily "run out" of dissolving species
  ramp_max_ionic_strength_initial = 0 # max_ionic_strength in such a simple problem does not need ramping
  execute_console_output_on = ''
[]

[Executioner]
  type = Transient
  [TimeStepper]
    type = FunctionDT
    function = 'max(1E6, 0.3 * t)'
  []
  end_time = 4E11
[]

[GlobalParams]
  point = '0 0 0'
[]

[Postprocessors]
  [temperature]
    type = PointValue
    variable = 'solution_temperature'
  []
  [cm3_Albite]
    type = PointValue
    variable = 'free_cm3_Albite'
  []
  [cm3_Anhydrite]
    type = PointValue
    variable = 'free_cm3_Anhydrite'
  []
  [cm3_Anorthite]
    type = PointValue
    variable = 'free_cm3_Anorthite'
  []
  [cm3_Calcite]
    type = PointValue
    variable = 'free_cm3_Calcite'
  []
  [cm3_Chalcedony]
    type = PointValue
    variable = 'free_cm3_Chalcedony'
  []
  [cm3_Clinochl-7A]
    type = PointValue
    variable = 'free_cm3_Clinochl-7A'
  []
  [cm3_Illite]
    type = PointValue
    variable = 'free_cm3_Illite'
  []
  [cm3_K-feldspar]
    type = PointValue
    variable = 'free_cm3_K-feldspar'
  []
  [cm3_Kaolinite]
    type = PointValue
    variable = 'free_cm3_Kaolinite'
  []
  [cm3_Quartz]
    type = PointValue
    variable = 'free_cm3_Quartz'
  []
  [cm3_Paragonite]
    type = PointValue
    variable = 'free_cm3_Paragonite'
  []
  [cm3_Phlogopite]
    type = PointValue
    variable = 'free_cm3_Phlogopite'
  []
  [cm3_Zoisite]
    type = PointValue
    variable = 'free_cm3_Zoisite'
  []
  [cm3_Laumontite]
    type = PointValue
    variable = 'free_cm3_Laumontite'
  []
  [cm3_mineral]
    type = LinearCombinationPostprocessor
    pp_names = 'cm3_Albite cm3_Anhydrite cm3_Anorthite cm3_Calcite cm3_Chalcedony cm3_Clinochl-7A cm3_Illite cm3_K-feldspar cm3_Kaolinite cm3_Quartz cm3_Paragonite cm3_Phlogopite cm3_Zoisite cm3_Laumontite'
    pp_coefs = '1 1 1 1 1 1 1 1 1 1 1 1 1 1'
  []
  [pH]
    type = PointValue
    variable = 'pH'
  []
[]

[Outputs]
  csv = true
[]

(test/tests/postprocessors/postprocessor_comparison/postprocessor_comparison.i)

# This tests the PostprocessorComparison post-processor, which compares two
# post-processors.

[Mesh]
  type = GeneratedMesh
  dim = 1
  nx = 1
  xmin = 0
  xmax = 1
[]

[Postprocessors]
  [./pp_to_compare]
    type = LinearCombinationPostprocessor
    pp_names = ''
    pp_coefs = ''
    b = 1
  [../]
  [./pp_comparison]
    type = PostprocessorComparison
    value_a = pp_to_compare
    value_b = 2
    comparison_type = greater_than
    execute_on = 'initial'
  [../]
[]

[Problem]
  solve = false
[]

[Executioner]
  type = Steady
[]

[Outputs]
  file_base = greater_than
  csv = true
  show = 'pp_comparison'
  execute_on = 'initial'
[]

(modules/combined/examples/geochem-porous_flow/forge/natural_reservoir.i)

# Simulation to assess natural changes in the reservoir.  Recall that water_60_to_220degC has provided a stable mineral assemblage that is in agreement with XRD observations, and a water at equilibrium with that assemblage.  However, Stuart Simmons suggested including Laumontite and Zoisite into the simulation, and they were not included in water_60_to_220degC since they are more stable than Anorthite, so Anorthite completely dissolves when equilibrium is assumed.  Here, all minerals suggested by Stuart Simmons are added to the system and kinetics are used to determine the time scales of the mineral changes.  The initial water composition is the reservoir water from water_60_to_220degC.
# The initial mole numbers of the kinetic species are chosen to be such that:
# - the mass fractions are: Albite 0.44; Anorthite 0.05; K-feldspar 0.29; Quartz 0.18, Phlgoptite 0.02 and Illite 0.02 with trace amounts of the remaining minerals.  These are similar to that measured in bulk X-ray diffraction results of 10 samples from well 58-32, assuming that "plagioclase feldspar" consists of Albite and Anorthite in the ratio 9:1, and that Biotite is Phlogoptite.  The trace amounts of each mineral are necessary because of the way the kinetics works: precipitation rate is proportional to mineral-species mass, so without any mass, no precipitation is possible.  Precisely:
# - it is assumed that water_60_to_220degC consists of 1 litre of water (there is 1kg of solvent water) and that the porosity is 0.01, so the amount of rock should be 99000cm^3
# - the cm^3 of the trace minerals Calcite and Anhydrite is exactly given by water_60_to_220degC (0.016 and 0.018 respectively)
# - see initial_kinetic_moles.xlsx for the remaining mole numbers
# The results depend on the kinetic rates used and these are recognised to be poorly constrained by experiment
[UserObjects]
  [rate_Albite]
    type = GeochemistryKineticRate
    kinetic_species_name = Albite
    intrinsic_rate_constant = 1E-17
    multiply_by_mass = true
    area_quantity = 10
    activation_energy = 69.8E3
    one_over_T0 = 0.003354
  []
  [rate_Anhydrite]
    type = GeochemistryKineticRate
    kinetic_species_name = Anhydrite
    intrinsic_rate_constant = 1.0E-7
    multiply_by_mass = true
    area_quantity = 10
    activation_energy = 14.3E3
    one_over_T0 = 0.003354
  []
  [rate_Anorthite]
    type = GeochemistryKineticRate
    kinetic_species_name = Anorthite
    intrinsic_rate_constant = 1.0E-13
    multiply_by_mass = true
    area_quantity = 10
    activation_energy = 17.8E3
    one_over_T0 = 0.003354
  []
  [rate_Calcite]
    type = GeochemistryKineticRate
    kinetic_species_name = Calcite
    intrinsic_rate_constant = 1.0E-10
    multiply_by_mass = true
    area_quantity = 10
    activation_energy = 23.5E3
    one_over_T0 = 0.003354
  []
  [rate_Chalcedony]
    type = GeochemistryKineticRate
    kinetic_species_name = Chalcedony
    intrinsic_rate_constant = 1.0E-18
    multiply_by_mass = true
    area_quantity = 10
    activation_energy = 90.1E3
    one_over_T0 = 0.003354
  []
  [rate_Clinochl-7A]
    type = GeochemistryKineticRate
    kinetic_species_name = Clinochl-7A
    intrinsic_rate_constant = 1.0E-17
    multiply_by_mass = true
    area_quantity = 10
    activation_energy = 88.0E3
    one_over_T0 = 0.003354
  []
  [rate_Illite]
    type = GeochemistryKineticRate
    kinetic_species_name = Illite
    intrinsic_rate_constant = 1E-17
    multiply_by_mass = true
    area_quantity = 10
    activation_energy = 29E3
    one_over_T0 = 0.003354
  []
  [rate_K-feldspar]
    type = GeochemistryKineticRate
    kinetic_species_name = K-feldspar
    intrinsic_rate_constant = 1E-17
    multiply_by_mass = true
    area_quantity = 10
    activation_energy = 38E3
    one_over_T0 = 0.003354
  []
  [rate_Kaolinite]
    type = GeochemistryKineticRate
    kinetic_species_name = Kaolinite
    intrinsic_rate_constant = 1E-18
    multiply_by_mass = true
    area_quantity = 10
    activation_energy = 22.2E3
    one_over_T0 = 0.003354
  []
  [rate_Quartz]
    type = GeochemistryKineticRate
    kinetic_species_name = Quartz
    intrinsic_rate_constant = 1E-18
    multiply_by_mass = true
    area_quantity = 10
    activation_energy = 90.1E3
    one_over_T0 = 0.003354
  []
  [rate_Paragonite]
    type = GeochemistryKineticRate
    kinetic_species_name = Paragonite
    intrinsic_rate_constant = 1E-17
    multiply_by_mass = true
    area_quantity = 10
    activation_energy = 22E3
    one_over_T0 = 0.003354
  []
  [rate_Phlogopite]
    type = GeochemistryKineticRate
    kinetic_species_name = Phlogopite
    intrinsic_rate_constant = 1E-17
    multiply_by_mass = true
    area_quantity = 10
    activation_energy = 22E3
    one_over_T0 = 0.003354
  []
  [rate_Laumontite]
    type = GeochemistryKineticRate
    kinetic_species_name = Laumontite
    intrinsic_rate_constant = 1.0E-15
    multiply_by_mass = true
    area_quantity = 10
    activation_energy = 17.8E3
    one_over_T0 = 0.003354
  []
  [rate_Zoisite]
    type = GeochemistryKineticRate
    kinetic_species_name = Zoisite
    intrinsic_rate_constant = 1E-16
    multiply_by_mass = true
    area_quantity = 10
    activation_energy = 66.1E3
    one_over_T0 = 0.003354
  []
  [definition]
    type = GeochemicalModelDefinition
    database_file = '../../../../geochemistry/database/moose_geochemdb.json'
    basis_species = 'H2O H+ Na+ K+ Ca++ Mg++ SiO2(aq) Al+++ Cl- SO4-- HCO3-'
    remove_all_extrapolated_secondary_species = true
    kinetic_minerals = 'Albite Anhydrite Anorthite Calcite Chalcedony Clinochl-7A Illite K-feldspar Kaolinite Quartz Paragonite Phlogopite Zoisite Laumontite'
    kinetic_rate_descriptions = 'rate_Albite rate_Anhydrite rate_Anorthite rate_Calcite rate_Chalcedony rate_Clinochl-7A rate_Illite rate_K-feldspar rate_Kaolinite rate_Quartz rate_Paragonite rate_Phlogopite rate_Zoisite rate_Laumontite'
  []
[]

[TimeDependentReactionSolver]
  model_definition = definition
  geochemistry_reactor_name = reactor
  charge_balance_species = 'Cl-'
  constraint_species = 'H2O              H+                  Na+                K+                 Ca++               Mg++                SiO2(aq)           Al+++               Cl-              SO4--               HCO3-'
# Following numbers are from water_60_to_220degC_out.csv
  constraint_value = '  1.0006383866109  9.5165072498215e-07 0.100020379171     0.0059389061065    0.011570884507621  4.6626763057447e-06 0.0045110404925255 5.8096968688789e-17 0.13500708594394 6.6523540147676e-05 7.7361407898089e-05'
  constraint_meaning = 'kg_solvent_water free_concentration  free_concentration free_concentration free_concentration free_concentration  free_concentration free_concentration  bulk_composition free_concentration  free_concentration'
  constraint_unit = '   kg               molal               molal              molal              molal              molal               molal              molal               moles            molal               molal'
  initial_temperature = 220
  temperature = 220
  kinetic_species_name = '         Albite             Anorthite          K-feldspar         Quartz             Phlogopite         Paragonite         Calcite            Anhydrite          Chalcedony         Illite             Kaolinite          Clinochl-7A        Zoisite            Laumontite'
  kinetic_species_initial_value = '4.324073236492E+02 4.631370307325E+01 2.685015418378E+02 7.720095013956E+02 1.235192062541E+01 7.545461404965E-01 4.234651808835E-04 4.000485907930E-04 4.407616361072E+00 1.342524904876E+01 1.004823151125E+00 4.728132387707E-01 7.326007326007E-01 4.818116116598E-01'
  kinetic_species_unit = '         moles              moles              moles              moles              moles              moles              moles              moles              moles              moles              moles              moles              moles              moles'
  evaluate_kinetic_rates_always = true # otherwise will easily "run out" of dissolving species
  ramp_max_ionic_strength_initial = 0 # max_ionic_strength in such a simple problem does not need ramping
  execute_console_output_on = ''
[]

[Executioner]
  type = Transient
  [TimeStepper]
    type = FunctionDT
    function = 'max(1E2, 0.1 * t)'
  []
  end_time = 4E11
[]

[GlobalParams]
  point = '0 0 0'
[]

[Postprocessors]
  [cm3_Albite]
    type = PointValue
    variable = 'free_cm3_Albite'
  []
  [cm3_Anhydrite]
    type = PointValue
    variable = 'free_cm3_Anhydrite'
  []
  [cm3_Anorthite]
    type = PointValue
    variable = 'free_cm3_Anorthite'
  []
  [cm3_Calcite]
    type = PointValue
    variable = 'free_cm3_Calcite'
  []
  [cm3_Chalcedony]
    type = PointValue
    variable = 'free_cm3_Chalcedony'
  []
  [cm3_Clinochl-7A]
    type = PointValue
    variable = 'free_cm3_Clinochl-7A'
  []
  [cm3_Illite]
    type = PointValue
    variable = 'free_cm3_Illite'
  []
  [cm3_K-feldspar]
    type = PointValue
    variable = 'free_cm3_K-feldspar'
  []
  [cm3_Kaolinite]
    type = PointValue
    variable = 'free_cm3_Kaolinite'
  []
  [cm3_Quartz]
    type = PointValue
    variable = 'free_cm3_Quartz'
  []
  [cm3_Paragonite]
    type = PointValue
    variable = 'free_cm3_Paragonite'
  []
  [cm3_Phlogopite]
    type = PointValue
    variable = 'free_cm3_Phlogopite'
  []
  [cm3_Zoisite]
    type = PointValue
    variable = 'free_cm3_Zoisite'
  []
  [cm3_Laumontite]
    type = PointValue
    variable = 'free_cm3_Laumontite'
  []
  [cm3_mineral]
    type = LinearCombinationPostprocessor
    pp_names = 'cm3_Albite cm3_Anhydrite cm3_Anorthite cm3_Calcite cm3_Chalcedony cm3_Clinochl-7A cm3_Illite cm3_K-feldspar cm3_Kaolinite cm3_Quartz cm3_Paragonite cm3_Phlogopite cm3_Zoisite cm3_Laumontite'
    pp_coefs = '1 1 1 1 1 1 1 1 1 1 1 1 1 1'
  []
  [pH]
    type = PointValue
    variable = 'pH'
  []
  [kg_solvent_H2O]
    type = PointValue
    variable = 'kg_solvent_H2O'
  []
[]

[Outputs]
  csv = true
[]

(modules/combined/examples/geochem-porous_flow/forge/porous_flow.i)

# Input file modified from RobPodgorney version
# - 2D instead of 3D with different resolution.  Effectively this means a 1m height of RobPodgorney aquifer is simulated.  RobPodgorney total mass flux is 2.5kg/s meaning 0.25kg/s is appropriate here
# - Celsius instead of Kelvin
# - no use of PorousFlowPointEnthalpySourceFromPostprocessor since that is not yet merged into MOOSE: a DirichletBC is used instead
# - Use of PorousFlowFullySaturated instead of PorousFlowUnsaturated, and the save_component_rate_in feature to record the change in kg of each species at each node for passing to the Geochem simulation
# - MultiApps and Transfers to transfer information between this simulation and the aquifer_geochemistry.i simulation
[Mesh]
  [gen]
    type = GeneratedMeshGenerator
    dim = 2
    nx = 225
    ny = 200
    xmin = -400
    xmax = 500
    ymin = -400
    ymax = 400
  []
  [injection_node]
    input = gen
    type = ExtraNodesetGenerator
    new_boundary = injection_node
    coord = '0 0 0'
  []
[]

[GlobalParams]
  PorousFlowDictator = dictator
  gravity = '0 0 0'
[]

[Variables]
  [f_H]
    initial_condition = 8.201229858451E-07
  []
  [f_Na]
    initial_condition = 2.281094143525E-03
  []
  [f_K]
    initial_condition = 2.305489507836E-04
  []
  [f_Ca]
    initial_condition = 5.818776782059E-04
  []
  [f_Mg]
    initial_condition = 1.539513498238E-07
  []
  [f_SiO2]
    initial_condition = 2.691822196469E-04
  []
  [f_Al]
    initial_condition = 4.457519474122E-08
  []
  [f_Cl]
    initial_condition = 4.744309776594E-03
  []
  [f_SO4]
    initial_condition = 9.516650880811E-06
  []
  [f_HCO3]
    initial_condition = 5.906126982324E-05
  []
  [porepressure]
    initial_condition = 20E6
  []
  [temperature]
    initial_condition = 220 # degC
    scaling = 1E-6 # fluid enthalpy is roughly 1E6
  []
[]

[BCs]
  [source_temperature]
    type = DirichletBC
    boundary = injection_node
    variable = temperature
    value = 70 # degC
  []
[]

[DiracKernels]
  [inject_H]
    type = PorousFlowPointSourceFromPostprocessor
    point = ' 0 0 0'
    mass_flux = 4.790385871045E-08
    variable = f_H
  []
  [inject_Na]
    type = PorousFlowPointSourceFromPostprocessor
    point = ' 0 0 0'
    mass_flux = 7.586252963780E-07
    variable = f_Na
  []
  [inject_K]
    type = PorousFlowPointSourceFromPostprocessor
    point = ' 0 0 0'
    mass_flux = 2.746517625125E-07
    variable = f_K
  []
  [inject_Ca]
    type = PorousFlowPointSourceFromPostprocessor
    point = ' 0 0 0'
    mass_flux = 7.775129478597E-07
    variable = f_Ca
  []
  [inject_Mg]
    type = PorousFlowPointSourceFromPostprocessor
    point = ' 0 0 0'
    mass_flux = 1.749872109005E-07
    variable = f_Mg
  []
  [inject_SiO2]
    type = PorousFlowPointSourceFromPostprocessor
    point = ' 0 0 0'
    mass_flux = 4.100547515915E-06
    variable = f_SiO2
  []
  [inject_Al]
    type = PorousFlowPointSourceFromPostprocessor
    point = ' 0 0 0'
    mass_flux = 2.502408592080E-08
    variable = f_Al
  []
  [inject_Cl]
    type = PorousFlowPointSourceFromPostprocessor
    point = ' 0 0 0'
    mass_flux = 1.997260386272E-06
    variable = f_Cl
  []
  [inject_SO4]
    type = PorousFlowPointSourceFromPostprocessor
    point = ' 0 0 0'
    mass_flux = 2.497372164191E-07
    variable = f_SO4
  []
  [inject_HCO3]
    type = PorousFlowPointSourceFromPostprocessor
    point = ' 0 0 0'
    mass_flux = 5.003150992902E-06
    variable = f_HCO3
  []
  [inject_H2O]
    type = PorousFlowPointSourceFromPostprocessor
    point = ' 0 0 0'
    mass_flux = 2.499865905987E-01
    variable = porepressure
  []

  [produce_H]
    type = PorousFlowPeacemanBorehole
    variable = f_H
    SumQuantityUO = produced_mass_H
    mass_fraction_component = 0
    point_file = production.bh
    line_length = 1
    bottom_p_or_t = 20E6
    unit_weight = '0 0 0'
    use_mobility = true
    character = 1
  []
  [produce_Na]
    type = PorousFlowPeacemanBorehole
    variable = f_Na
    SumQuantityUO = produced_mass_Na
    mass_fraction_component = 1
    point_file = production.bh
    line_length = 1
    bottom_p_or_t = 20E6
    unit_weight = '0 0 0'
    use_mobility = true
    character = 1
  []
  [produce_K]
    type = PorousFlowPeacemanBorehole
    variable = f_K
    SumQuantityUO = produced_mass_K
    mass_fraction_component = 2
    point_file = production.bh
    line_length = 1
    bottom_p_or_t = 20E6
    unit_weight = '0 0 0'
    use_mobility = true
    character = 1
  []
  [produce_Ca]
    type = PorousFlowPeacemanBorehole
    variable = f_Ca
    SumQuantityUO = produced_mass_Ca
    mass_fraction_component = 3
    point_file = production.bh
    line_length = 1
    bottom_p_or_t = 20E6
    unit_weight = '0 0 0'
    use_mobility = true
    character = 1
  []
  [produce_Mg]
    type = PorousFlowPeacemanBorehole
    variable = f_Mg
    SumQuantityUO = produced_mass_Mg
    mass_fraction_component = 4
    point_file = production.bh
    line_length = 1
    bottom_p_or_t = 20E6
    unit_weight = '0 0 0'
    use_mobility = true
    character = 1
  []
  [produce_SiO2]
    type = PorousFlowPeacemanBorehole
    variable = f_SiO2
    SumQuantityUO = produced_mass_SiO2
    mass_fraction_component = 5
    point_file = production.bh
    line_length = 1
    bottom_p_or_t = 20E6
    unit_weight = '0 0 0'
    use_mobility = true
    character = 1
  []
  [produce_Al]
    type = PorousFlowPeacemanBorehole
    variable = f_Al
    SumQuantityUO = produced_mass_Al
    mass_fraction_component = 6
    point_file = production.bh
    line_length = 1
    bottom_p_or_t = 20E6
    unit_weight = '0 0 0'
    use_mobility = true
    character = 1
  []
  [produce_Cl]
    type = PorousFlowPeacemanBorehole
    variable = f_Cl
    SumQuantityUO = produced_mass_Cl
    mass_fraction_component = 7
    point_file = production.bh
    line_length = 1
    bottom_p_or_t = 20E6
    unit_weight = '0 0 0'
    use_mobility = true
    character = 1
  []
  [produce_SO4]
    type = PorousFlowPeacemanBorehole
    variable = f_SO4
    SumQuantityUO = produced_mass_SO4
    mass_fraction_component = 8
    point_file = production.bh
    line_length = 1
    bottom_p_or_t = 20E6
    unit_weight = '0 0 0'
    use_mobility = true
    character = 1
  []
  [produce_HCO3]
    type = PorousFlowPeacemanBorehole
    variable = f_HCO3
    SumQuantityUO = produced_mass_HCO3
    mass_fraction_component = 9
    point_file = production.bh
    line_length = 1
    bottom_p_or_t = 20E6
    unit_weight = '0 0 0'
    use_mobility = true
    character = 1
  []
  [produce_H2O]
    type = PorousFlowPeacemanBorehole
    variable = porepressure
    SumQuantityUO = produced_mass_H2O
    mass_fraction_component = 10
    point_file = production.bh
    line_length = 1
    bottom_p_or_t = 20E6
    unit_weight = '0 0 0'
    use_mobility = true
    character = 1
  []
  [remove_heat_at_production_well]
    type = PorousFlowPeacemanBorehole
    variable = temperature
    SumQuantityUO = produced_heat
    point_file = production.bh
    line_length = 1
    bottom_p_or_t = 20E6
    unit_weight = '0 0 0'
    use_mobility = true
    use_enthalpy = true
    character = 1
  []
[]

[UserObjects]
  [produced_mass_H]
    type = PorousFlowSumQuantity
  []
  [produced_mass_Na]
    type = PorousFlowSumQuantity
  []
  [produced_mass_K]
    type = PorousFlowSumQuantity
  []
  [produced_mass_Ca]
    type = PorousFlowSumQuantity
  []
  [produced_mass_Mg]
    type = PorousFlowSumQuantity
  []
  [produced_mass_SiO2]
    type = PorousFlowSumQuantity
  []
  [produced_mass_Al]
    type = PorousFlowSumQuantity
  []
  [produced_mass_Cl]
    type = PorousFlowSumQuantity
  []
  [produced_mass_SO4]
    type = PorousFlowSumQuantity
  []
  [produced_mass_HCO3]
    type = PorousFlowSumQuantity
  []
  [produced_mass_H2O]
    type = PorousFlowSumQuantity
  []
  [produced_heat]
    type = PorousFlowSumQuantity
  []
[]

[Postprocessors]
  [heat_extracted]
    type = PorousFlowPlotQuantity
    uo = produced_heat
  []
  [approx_production_temperature]
    type = PointValue
    point = '100 0 0'
    variable = temperature
  []
  [mass_extracted_H]
    type = PorousFlowPlotQuantity
    uo = produced_mass_H
    execute_on = 'initial timestep_end'
  []
  [mass_extracted_Na]
    type = PorousFlowPlotQuantity
    uo = produced_mass_Na
    execute_on = 'initial timestep_end'
  []
  [mass_extracted_K]
    type = PorousFlowPlotQuantity
    uo = produced_mass_K
    execute_on = 'initial timestep_end'
  []
  [mass_extracted_Ca]
    type = PorousFlowPlotQuantity
    uo = produced_mass_Ca
    execute_on = 'initial timestep_end'
  []
  [mass_extracted_Mg]
    type = PorousFlowPlotQuantity
    uo = produced_mass_Mg
    execute_on = 'initial timestep_end'
  []
  [mass_extracted_SiO2]
    type = PorousFlowPlotQuantity
    uo = produced_mass_SiO2
    execute_on = 'initial timestep_end'
  []
  [mass_extracted_Al]
    type = PorousFlowPlotQuantity
    uo = produced_mass_Al
    execute_on = 'initial timestep_end'
  []
  [mass_extracted_Cl]
    type = PorousFlowPlotQuantity
    uo = produced_mass_Cl
    execute_on = 'initial timestep_end'
  []
  [mass_extracted_SO4]
    type = PorousFlowPlotQuantity
    uo = produced_mass_SO4
    execute_on = 'initial timestep_end'
  []
  [mass_extracted_HCO3]
    type = PorousFlowPlotQuantity
    uo = produced_mass_HCO3
    execute_on = 'initial timestep_end'
  []
  [mass_extracted_H2O]
    type = PorousFlowPlotQuantity
    uo = produced_mass_H2O
    execute_on = 'initial timestep_end'
  []
  [mass_extracted]
    type = LinearCombinationPostprocessor
    pp_names = 'mass_extracted_H mass_extracted_Na mass_extracted_K mass_extracted_Ca mass_extracted_Mg mass_extracted_SiO2 mass_extracted_Al mass_extracted_Cl mass_extracted_SO4 mass_extracted_HCO3 mass_extracted_H2O'
    pp_coefs = '1 1 1 1 1 1 1 1 1 1 1'
    execute_on = 'initial timestep_end'
  []
  [dt]
    type = TimestepSize
    execute_on = 'timestep_begin'
  []
[]

[Modules]
  [FluidProperties]
    [the_simple_fluid]
      type = SimpleFluidProperties
      thermal_expansion = 2E-4
      bulk_modulus = 2E9
      viscosity = 1E-3
      density0 = 980
      cv = 4000.0
      cp = 4000.0
      porepressure_coefficient = 0
    []
  []
[]

[PorousFlowFullySaturated]
  coupling_type = ThermoHydro
  porepressure = porepressure
  temperature = temperature
  mass_fraction_vars = 'f_H f_Na f_K f_Ca f_Mg f_SiO2 f_Al f_Cl f_SO4 f_HCO3'
  save_component_rate_in = 'rate_H rate_Na rate_K rate_Ca rate_Mg rate_SiO2 rate_Al rate_Cl rate_SO4 rate_HCO3 rate_H2O' # change in kg at every node / dt
  fp = the_simple_fluid
  temperature_unit = Celsius
[]

[AuxVariables]
  [rate_H]
  []
  [rate_Na]
  []
  [rate_K]
  []
  [rate_Ca]
  []
  [rate_Mg]
  []
  [rate_SiO2]
  []
  [rate_Al]
  []
  [rate_Cl]
  []
  [rate_SO4]
  []
  [rate_HCO3]
  []
  [rate_H2O]
  []
[]

[Materials]
  [porosity]
    type = PorousFlowPorosityConst
    porosity = 0.01
  []
  [permeability]
    type = PorousFlowPermeabilityConst
    permeability = '1E-14 0 0   0 1E-14 0   0 0 1E-14'
  []
  [thermal_conductivity]
    type = PorousFlowThermalConductivityIdeal
    dry_thermal_conductivity = '2.5 0 0  0 2.5 0  0 0 2.5'
  []
  [rock_heat]
    type = PorousFlowMatrixInternalEnergy
    density = 2750.0
    specific_heat_capacity = 900.0
  []
  [relperm] # this is necessary because of the use_mobility = true used in the PorousFlowPeacemanBorehole objects
    type = PorousFlowRelativePermeabilityConst
    at_nodes = true
    phase = 0
  []
[]

[Preconditioning]
  active = typically_efficient
  [typically_efficient]
    type = SMP
    full = true
    petsc_options_iname = '-pc_type -pc_hypre_type'
    petsc_options_value = ' hypre    boomeramg'
  []
  [strong]
    type = SMP
    full = true
    petsc_options = '-ksp_diagonal_scale -ksp_diagonal_scale_fix'
    petsc_options_iname = '-pc_type -sub_pc_type -sub_pc_factor_shift_type -pc_asm_overlap'
    petsc_options_value = ' asm      ilu           NONZERO                   2'
  []
  [probably_too_strong]
    type = SMP
    full = true
    petsc_options_iname = '-pc_type -pc_factor_mat_solver_package'
    petsc_options_value = ' lu       mumps'
  []
[]

[Executioner]
  type = Transient
  solve_type = Newton
  end_time = 31536000 #1 year

  [TimeStepper]
    type = SolutionTimeAdaptiveDT
    dt = 500
  []
[]

[Outputs]
  exodus = true
  csv = true
[]

[MultiApps]
  [react]
    type = TransientMultiApp
    input_files = aquifer_geochemistry.i
    clone_master_mesh = true
    execute_on = 'timestep_end'
  []
[]
[Transfers]
  [changes_due_to_flow]
    type = MultiAppCopyTransfer
    direction = to_multiapp
    source_variable = 'rate_H rate_Na rate_K rate_Ca rate_Mg rate_SiO2 rate_Al rate_Cl rate_SO4 rate_HCO3 rate_H2O temperature'
    variable = 'pf_rate_H pf_rate_Na pf_rate_K pf_rate_Ca pf_rate_Mg pf_rate_SiO2 pf_rate_Al pf_rate_Cl pf_rate_SO4 pf_rate_HCO3 pf_rate_H2O temperature'
    multi_app = react
  []
  [massfrac_from_geochem]
    type = MultiAppCopyTransfer
    direction = from_multiapp
    source_variable = 'massfrac_H massfrac_Na massfrac_K massfrac_Ca massfrac_Mg massfrac_SiO2 massfrac_Al massfrac_Cl massfrac_SO4 massfrac_HCO3'
    variable = 'f_H f_Na f_K f_Ca f_Mg f_SiO2 f_Al f_Cl f_SO4 f_HCO3'
    multi_app = react
  []
[]

Description
Example Syntax
Input Parameters
Input Files

Install MOOSE

New Users

Examples and Tutorials

Application Usage

Physics and Syntax

Application Development

Framework Development

MOOSEDocs

Infrastructure

Questions

Information and Tools

INL Applications and Remote Access