NitrogenFluidProperties

Fluid properties for Nitrogen (N2)

Fluid properties for nitrogen are mainly calculated using the Span et al. equation of state (Span et al., 2000). This formulation uses density and temperature as the primary variables with which to calculate properties such as density, enthalpy and internal energy.

When used with the pressure and temperature interface, which is the case in the Porous Flow module, nitrogen properties are typically calculated by first calculating density iteratively for a given pressure and temperature. This density is then used to calculate the other properties, such as internal energy, directly.

Viscosity and thermal conductivity are calculated using the formulation presented in Lemmon and Jacobsen (2004).

Dissolution of nitrogen into water is calculated using Henry's law (IAPWS, 2004).

Properties of nitrogen

Propertyvalue
Molar mass0.02801348 kg/mol
Critical temperature126.192 K
Critical pressure3.3958 MPa
Critical density313.3 kg/m
Triple point temperature63.151 K
Triple point pressure12.523 kPa

Range of validity

The NitrogenFluidProperties UserObject is valid for:

  • 63.151 K T 1000 K for p 2200 MPa

Input Parameters

  • T_initial_guess400Temperature initial guess for Newton Method variable set conversion

    Default:400

    C++ Type:double

    Unit:(no unit assumed)

    Controllable:No

    Description:Temperature initial guess for Newton Method variable set conversion

  • max_newton_its100Maximum number of Newton iterations for variable set conversions

    Default:100

    C++ Type:unsigned int

    Controllable:No

    Description:Maximum number of Newton iterations for variable set conversions

  • p_initial_guess200000Pressure initial guess for Newton Method variable set conversion

    Default:200000

    C++ Type:double

    Unit:(no unit assumed)

    Controllable:No

    Description:Pressure initial guess for Newton Method variable set conversion

  • tolerance1e-08Tolerance for 2D Newton variable set conversion

    Default:1e-08

    C++ Type:double

    Unit:(no unit assumed)

    Controllable:No

    Description:Tolerance for 2D Newton variable set conversion

Variable Set Conversions Newton Solve Parameters

  • allow_imperfect_jacobiansFalsetrue to allow unimplemented property derivative terms to be set to zero for the AD API

    Default:False

    C++ Type:bool

    Controllable:No

    Description:true to allow unimplemented property derivative terms to be set to zero for the AD API

  • control_tagsAdds user-defined labels for accessing object parameters via control logic.

    C++ Type:std::vector<std::string>

    Controllable:No

    Description:Adds user-defined labels for accessing object parameters via control logic.

  • enableTrueSet the enabled status of the MooseObject.

    Default:True

    C++ Type:bool

    Controllable:Yes

    Description:Set the enabled status of the MooseObject.

  • fp_typesingle-phase-fpType of the fluid property object

    Default:single-phase-fp

    C++ Type:FPType

    Controllable:No

    Description:Type of the fluid property object

Advanced Parameters

  • prop_getter_suffixAn optional suffix parameter that can be appended to any attempt to retrieve/get material properties. The suffix will be prepended with a '_' character.

    C++ Type:MaterialPropertyName

    Unit:(no unit assumed)

    Controllable:No

    Description:An optional suffix parameter that can be appended to any attempt to retrieve/get material properties. The suffix will be prepended with a '_' character.

  • use_interpolated_stateFalseFor the old and older state use projected material properties interpolated at the quadrature points. To set up projection use the ProjectedStatefulMaterialStorageAction.

    Default:False

    C++ Type:bool

    Controllable:No

    Description:For the old and older state use projected material properties interpolated at the quadrature points. To set up projection use the ProjectedStatefulMaterialStorageAction.

Material Property Retrieval Parameters

References

  1. IAPWS. Guidelines on the Henry's constant and vapour liquid distribution constant for gases in H$_2$O and D$_2$O at high temperatures. Technical Report, IAPWS, 2004.[BibTeX]
  2. Eric W Lemmon and RT Jacobsen. Viscosity and thermal conductivity equations for nitrogen, oxygen, argon, and air. International journal of thermophysics, 25(1):21–69, 2004.[BibTeX]
  3. Roland Span, Eric W Lemmon, Richard T Jacobsen, Wolfgang Wagner, and Akimichi Yokozeki. A reference equation of state for the thermodynamic properties of nitrogen for temperatures from 63.151 to 1000 k and pressures to 2200 mpa. J. Phys. Chem. Ref. Data, 29(6):1361–1433, 2000.[BibTeX]