CO2FluidProperties

Fluid properties for carbon dioxide (CO2) using the Span & Wagner EOS

Fluid properties for CO $var element = document.getElementById("moose-equation-89aefad3-bdd3-405c-bb15-c7e7f0fc890b");katex.render("_2", element, {displayMode:false,throwOnError:false,macros:{"\\eqc":"\\,,","\\eqp":"\\,.","\\pd":"\\frac{\\partial #1}{\\partial #2}","\\pr":"\\left(#1\\right)","\\ddt":"\\frac{d #1}{d t}"}});$ are mainly calculated using the Span and Wagner equation of state (Span and Wagner, 1996). This formulation uses density and temperature as the primary variables with which to calculate properties such as density, enthalpy and internal energy. However, the Fluid Properties module uses pressure and temperature in its interface, which is suitable for use in the Porous Flow module. As a result, CO $var element = document.getElementById("moose-equation-90a476ed-4a0d-4b52-9a2a-951f79d649c6");katex.render("_2", element, {displayMode:false,throwOnError:false,macros:{"\\eqc":"\\,,","\\eqp":"\\,.","\\pd":"\\frac{\\partial #1}{\\partial #2}","\\pr":"\\left(#1\\right)","\\ddt":"\\frac{d #1}{d t}"}});$ properties are typically calculated by first calculating density iteratively for a given pressure and temperature. This density is then used to calculate the other properties, such as internal energy, directly.

Viscosity is calculated using the formulation presented in Fenghour et al. (1998), while thermal conductivity is taken from Scalabrin et al. (2006).

Dissolution of CO $var element = document.getElementById("moose-equation-c10b7252-8801-48e8-9779-76ae668b0751");katex.render("_2", element, {displayMode:false,throwOnError:false,macros:{"\\eqc":"\\,,","\\eqp":"\\,.","\\pd":"\\frac{\\partial #1}{\\partial #2}","\\pr":"\\left(#1\\right)","\\ddt":"\\frac{d #1}{d t}"}});$ into water is calculated using Henry's law (IAPWS, 2004).

Properties of CO $var element = document.getElementById("moose-equation-32f59c47-1162-4490-b613-99522aeca9f4");katex.render("_2", element, {displayMode:false,throwOnError:false,macros:{"\\eqc":"\\,,","\\eqp":"\\,.","\\pd":"\\frac{\\partial #1}{\\partial #2}","\\pr":"\\left(#1\\right)","\\ddt":"\\frac{d #1}{d t}"}});$

Property	value
Molar mass	0.0440098 kg/mol
Critical temperature	304.1282 K
Critical pressure	7.3773 MPa
Critical density	467.6 kg/m $var element = document.getElementById("moose-equation-a810c51e-2d62-49c3-bb69-d3a0a294d7b3");katex.render("^3", element, {displayMode:false,throwOnError:false,macros:{"\\eqc":"\\,,","\\eqp":"\\,.","\\pd":"\\frac{\\partial #1}{\\partial #2}","\\pr":"\\left(#1\\right)","\\ddt":"\\frac{d #1}{d t}"}});$
Triple point temperature	216.592 K
Triple point pressure	0.51795 MPa

Range of validity

The CO2FluidProperties UserObject is valid for:

216.592 K $var element = document.getElementById("moose-equation-99ec1a26-7c25-4d46-86fc-c011b86e1d78");katex.render("\\le", element, {displayMode:false,throwOnError:false,macros:{"\\eqc":"\\,,","\\eqp":"\\,.","\\pd":"\\frac{\\partial #1}{\\partial #2}","\\pr":"\\left(#1\\right)","\\ddt":"\\frac{d #1}{d t}"}});$ T $var element = document.getElementById("moose-equation-0e4fcd10-2202-4c4e-be6b-e15895d1dfdf");katex.render("\\le", element, {displayMode:false,throwOnError:false,macros:{"\\eqc":"\\,,","\\eqp":"\\,.","\\pd":"\\frac{\\partial #1}{\\partial #2}","\\pr":"\\left(#1\\right)","\\ddt":"\\frac{d #1}{d t}"}});$ 1100 K for p $var element = document.getElementById("moose-equation-e803e8e7-d2a0-43d0-aa43-bd793f53c367");katex.render("\\le", element, {displayMode:false,throwOnError:false,macros:{"\\eqc":"\\,,","\\eqp":"\\,.","\\pd":"\\frac{\\partial #1}{\\partial #2}","\\pr":"\\left(#1\\right)","\\ddt":"\\frac{d #1}{d t}"}});$ 800 MPa

Input Parameters

T_initial_guess400Temperature initial guess for Newton Method variable set conversion
Default:400
C++ Type:double
Unit:(no unit assumed)
Controllable:No
Description:Temperature initial guess for Newton Method variable set conversion
max_newton_its100Maximum number of Newton iterations for variable set conversions
Default:100
C++ Type:unsigned int
Controllable:No
Description:Maximum number of Newton iterations for variable set conversions
p_initial_guess200000Pressure initial guess for Newton Method variable set conversion
Default:200000
C++ Type:double
Unit:(no unit assumed)
Controllable:No
Description:Pressure initial guess for Newton Method variable set conversion
tolerance1e-08Tolerance for 2D Newton variable set conversion
Default:1e-08
C++ Type:double
Unit:(no unit assumed)
Controllable:No
Description:Tolerance for 2D Newton variable set conversion

Variable Set Conversions Newton Solve Parameters

allow_imperfect_jacobiansFalsetrue to allow unimplemented property derivative terms to be set to zero for the AD API
Default:False
C++ Type:bool
Controllable:No
Description:true to allow unimplemented property derivative terms to be set to zero for the AD API
control_tagsAdds user-defined labels for accessing object parameters via control logic.
C++ Type:std::vector<std::string>
Controllable:No
Description:Adds user-defined labels for accessing object parameters via control logic.
enableTrueSet the enabled status of the MooseObject.
Default:True
C++ Type:bool
Controllable:Yes
Description:Set the enabled status of the MooseObject.
fp_typesingle-phase-fpType of the fluid property object
Default:single-phase-fp
C++ Type:FPType
Controllable:No
Description:Type of the fluid property object

Advanced Parameters

prop_getter_suffixAn optional suffix parameter that can be appended to any attempt to retrieve/get material properties. The suffix will be prepended with a '_' character.
C++ Type:MaterialPropertyName
Unit:(no unit assumed)
Controllable:No
Description:An optional suffix parameter that can be appended to any attempt to retrieve/get material properties. The suffix will be prepended with a '_' character.
use_interpolated_stateFalseFor the old and older state use projected material properties interpolated at the quadrature points. To set up projection use the ProjectedStatefulMaterialStorageAction.
Default:False
C++ Type:bool
Controllable:No
Description:For the old and older state use projected material properties interpolated at the quadrature points. To set up projection use the ProjectedStatefulMaterialStorageAction.

Material Property Retrieval Parameters

Input Files

(modules/porous_flow/test/tests/fluidstate/waterncg_ic.i)
(modules/porous_flow/test/tests/jacobian/waterncg_twophase.i)
(modules/porous_flow/test/tests/fluidstate/theis.i)
(modules/porous_flow/test/tests/fluidstate/brineco2_2.i)
(modules/porous_flow/test/tests/fluidstate/theis_tabulated.i)
(modules/porous_flow/test/tests/jacobian/brineco2_gas.i)
(modules/porous_flow/examples/co2_intercomparison/1Dradial/1Dradial.i)
(modules/porous_flow/test/tests/fluidstate/waterncg.i)
(modules/porous_flow/test/tests/fluidstate/theis_brineco2_nonisothermal.i)
(modules/porous_flow/test/tests/fluidstate/brineco2_nonisothermal.i)
(modules/porous_flow/test/tests/fluidstate/brineco2_ic.i)
(modules/porous_flow/test/tests/sinks/injection_production_eg.i)
(modules/porous_flow/test/tests/recover/theis.i)
(modules/porous_flow/test/tests/fluidstate/brineco2.i)
(modules/porous_flow/test/tests/jacobian/waterncg_gas.i)
(modules/porous_flow/test/tests/jacobian/waterncg_liquid.i)
(modules/porous_flow/test/tests/fluidstate/brineco2_hightemp.i)
(modules/porous_flow/test/tests/jacobian/brineco2_twophase.i)
(modules/porous_flow/test/tests/jacobian/brineco2_liquid.i)
(modules/porous_flow/examples/co2_intercomparison/1Dradial/properties.i)
(modules/porous_flow/test/tests/jacobian/brineco2_twophase_nonisothermal.i)
(modules/porous_flow/test/tests/jacobian/brineco2_liquid_2.i)
(modules/porous_flow/test/tests/fluidstate/waterncg_nonisothermal.i)
(modules/fluid_properties/test/tests/co2/co2.i)
(modules/porous_flow/test/tests/fluidstate/theis_brineco2.i)
(modules/porous_flow/test/tests/jacobian/waterncg_twophase_nonisothermal.i)
(modules/porous_flow/test/tests/fluidstate/brineco2_fv.i)
(modules/porous_flow/examples/tutorial/11.i)
(modules/porous_flow/examples/fluidflower/fluidflower.i)
(modules/fluid_properties/test/tests/tabulated/tabulated.i)
(modules/porous_flow/test/tests/fluids/co2.i)
(modules/porous_flow/test/tests/sinks/injection_production_eg_outflowBC.i)
(modules/porous_flow/examples/tutorial/11_2D.i)
(modules/porous_flow/examples/lava_lamp/1phase_convection.i)
(modules/porous_flow/examples/lava_lamp/2phase_convection.i)

References

A. Fenghour, W. A. Wakeham, and V. Vesovic. The viscosity of carbon dioxide. J. Phys. Chem. Ref. Data, 27:31–44, 1998.

@article{fenghour1998,
    author = "Fenghour, A. and Wakeham, W. A. and Vesovic, V.",
    title = "The viscosity of carbon dioxide",
    journal = "J. Phys. Chem. Ref. Data",
    volume = "27",
    pages = "31--44",
    year = "1998"
}

IAPWS. Guidelines on the Henry's constant and vapour liquid distribution constant for gases in H$_2$O and D$_2$O at high temperatures. Technical Report, IAPWS, 2004.

@techreport{iapws2004,
    author = "IAPWS",
    title = "{Guidelines on the Henry's constant and vapour liquid distribution constant for gases in H$\_2$O and D$\_2$O at high temperatures}",
    institution = "IAPWS",
    year = "2004"
}

G. Scalabrin, P. Marchi, F. Finezzo, and R. Span. A reference multiparameter thermal conductivity equation for carbon dioxide with an optimized functional form. J. Phys. Chem. Ref. Data, 35:1549–1575, 2006.

@article{scalabrin2006,
    author = "Scalabrin, G. and Marchi, P. and Finezzo, F. and Span, R.",
    title = "A Reference Multiparameter Thermal Conductivity Equation for Carbon Dioxide with an Optimized Functional Form",
    journal = "J. Phys. Chem. Ref. Data",
    volume = "35",
    pages = "1549--1575",
    year = "2006"
}

R. Span and W. Wagner. A new equation of state for carbon dioxide covering the fluid region from the triple-point temperature to 1100 K at pressures up to 800 MPa. J. Phys. Chem. Ref. Data, 25:1509–1596, 1996.

@article{spanwagner1996,
    author = "Span, R. and Wagner, W.",
    title = "{A new equation of state for carbon dioxide covering the fluid region from the triple-point temperature to 1100 K at pressures up to 800 MPa}",
    journal = "J. Phys. Chem. Ref. Data",
    volume = "25",
    pages = "1509--1596",
    year = "1996"
}

(modules/porous_flow/test/tests/fluidstate/waterncg_ic.i)

# Tests correct calculation of z (total mass fraction of NCG summed over all
# phases) using the PorousFlowFluidStateIC initial condition. Once z is
# calculated by the initial condition, the thermophysical properties are calculated
# and the resulting gas saturation should be equal to that given in the intial condition

[Mesh]
  type = GeneratedMesh
  dim = 2
[]

[GlobalParams]
  PorousFlowDictator = dictator
  temperature_unit = Celsius
[]

[Variables]
  [pgas]
    initial_condition = 1e6
  []
  [z]
  []
[]

[ICs]
  [z]
    type = PorousFlowFluidStateIC
    saturation = 0.5
    gas_porepressure = pgas
    temperature = 50
    variable = z
    fluid_state = fs
  []
[]

[AuxVariables]
  [saturation_gas]
    order = CONSTANT
    family = MONOMIAL
  []
  [saturation_water]
    order = CONSTANT
    family = MONOMIAL
  []
[]

[AuxKernels]
  [saturation_water]
    type = PorousFlowPropertyAux
    variable = saturation_water
    property = saturation
    phase = 0
    execute_on = timestep_end
  []
  [saturation_gas]
    type = PorousFlowPropertyAux
    variable = saturation_gas
    property = saturation
    phase = 1
    execute_on = timestep_end
  []
[]

[Kernels]
  [mass0]
    type = PorousFlowMassTimeDerivative
    variable = pgas
    fluid_component = 0
  []
  [mass1]
    type = PorousFlowMassTimeDerivative
    variable = z
    fluid_component = 1
  []
[]

[UserObjects]
  [dictator]
    type = PorousFlowDictator
    porous_flow_vars = 'pgas z'
    number_fluid_phases = 2
    number_fluid_components = 2
  []
  [pc]
    type = PorousFlowCapillaryPressureConst
    pc = 0
  []
  [fs]
    type = PorousFlowWaterNCG
    water_fp = water
    gas_fp = co2
    capillary_pressure = pc
  []
[]

[FluidProperties]
  [co2]
    type = CO2FluidProperties
  []
  [water]
    type = Water97FluidProperties
  []
[]

[Materials]
  [temperature]
    type = PorousFlowTemperature
    temperature = 50
  []
  [waterncg]
    type = PorousFlowFluidState
    gas_porepressure = pgas
    z = z
    fluid_state = fs
    capillary_pressure = pc
  []
  [permeability]
    type = PorousFlowPermeabilityConst
    permeability = '1e-12 0 0 0 1e-12 0 0 0 1e-12'
  []
  [relperm0]
    type = PorousFlowRelativePermeabilityCorey
    n = 2
    phase = 0
  []
  [relperm1]
    type = PorousFlowRelativePermeabilityCorey
    n = 3
    phase = 1
  []
  [porosity]
    type = PorousFlowPorosityConst
    porosity = 0.1
  []
[]

[Executioner]
  type = Transient
  solve_type = NEWTON
  dt = 1
  end_time = 1
  nl_abs_tol = 1e-12
[]

[Preconditioning]
  [smp]
    type = SMP
    full = true
  []
[]

[Postprocessors]
  [sg]
    type = ElementIntegralVariablePostprocessor
    variable = saturation_gas
    execute_on = 'initial timestep_end'
  []
  [sw]
    type = ElementIntegralVariablePostprocessor
    variable = saturation_water
    execute_on = 'initial timestep_end'
  []
  [z]
    type = ElementIntegralVariablePostprocessor
    variable = z
    execute_on = 'initial timestep_end'
  []
[]

[Outputs]
  csv = true
[]

(modules/porous_flow/test/tests/jacobian/waterncg_twophase.i)

# Tests correct calculation of properties derivatives in PorousFlowWaterNCG
# for conditions for two phases

[Mesh]
  type = GeneratedMesh
  dim = 2
  nx = 2
  ny = 2
[]

[GlobalParams]
  PorousFlowDictator = dictator
  gravity = '0 0 0'
[]

[Variables]
  [pgas]
  []
  [z]
  []
[]

[ICs]
  [pgas]
    type = RandomIC
    min = 1e5
    max = 5e5
    variable = pgas
  []
  [z]
    type = RandomIC
    min = 0.01
    max = 0.06
    variable = z
  []
[]

[Kernels]
  [mass0]
    type = PorousFlowMassTimeDerivative
    variable = pgas
    fluid_component = 0
  []
  [mass1]
    type = PorousFlowMassTimeDerivative
    variable = z
    fluid_component = 1
  []
  [adv0]
    type = PorousFlowAdvectiveFlux
    variable = pgas
    fluid_component = 0
  []
  [adv1]
    type = PorousFlowAdvectiveFlux
    variable = z
    fluid_component = 1
  []
[]

[UserObjects]
  [dictator]
    type = PorousFlowDictator
    porous_flow_vars = 'pgas z'
    number_fluid_phases = 2
    number_fluid_components = 2
  []
  [pc]
    type = PorousFlowCapillaryPressureVG
    m = 0.5
    alpha = 1e1
    pc_max = 1e4
  []
  [fs]
    type = PorousFlowWaterNCG
    water_fp = water
    gas_fp = co2
    capillary_pressure = pc
  []
[]

[FluidProperties]
  [co2]
    type = CO2FluidProperties
  []
  [water]
    type = Water97FluidProperties
  []
[]

[Materials]
  [temperature]
    type = PorousFlowTemperature
    temperature = 50
  []
  [waterncg]
    type = PorousFlowFluidState
    gas_porepressure = pgas
    z = z
    temperature_unit = Celsius
    capillary_pressure = pc
    fluid_state = fs
  []
  [permeability]
    type = PorousFlowPermeabilityConst
    permeability = '1e-12 0 0 0 1e-12 0 0 0 1e-12'
  []
  [relperm0]
    type = PorousFlowRelativePermeabilityCorey
    n = 2
    phase = 0
  []
  [relperm1]
    type = PorousFlowRelativePermeabilityCorey
    n = 2
    phase = 1
  []
  [porosity]
    type = PorousFlowPorosityConst
    porosity = 0.1
  []
[]

[Executioner]
  type = Transient
  solve_type = NEWTON
  dt = 1
  end_time = 1
  nl_abs_tol = 1e-12
[]

[Preconditioning]
  [smp]
    type = SMP
    full = true
  []
[]

[AuxVariables]
  [sgas]
    family = MONOMIAL
    order = CONSTANT
  []
[]

[AuxKernels]
  [sgas]
    type = PorousFlowPropertyAux
    property = saturation
    phase = 1
    variable = sgas
  []
[]

[Postprocessors]
  [sgas_min]
    type = ElementExtremeValue
    variable = sgas
    value_type = min
  []
  [sgas_max]
    type = ElementExtremeValue
    variable = sgas
    value_type = max
  []
[]

(modules/porous_flow/test/tests/fluidstate/theis.i)

# Two phase Theis problem: Flow from single source using WaterNCG fluidstate.
# Constant rate injection 2 kg/s
# 1D cylindrical mesh
# Initially, system has only a liquid phase, until enough gas is injected
# to form a gas phase, in which case the system becomes two phase.

[Mesh]
  type = GeneratedMesh
  dim = 1
  nx = 40
  xmax = 200
  bias_x = 1.05
  coord_type = RZ
  rz_coord_axis = Y
[]

[GlobalParams]
  PorousFlowDictator = dictator
  gravity = '0 0 0'
[]

[AuxVariables]
  [saturation_gas]
    order = CONSTANT
    family = MONOMIAL
  []
  [x1]
    order = CONSTANT
    family = MONOMIAL
  []
  [y0]
    order = CONSTANT
    family = MONOMIAL
  []
[]

[AuxKernels]
  [saturation_gas]
    type = PorousFlowPropertyAux
    variable = saturation_gas
    property = saturation
    phase = 1
    execute_on = timestep_end
  []
  [x1]
    type = PorousFlowPropertyAux
    variable = x1
    property = mass_fraction
    phase = 0
    fluid_component = 1
    execute_on = timestep_end
  []
  [y0]
    type = PorousFlowPropertyAux
    variable = y0
    property = mass_fraction
    phase = 1
    fluid_component = 0
    execute_on = timestep_end
  []
[]

[Variables]
  [pgas]
    initial_condition = 20e6
  []
  [zi]
    initial_condition = 0
  []
[]

[Kernels]
  [mass0]
    type = PorousFlowMassTimeDerivative
    fluid_component = 0
    variable = pgas
  []
  [flux0]
    type = PorousFlowAdvectiveFlux
    fluid_component = 0
    variable = pgas
  []
  [mass1]
    type = PorousFlowMassTimeDerivative
    fluid_component = 1
    variable = zi
  []
  [flux1]
    type = PorousFlowAdvectiveFlux
    fluid_component = 1
    variable = zi
  []
[]

[UserObjects]
  [dictator]
    type = PorousFlowDictator
    porous_flow_vars = 'pgas zi'
    number_fluid_phases = 2
    number_fluid_components = 2
  []
  [pc]
    type = PorousFlowCapillaryPressureConst
    pc = 0
  []
  [fs]
    type = PorousFlowWaterNCG
    water_fp = water
    gas_fp = co2
    capillary_pressure = pc
  []
[]

[FluidProperties]
  [co2]
    type = CO2FluidProperties
  []
  [water]
    type = Water97FluidProperties
  []
[]

[Materials]
  [temperature]
    type = PorousFlowTemperature
    temperature = 20
  []
  [waterncg]
    type = PorousFlowFluidState
    gas_porepressure = pgas
    z = zi
    temperature_unit = Celsius
    capillary_pressure = pc
    fluid_state = fs
  []
  [porosity]
    type = PorousFlowPorosityConst
    porosity = 0.2
  []
  [permeability]
    type = PorousFlowPermeabilityConst
    permeability = '1e-12 0 0 0 1e-12 0 0 0 1e-12'
  []
  [relperm_water]
    type = PorousFlowRelativePermeabilityCorey
    n = 2
    phase = 0
    s_res = 0.1
    sum_s_res = 0.1
  []
  [relperm_gas]
    type = PorousFlowRelativePermeabilityCorey
    n = 2
    phase = 1
  []
[]

[BCs]
  [rightwater]
    type = DirichletBC
    boundary = right
    value = 20e6
    variable = pgas
  []
[]

[DiracKernels]
  [source]
    type = PorousFlowSquarePulsePointSource
    point = '0 0 0'
    mass_flux = 2
    variable = zi
  []
[]

[Preconditioning]
  [smp]
    type = SMP
    full = true
    petsc_options = '-snes_converged_reason -ksp_diagonal_scale -ksp_diagonal_scale_fix -ksp_gmres_modifiedgramschmidt -snes_linesearch_monitor'
    petsc_options_iname = '-ksp_type -pc_type -sub_pc_type -sub_pc_factor_shift_type -pc_asm_overlap -snes_atol -snes_rtol -snes_max_it'
    petsc_options_value = 'gmres      asm      lu           NONZERO                   2               1E-8       1E-10 20'
  []
[]

[Executioner]
  type = Transient
  solve_type = NEWTON
  end_time = 2e2
  [TimeStepper]
    type = IterationAdaptiveDT
    dt = 10
    growth_factor = 2
  []
[]

[VectorPostprocessors]
  [line]
    type = NodalValueSampler
    sort_by = x
    variable = 'pgas zi'
    execute_on = 'timestep_end'
  []
[]

[Postprocessors]
  [pgas]
    type = PointValue
    point = '1 0 0'
    variable = pgas
  []
  [sgas]
    type = PointValue
    point = '1 0 0'
    variable = saturation_gas
  []
  [zi]
    type = PointValue
    point = '1 0 0'
    variable = zi
  []
  [massgas]
    type = PorousFlowFluidMass
    fluid_component = 1
  []
  [x1]
    type = PointValue
    point = '1 0 0'
    variable = x1
  []
  [y0]
    type = PointValue
    point = '1 0 0'
    variable = y0
  []
[]

[Outputs]
  print_linear_residuals = false
  perf_graph = true
  [csvout]
    type = CSV
    execute_on = timestep_end
    execute_vector_postprocessors_on = final
  []
[]

(modules/porous_flow/test/tests/fluidstate/brineco2_2.i)

# Injection of supercritical CO2 into a single brine saturated cell. The CO2 initially fully
# dissolves into the brine, increasing its density slightly. After a few time steps,
# the brine is saturated with CO2, and subsequently a supercritical gas phase of CO2 saturated
# with a small amount of H2O is formed. Salt is included as a nonlinear variable.

[Mesh]
  type = GeneratedMesh
  dim = 2
[]

[GlobalParams]
  PorousFlowDictator = dictator
  temperature = 30
[]

[Variables]
  [pgas]
    initial_condition = 20e6
  []
  [z]
  []
  [xnacl]
    initial_condition = 0.1
  []
[]

[DiracKernels]
  [source]
    type = PorousFlowSquarePulsePointSource
    variable = z
    point = '0.5 0.5 0'
    mass_flux = 2
  []
[]

[BCs]
  [left]
    type = DirichletBC
    value = 20e6
    variable = pgas
    boundary = left
  []
  [right]
    type = DirichletBC
    value = 20e6
    variable = pgas
    boundary = right
  []
[]

[AuxVariables]
  [pressure_gas]
    order = CONSTANT
    family = MONOMIAL
  []
  [pressure_water]
    order = CONSTANT
    family = MONOMIAL
  []
  [saturation_gas]
    order = CONSTANT
    family = MONOMIAL
  []
  [saturation_water]
    order = CONSTANT
    family = MONOMIAL
  []
  [density_water]
    order = CONSTANT
    family = MONOMIAL
  []
  [density_gas]
    order = CONSTANT
    family = MONOMIAL
  []
  [viscosity_water]
    order = CONSTANT
    family = MONOMIAL
  []
  [viscosity_gas]
    order = CONSTANT
    family = MONOMIAL
  []
  [x0_water]
    order = CONSTANT
    family = MONOMIAL
  []
  [x0_gas]
    order = CONSTANT
    family = MONOMIAL
  []
  [x1_water]
    order = CONSTANT
    family = MONOMIAL
  []
  [x1_gas]
    order = CONSTANT
    family = MONOMIAL
  []
[]

[AuxKernels]
  [pressure_water]
    type = PorousFlowPropertyAux
    variable = pressure_water
    property = pressure
    phase = 0
    execute_on = 'initial timestep_end'
  []
  [pressure_gas]
    type = PorousFlowPropertyAux
    variable = pressure_gas
    property = pressure
    phase = 1
    execute_on = 'initial timestep_end'
  []
  [saturation_water]
    type = PorousFlowPropertyAux
    variable = saturation_water
    property = saturation
    phase = 0
    execute_on = 'initial timestep_end'
  []
  [saturation_gas]
    type = PorousFlowPropertyAux
    variable = saturation_gas
    property = saturation
    phase = 1
    execute_on = 'initial timestep_end'
  []
  [density_water]
    type = PorousFlowPropertyAux
    variable = density_water
    property = density
    phase = 0
    execute_on = 'initial timestep_end'
  []
  [density_gas]
    type = PorousFlowPropertyAux
    variable = density_gas
    property = density
    phase = 1
    execute_on = 'initial timestep_end'
  []
  [viscosity_water]
    type = PorousFlowPropertyAux
    variable = viscosity_water
    property = viscosity
    phase = 0
    execute_on = 'initial timestep_end'
  []
  [viscosity_gas]
    type = PorousFlowPropertyAux
    variable = viscosity_gas
    property = viscosity
    phase = 1
    execute_on = 'initial timestep_end'
  []
  [x1_water]
    type = PorousFlowPropertyAux
    variable = x1_water
    property = mass_fraction
    phase = 0
    fluid_component = 1
    execute_on = 'initial timestep_end'
  []
  [x1_gas]
    type = PorousFlowPropertyAux
    variable = x1_gas
    property = mass_fraction
    phase = 1
    fluid_component = 1
    execute_on = 'initial timestep_end'
  []
  [x0_water]
    type = PorousFlowPropertyAux
    variable = x0_water
    property = mass_fraction
    phase = 0
    fluid_component = 0
    execute_on = 'initial timestep_end'
  []
  [x0_gas]
    type = PorousFlowPropertyAux
    variable = x0_gas
    property = mass_fraction
    phase = 1
    fluid_component = 0
    execute_on = 'initial timestep_end'
  []
[]

[Kernels]
  [mass0]
    type = PorousFlowMassTimeDerivative
    variable = pgas
    fluid_component = 0
  []
  [mass1]
    type = PorousFlowMassTimeDerivative
    variable = z
    fluid_component = 1
  []
  [mass2]
    type = PorousFlowMassTimeDerivative
    variable = xnacl
    fluid_component = 2
  []
[]

[UserObjects]
  [dictator]
    type = PorousFlowDictator
    porous_flow_vars = 'pgas z xnacl'
    number_fluid_phases = 2
    number_fluid_components = 3
  []
  [pc]
    type = PorousFlowCapillaryPressureConst
    pc = 0
  []
  [fs]
    type = PorousFlowBrineCO2
    brine_fp = brine
    co2_fp = co2
    capillary_pressure = pc
  []
[]

[FluidProperties]
  [co2]
    type = CO2FluidProperties
  []
  [brine]
    type = BrineFluidProperties
  []
[]

[Materials]
  [temperature]
    type = PorousFlowTemperature
  []
  [brineco2]
    type = PorousFlowFluidState
    gas_porepressure = pgas
    z = z
    temperature_unit = Celsius
    xnacl = xnacl
    capillary_pressure = pc
    fluid_state = fs
  []
  [permeability]
    type = PorousFlowPermeabilityConst
    permeability = '1e-12 0 0 0 1e-12 0 0 0 1e-12'
  []
  [relperm0]
    type = PorousFlowRelativePermeabilityCorey
    n = 2
    phase = 0
  []
  [relperm1]
    type = PorousFlowRelativePermeabilityCorey
    n = 3
    phase = 1
  []
  [porosity]
    type = PorousFlowPorosityConst
    porosity = 0.1
  []
[]

[Executioner]
  type = Transient
  solve_type = NEWTON
  dt = 1
  end_time = 10
[]

[Preconditioning]
  [smp]
    type = SMP
    full = true
  []
[]

[Postprocessors]
  [density_water]
    type = ElementIntegralVariablePostprocessor
    variable = density_water
    execute_on = 'initial timestep_end'
  []
  [density_gas]
    type = ElementIntegralVariablePostprocessor
    variable = density_gas
    execute_on = 'initial timestep_end'
  []
  [viscosity_water]
    type = ElementIntegralVariablePostprocessor
    variable = viscosity_water
    execute_on = 'initial timestep_end'
  []
  [viscosity_gas]
    type = ElementIntegralVariablePostprocessor
    variable = viscosity_gas
    execute_on = 'initial timestep_end'
  []
  [x1_water]
    type = ElementIntegralVariablePostprocessor
    variable = x1_water
    execute_on = 'initial timestep_end'
  []
  [x0_water]
    type = ElementIntegralVariablePostprocessor
    variable = x0_water
    execute_on = 'initial timestep_end'
  []
  [x1_gas]
    type = ElementIntegralVariablePostprocessor
    variable = x1_gas
    execute_on = 'initial timestep_end'
  []
  [x0_gas]
    type = ElementIntegralVariablePostprocessor
    variable = x0_gas
    execute_on = 'initial timestep_end'
  []
  [sg]
    type = ElementIntegralVariablePostprocessor
    variable = saturation_gas
    execute_on = 'initial timestep_end'
  []
  [sw]
    type = ElementIntegralVariablePostprocessor
    variable = saturation_water
    execute_on = 'initial timestep_end'
  []
  [pwater]
    type = ElementIntegralVariablePostprocessor
    variable = pressure_water
    execute_on = 'initial timestep_end'
  []
  [pgas]
    type = ElementIntegralVariablePostprocessor
    variable = pressure_gas
    execute_on = 'initial timestep_end'
  []
  [xnacl]
    type = ElementIntegralVariablePostprocessor
    variable = xnacl
    execute_on = 'initial timestep_end'
  []
  [x0mass]
    type = PorousFlowFluidMass
    fluid_component = 0
    phase = '0 1'
    execute_on = 'initial timestep_end'
  []
  [x1mass]
    type = PorousFlowFluidMass
    fluid_component = 1
    phase = '0 1'
    execute_on = 'initial timestep_end'
  []
  [x2mass]
    type = PorousFlowFluidMass
    fluid_component = 2
    phase = '0 1'
    execute_on = 'initial timestep_end'
  []
[]

[Outputs]
  csv = true
  file_base = brineco2_2
  execute_on = 'initial timestep_end'
  perf_graph = true
[]

(modules/porous_flow/test/tests/fluidstate/theis_tabulated.i)

# Two phase Theis problem: Flow from single source using WaterNCG fluidstate.
# Constant rate injection 2 kg/s
# 1D cylindrical mesh
# Initially, system has only a liquid phase, until enough gas is injected
# to form a gas phase, in which case the system becomes two phase.
# Note: this test is the same as theis.i, but uses the tabulated version of the CO2FluidProperties

[Mesh]
  type = GeneratedMesh
  dim = 1
  nx = 80
  xmax = 200
  bias_x = 1.05
  coord_type = RZ
  rz_coord_axis = Y
[]

[GlobalParams]
  PorousFlowDictator = dictator
  gravity = '0 0 0'
[]

[AuxVariables]
  [saturation_gas]
    order = CONSTANT
    family = MONOMIAL
  []
  [x1]
    order = CONSTANT
    family = MONOMIAL
  []
  [y0]
    order = CONSTANT
    family = MONOMIAL
  []
[]

[AuxKernels]
  [saturation_gas]
    type = PorousFlowPropertyAux
    variable = saturation_gas
    property = saturation
    phase = 1
    execute_on = timestep_end
  []
  [x1]
    type = PorousFlowPropertyAux
    variable = x1
    property = mass_fraction
    phase = 0
    fluid_component = 1
    execute_on = timestep_end
  []
  [y0]
    type = PorousFlowPropertyAux
    variable = y0
    property = mass_fraction
    phase = 1
    fluid_component = 0
    execute_on = timestep_end
  []
[]

[Variables]
  [pgas]
    initial_condition = 20e6
  []
  [zi]
    initial_condition = 0
  []
[]

[Kernels]
  [mass0]
    type = PorousFlowMassTimeDerivative
    fluid_component = 0
    variable = pgas
  []
  [flux0]
    type = PorousFlowAdvectiveFlux
    fluid_component = 0
    variable = pgas
  []
  [mass1]
    type = PorousFlowMassTimeDerivative
    fluid_component = 1
    variable = zi
  []
  [flux1]
    type = PorousFlowAdvectiveFlux
    fluid_component = 1
    variable = zi
  []
[]

[UserObjects]
  [dictator]
    type = PorousFlowDictator
    porous_flow_vars = 'pgas zi'
    number_fluid_phases = 2
    number_fluid_components = 2
  []
  [pc]
    type = PorousFlowCapillaryPressureConst
    pc = 0
  []
  [fs]
    type = PorousFlowWaterNCG
    water_fp = water
    gas_fp = tabulated
    capillary_pressure = pc
  []
[]

[FluidProperties]
  [co2]
    type = CO2FluidProperties
  []
  [tabulated]
    type = TabulatedBicubicFluidProperties
    fp = co2
    fluid_property_file = fluid_properties.csv
    # We try to avoid using both, but some properties are not implemented in the tabulation
    allow_fp_and_tabulation = true
    # Test was design prior to bounds check
    error_on_out_of_bounds = false
    # Comment out the fp parameter and uncomment below to use the newly generated tabulation
    # fluid_property_file = fluid_properties.csv
  []
  [water]
    type = Water97FluidProperties
  []
[]

[Materials]
  [temperature]
    type = PorousFlowTemperature
    temperature = 20
  []
  [waterncg]
    type = PorousFlowFluidState
    gas_porepressure = pgas
    z = zi
    temperature_unit = Celsius
    capillary_pressure = pc
    fluid_state = fs
  []
  [porosity]
    type = PorousFlowPorosityConst
    porosity = 0.2
  []
  [permeability]
    type = PorousFlowPermeabilityConst
    permeability = '1e-12 0 0 0 1e-12 0 0 0 1e-12'
  []
  [relperm_water]
    type = PorousFlowRelativePermeabilityCorey
    n = 2
    phase = 0
    s_res = 0.1
    sum_s_res = 0.1
  []
  [relperm_gas]
    type = PorousFlowRelativePermeabilityCorey
    n = 2
    phase = 1
  []
[]

[BCs]
  [rightwater]
    type = DirichletBC
    boundary = right
    value = 20e6
    variable = pgas
  []
[]

[DiracKernels]
  [source]
    type = PorousFlowSquarePulsePointSource
    point = '0 0 0'
    mass_flux = 2
    variable = zi
  []
[]

[Preconditioning]
  [smp]
    type = SMP
    full = true
    petsc_options = '-snes_converged_reason -ksp_diagonal_scale -ksp_diagonal_scale_fix -ksp_gmres_modifiedgramschmidt -snes_linesearch_monitor'
    petsc_options_iname = '-ksp_type -pc_type -sub_pc_type -sub_pc_factor_shift_type -pc_asm_overlap -snes_atol -snes_rtol -snes_max_it'
    petsc_options_value = 'gmres      asm      lu           NONZERO                   2               1E-8       1E-10 20'
  []
[]

[Executioner]
  type = Transient
  solve_type = NEWTON
  end_time = 8e2
  [TimeStepper]
    type = IterationAdaptiveDT
    dt = 2
    growth_factor = 2
  []
[]

[VectorPostprocessors]
  [line]
    type = LineValueSampler
    warn_discontinuous_face_values = false
    sort_by = x
    start_point = '0 0 0'
    end_point = '200 0 0'
    num_points = 1000
    variable = 'pgas zi x1 saturation_gas'
    execute_on = 'timestep_end'
  []
[]

[Postprocessors]
  [pgas]
    type = PointValue
    point = '1 0 0'
    variable = pgas
  []
  [sgas]
    type = PointValue
    point = '1 0 0'
    variable = saturation_gas
  []
  [zi]
    type = PointValue
    point = '1 0 0'
    variable = zi
  []
  [massgas]
    type = PorousFlowFluidMass
    fluid_component = 1
  []
  [x1]
    type = PointValue
    point = '1 0 0'
    variable = x1
  []
  [y0]
    type = PointValue
    point = '1 0 0'
    variable = y0
  []
[]

[Outputs]
  print_linear_residuals = false
  perf_graph = true
  [csvout]
    type = CSV
    file_base = theis_tabulated_csvout
    execute_on = timestep_end
    execute_vector_postprocessors_on = final
  []
[]

(modules/porous_flow/test/tests/jacobian/brineco2_gas.i)

# Tests correct calculation of properties derivatives in PorousFlowFluidState
# for conditions that give a single gas phase

[Mesh]
  type = GeneratedMesh
  dim = 2
  nx = 2
  ny = 2
[]

[GlobalParams]
  PorousFlowDictator = dictator
  gravity = '0 0 0'
[]

[AuxVariables]
  [xnacl]
    initial_condition = 0.05
  []
[]

[Variables]
  [pgas]
  []
  [zi]
  []
[]

[ICs]
  [pgas]
    type = RandomIC
    min = 5e4
    max = 1e5
    variable = pgas
  []
  [z]
    type = RandomIC
    min = 0.9
    max = 0.99
    variable = zi
  []
[]

[Kernels]
  [mass0]
    type = PorousFlowMassTimeDerivative
    variable = pgas
    fluid_component = 0
  []
  [mass1]
    type = PorousFlowMassTimeDerivative
    variable = zi
    fluid_component = 1
  []
  [adv0]
    type = PorousFlowAdvectiveFlux
    variable = pgas
    fluid_component = 0
  []
  [adv1]
    type = PorousFlowAdvectiveFlux
    variable = zi
    fluid_component = 1
  []
[]

[UserObjects]
  [dictator]
    type = PorousFlowDictator
    porous_flow_vars = 'pgas zi'
    number_fluid_phases = 2
    number_fluid_components = 2
  []
  [pc]
    type = PorousFlowCapillaryPressureVG
    m = 0.5
    alpha = 1
    pc_max = 1e3
  []
  [fs]
    type = PorousFlowBrineCO2
    brine_fp = brine
    co2_fp = co2
    capillary_pressure = pc
  []
[]

[FluidProperties]
  [co2]
    type = CO2FluidProperties
  []
  [brine]
    type = BrineFluidProperties
  []
  [water]
    type = Water97FluidProperties
  []
[]

[Materials]
  [temperature]
    type = PorousFlowTemperature
    temperature = 50
  []
  [brineco2]
    type = PorousFlowFluidState
    gas_porepressure = pgas
    z = zi
    temperature_unit = Celsius
    xnacl = xnacl
    capillary_pressure = pc
    fluid_state = fs
  []
  [permeability]
    type = PorousFlowPermeabilityConst
    permeability = '1e-12 0 0 0 1e-12 0 0 0 1e-12'
  []
  [relperm0]
    type = PorousFlowRelativePermeabilityCorey
    n = 2
    phase = 0
  []
  [relperm1]
    type = PorousFlowRelativePermeabilityCorey
    n = 3
    phase = 1
  []
  [porosity]
    type = PorousFlowPorosityConst
    porosity = 0.1
  []
[]

[Executioner]
  type = Transient
  solve_type = NEWTON
  dt = 1
  end_time = 1
  nl_abs_tol = 1e-12
[]

[Preconditioning]
  [smp]
    type = SMP
    full = true
  []
[]

[AuxVariables]
  [sgas]
    family = MONOMIAL
    order = CONSTANT
  []
[]

[AuxKernels]
  [sgas]
    type = PorousFlowPropertyAux
    property = saturation
    phase = 1
    variable = sgas
  []
[]

[Postprocessors]
  [sgas_min]
    type = ElementExtremeValue
    variable = sgas
    value_type = min
  []
  [sgas_max]
    type = ElementExtremeValue
    variable = sgas
    value_type = max
  []
[]

(modules/porous_flow/examples/co2_intercomparison/1Dradial/1Dradial.i)

# Intercomparison problem 3: Radial flow from an injection well
#
# From Pruess et al, Code intercomparison builds confidence in
# numerical simulation models for geologic disposal of CO2, Energy 29 (2004)
#
# A variation with zero salinity can be run by changing the initial condition
# of the AuxVariable xnacl

[Mesh]
  type = GeneratedMesh
  dim = 1
  nx = 500
  xmax = 10000
  bias_x = 1.01
  coord_type = 'RZ'
  rz_coord_axis = Y
[]

[GlobalParams]
  PorousFlowDictator = 'dictator'
  gravity = '0 0 0'
[]

[AuxVariables]
  [pressure_liquid]
    order = CONSTANT
    family = MONOMIAL
  []
  [saturation_gas]
    order = CONSTANT
    family = MONOMIAL
  []
  [x1]
    order = CONSTANT
    family = MONOMIAL
  []
  [y0]
    order = CONSTANT
    family = MONOMIAL
  []
  [xnacl]
    initial_condition = 0.15
  []
[]

[AuxKernels]
  [pressure_liquid]
    type = PorousFlowPropertyAux
    variable = pressure_liquid
    property = pressure
    phase = 0
    execute_on = 'timestep_end'
  []
  [saturation_gas]
    type = PorousFlowPropertyAux
    variable = saturation_gas
    property = saturation
    phase = 1
    execute_on = 'timestep_end'
  []
  [x1]
    type = PorousFlowPropertyAux
    variable = x1
    property = mass_fraction
    phase = 0
    fluid_component = 1
    execute_on = 'timestep_end'
  []
  [y0]
    type = PorousFlowPropertyAux
    variable = y0
    property = mass_fraction
    phase = 1
    fluid_component = 0
    execute_on = 'timestep_end'
  []
[]

[Variables]
  [pgas]
    initial_condition = 12e6
  []
  [zi]
    initial_condition = 0
    scaling = 1e4
  []
[]

[Kernels]
  [mass0]
    type = PorousFlowMassTimeDerivative
    fluid_component = 0
    variable = pgas
  []
  [flux0]
    type = PorousFlowAdvectiveFlux
    fluid_component = 0
    variable = pgas
  []
  [mass1]
    type = PorousFlowMassTimeDerivative
    fluid_component = 1
    variable = zi
  []
  [flux1]
    type = PorousFlowAdvectiveFlux
    fluid_component = 1
    variable = zi
  []
[]

[UserObjects]
  [dictator]
    type = PorousFlowDictator
    porous_flow_vars = 'pgas zi'
    number_fluid_phases = 2
    number_fluid_components = 3
  []
  [pc]
    type = PorousFlowCapillaryPressureVG
    alpha = 5.099e-5
    m = 0.457
    sat_lr = 0.0
    pc_max = 1e7
  []
  [fs]
    type = PorousFlowBrineCO2
    brine_fp = brine
    co2_fp = co2
    capillary_pressure = pc
  []
[]

[FluidProperties]
  [co2sw]
    type = CO2FluidProperties
  []
  [co2]
    type = TabulatedBicubicFluidProperties
    fp = co2sw
  []
  [water]
    type = Water97FluidProperties
  []
  [watertab]
    type = TabulatedBicubicFluidProperties
    fp = water
    temperature_min = 273.15
    temperature_max = 573.15
    fluid_property_output_file = water_fluid_properties.csv
    # Comment out the fp parameter and uncomment below to use the newly generated tabulation
    # fluid_property_file = water_fluid_properties.csv
  []
  [brine]
    type = BrineFluidProperties
    water_fp = watertab
  []
[]

[Materials]
  [temperature]
    type = PorousFlowTemperature
    temperature = '45'
  []
  [brineco2]
    type = PorousFlowFluidState
    gas_porepressure = 'pgas'
    z = 'zi'
    temperature_unit = Celsius
    xnacl = 'xnacl'
    capillary_pressure = pc
    fluid_state = fs
  []
  [porosity]
    type = PorousFlowPorosityConst
    porosity = '0.12'
  []
  [permeability]
    type = PorousFlowPermeabilityConst
    permeability = '1e-13 0 0 0 1e-13 0 0 0 1e-13'
  []
  [relperm_water]
    type = PorousFlowRelativePermeabilityVG
    m = 0.457
    phase = 0
    s_res = 0.3
    sum_s_res = 0.35
  []
  [relperm_gas]
    type = PorousFlowRelativePermeabilityCorey
    n = 2
    phase = 1
    s_res = 0.05
    sum_s_res = 0.35
  []
[]

[BCs]
  [rightwater]
    type = PorousFlowPiecewiseLinearSink
    boundary = 'right'
    variable = pgas
    use_mobility = true
    PorousFlowDictator = dictator
    fluid_phase = 0
    multipliers = '0 1e9'
    PT_shift = '12e6'
    pt_vals = '0 1e9'
    mass_fraction_component = 0
    use_relperm = true
  []
  [rightco2]
    type = PorousFlowPiecewiseLinearSink
    variable = zi
    boundary = 'right'
    use_mobility = true
    PorousFlowDictator = dictator
    fluid_phase = 1
    multipliers = '0 1e9'
    PT_shift = '12e6'
    pt_vals = '0 1e9'
    mass_fraction_component = 1
    use_relperm = true
  []
[]

[DiracKernels]
  [source]
    type = PorousFlowSquarePulsePointSource
    point = '0 0 0'
    mass_flux = 1
    variable = zi
  []
[]

[Preconditioning]
  [smp]
    type = SMP
    full = true
    petsc_options_iname = '-ksp_type -pc_type -sub_pc_type -sub_pc_factor_shift_type'
    petsc_options_value = 'gmres bjacobi lu NONZERO'
  []
[]

[Executioner]
  type = Transient
  solve_type = NEWTON
  end_time = 8.64e8
  nl_max_its = 25
  l_max_its = 100
  dtmax = 5e6
  [TimeStepper]
    type = IterationAdaptiveDT
    dt = 100
  []
[]

[VectorPostprocessors]
  [vars]
    type = NodalValueSampler
    sort_by = x
    variable = 'pgas zi xnacl'
    execute_on = 'timestep_end'
    outputs = spatial
  []
  [auxvars]
    type = ElementValueSampler
    sort_by = x
    variable = 'saturation_gas x1 y0'
    execute_on = 'timestep_end'
    outputs = spatial
  []
[]

[Postprocessors]
  [pgas]
    type = PointValue
    point = '25.25 0 0'
    variable = pgas
    outputs = time
  []
  [sgas]
    type = PointValue
    point = '25.25 0 0'
    variable = saturation_gas
    outputs = time
  []
  [zi]
    type = PointValue
    point = '25.25 0 0'
    variable = zi
    outputs = time
  []
  [massgas]
    type = PorousFlowFluidMass
    fluid_component = 1
    outputs = time
  []
  [x1]
    type = PointValue
    point = '25.25 0 0'
    variable = x1
    outputs = time
  []
  [y0]
    type = PointValue
    point = '25.25 0 0'
    variable = y0
    outputs = time
  []
  [xnacl]
    type = PointValue
    point = '25.25 0 0'
    variable = xnacl
    outputs = time
  []
[]

[Outputs]
  print_linear_residuals = false
  perf_graph = true
  sync_times = '2.592e6 8.64e6 8.64e7 8.64e8'
  [time]
    type = CSV
  []
  [spatial]
    type = CSV
    sync_only = true
  []
[]

(modules/porous_flow/test/tests/fluidstate/waterncg.i)

# Tests correct calculation of properties in PorousFlowWaterNCG.
# This test is run three times, with the initial condition of z (the total mass
# fraction of NCG in all phases) varied to give either a single phase liquid, a
# single phase gas, or two phases.

[Mesh]
  [mesh]
    type = GeneratedMeshGenerator
    dim = 2
  []
[]

[GlobalParams]
  PorousFlowDictator = dictator
[]

[Variables]
  [pgas]
    initial_condition = 1e6
  []
  [z]
     initial_condition = 0.005
  []
[]

[AuxVariables]
  [pressure_gas]
    order = CONSTANT
    family = MONOMIAL
  []
  [pressure_water]
    order = CONSTANT
    family = MONOMIAL
  []
  [saturation_gas]
    order = CONSTANT
    family = MONOMIAL
  []
  [saturation_water]
    order = CONSTANT
    family = MONOMIAL
  []
  [density_water]
    order = CONSTANT
    family = MONOMIAL
  []
  [density_gas]
    order = CONSTANT
    family = MONOMIAL
  []
  [viscosity_water]
    order = CONSTANT
    family = MONOMIAL
  []
  [viscosity_gas]
    order = CONSTANT
    family = MONOMIAL
  []
  [enthalpy_water]
    order = CONSTANT
    family = MONOMIAL
  []
  [enthalpy_gas]
    order = CONSTANT
    family = MONOMIAL
  []
  [internal_energy_water]
    order = CONSTANT
    family = MONOMIAL
  []
  [internal_energy_gas]
    order = CONSTANT
    family = MONOMIAL
  []
  [x0_water]
    order = CONSTANT
    family = MONOMIAL
  []
  [x0_gas]
    order = CONSTANT
    family = MONOMIAL
  []
  [x1_water]
    order = CONSTANT
    family = MONOMIAL
  []
  [x1_gas]
    order = CONSTANT
    family = MONOMIAL
  []
[]

[AuxKernels]
  [pressure_water]
    type = PorousFlowPropertyAux
    variable = pressure_water
    property = pressure
    phase = 0
    execute_on = timestep_end
  []
  [pressure_gas]
    type = PorousFlowPropertyAux
    variable = pressure_gas
    property = pressure
    phase = 1
    execute_on = timestep_end
  []
  [saturation_water]
    type = PorousFlowPropertyAux
    variable = saturation_water
    property = saturation
    phase = 0
    execute_on = timestep_end
  []
  [saturation_gas]
    type = PorousFlowPropertyAux
    variable = saturation_gas
    property = saturation
    phase = 1
    execute_on = timestep_end
  []
  [density_water]
    type = PorousFlowPropertyAux
    variable = density_water
    property = density
    phase = 0
    execute_on = timestep_end
  []
  [density_gas]
    type = PorousFlowPropertyAux
    variable = density_gas
    property = density
    phase = 1
    execute_on = timestep_end
  []
  [viscosity_water]
    type = PorousFlowPropertyAux
    variable = viscosity_water
    property = viscosity
    phase = 0
    execute_on = timestep_end
  []
  [viscosity_gas]
    type = PorousFlowPropertyAux
    variable = viscosity_gas
    property = viscosity
    phase = 1
    execute_on = timestep_end
  []
  [enthalpy_water]
    type = PorousFlowPropertyAux
    variable = enthalpy_water
    property = enthalpy
    phase = 0
    execute_on = timestep_end
  []
  [enthalpy_gas]
    type = PorousFlowPropertyAux
    variable = enthalpy_gas
    property = enthalpy
    phase = 1
    execute_on = timestep_end
  []
  [internal_energy_water]
    type = PorousFlowPropertyAux
    variable = internal_energy_water
    property = internal_energy
    phase = 0
    execute_on = timestep_end
  []
  [internal_energy_gas]
    type = PorousFlowPropertyAux
    variable = internal_energy_gas
    property = internal_energy
    phase = 1
    execute_on = timestep_end
  []
  [x1_water]
    type = PorousFlowPropertyAux
    variable = x1_water
    property = mass_fraction
    phase = 0
    fluid_component = 1
    execute_on = timestep_end
  []
  [x1_gas]
    type = PorousFlowPropertyAux
    variable = x1_gas
    property = mass_fraction
    phase = 1
    fluid_component = 1
    execute_on = timestep_end
  []
  [x0_water]
    type = PorousFlowPropertyAux
    variable = x0_water
    property = mass_fraction
    phase = 0
    fluid_component = 0
    execute_on = timestep_end
  []
  [x0_gas]
    type = PorousFlowPropertyAux
    variable = x0_gas
    property = mass_fraction
    phase = 1
    fluid_component = 0
    execute_on = timestep_end
  []
[]

[Kernels]
  [mass0]
    type = PorousFlowMassTimeDerivative
    variable = pgas
    fluid_component = 0
  []
  [mass1]
    type = PorousFlowMassTimeDerivative
    variable = z
    fluid_component = 1
  []
[]

[UserObjects]
  [dictator]
    type = PorousFlowDictator
    porous_flow_vars = 'pgas z'
    number_fluid_phases = 2
    number_fluid_components = 2
  []
  [pc]
    type = PorousFlowCapillaryPressureConst
    pc = 0
  []
  [fs]
    type = PorousFlowWaterNCG
    water_fp = water
    gas_fp = co2
    capillary_pressure = pc
  []
[]

[FluidProperties]
  [co2]
    type = CO2FluidProperties
  []
  [water]
    type = Water97FluidProperties
  []
[]

[Materials]
  [temperature]
    type = PorousFlowTemperature
    temperature = 50
  []
  [waterncg]
    type = PorousFlowFluidState
    gas_porepressure = pgas
    z = z
    temperature_unit = Celsius
    capillary_pressure = pc
    fluid_state = fs
  []
  [permeability]
    type = PorousFlowPermeabilityConst
    permeability = '1e-12 0 0 0 1e-12 0 0 0 1e-12'
  []
  [relperm0]
    type = PorousFlowRelativePermeabilityCorey
    n = 2
    phase = 0
  []
  [relperm1]
    type = PorousFlowRelativePermeabilityCorey
    n = 3
    phase = 1
  []
  [porosity]
    type = PorousFlowPorosityConst
    porosity = 0.1
  []
[]

[Executioner]
  type = Transient
  solve_type = NEWTON
  dt = 1
  end_time = 1
  nl_abs_tol = 1e-12
[]

[Preconditioning]
  [smp]
    type = SMP
    full = true
  []
[]

[Postprocessors]
  [density_water]
    type = ElementIntegralVariablePostprocessor
    variable = density_water
  []
  [density_gas]
    type = ElementIntegralVariablePostprocessor
    variable = density_gas
  []
  [viscosity_water]
    type = ElementIntegralVariablePostprocessor
    variable = viscosity_water
  []
  [viscosity_gas]
    type = ElementIntegralVariablePostprocessor
    variable = viscosity_gas
  []
  [enthalpy_water]
    type = ElementIntegralVariablePostprocessor
    variable = enthalpy_water
  []
  [enthalpy_gas]
    type = ElementIntegralVariablePostprocessor
    variable = enthalpy_gas
  []
  [internal_energy_water]
    type = ElementIntegralVariablePostprocessor
    variable = internal_energy_water
  []
  [internal_energy_gas]
    type = ElementIntegralVariablePostprocessor
    variable = internal_energy_gas
  []
  [x1_water]
    type = ElementIntegralVariablePostprocessor
    variable = x1_water
  []
  [x0_water]
    type = ElementIntegralVariablePostprocessor
    variable = x0_water
  []
  [x1_gas]
    type = ElementIntegralVariablePostprocessor
    variable = x1_gas
  []
  [x0_gas]
    type = ElementIntegralVariablePostprocessor
    variable = x0_gas
  []
  [sg]
    type = ElementIntegralVariablePostprocessor
    variable = saturation_gas
  []
  [sw]
    type = ElementIntegralVariablePostprocessor
    variable = saturation_water
  []
  [pwater]
    type = ElementIntegralVariablePostprocessor
    variable = pressure_water
  []
  [pgas]
    type = ElementIntegralVariablePostprocessor
    variable = pressure_gas
  []
  [x0mass]
    type = PorousFlowFluidMass
    fluid_component = 0
    phase = '0 1'
  []
  [x1mass]
    type = PorousFlowFluidMass
    fluid_component = 1
    phase = '0 1'
  []
[]

[Outputs]
  exodus = true
  file_base = waterncg_liquid
[]

(modules/porous_flow/test/tests/fluidstate/theis_brineco2_nonisothermal.i)

# Two phase nonisothermal Theis problem: Flow from single source.
# Constant rate injection 2 kg/s of cold CO2 into warm reservoir
# 1D cylindrical mesh
# Initially, system has only a liquid phase, until enough gas is injected
# to form a gas phase, in which case the system becomes two phase.

[Mesh]
  [mesh]
    type = GeneratedMeshGenerator
    dim = 1
    nx = 40
    xmin = 0.1
    xmax = 200
    bias_x = 1.05

  []
  coord_type = RZ
  rz_coord_axis = Y
[]

[GlobalParams]
  PorousFlowDictator = dictator
  gravity = '0 0 0'
[]

[AuxVariables]
  [saturation_gas]
    order = CONSTANT
    family = MONOMIAL
  []
  [x1]
    order = CONSTANT
    family = MONOMIAL
  []
  [y0]
    order = CONSTANT
    family = MONOMIAL
  []
[]

[AuxKernels]
  [saturation_gas]
    type = PorousFlowPropertyAux
    variable = saturation_gas
    property = saturation
    phase = 1
    execute_on = timestep_end
  []
  [x1]
    type = PorousFlowPropertyAux
    variable = x1
    property = mass_fraction
    phase = 0
    fluid_component = 1
    execute_on = timestep_end
  []
  [y0]
    type = PorousFlowPropertyAux
    variable = y0
    property = mass_fraction
    phase = 1
    fluid_component = 0
    execute_on = timestep_end
  []
[]

[Variables]
  [pgas]
    initial_condition = 20e6
  []
  [zi]
    initial_condition = 0
  []
  [xnacl]
    initial_condition = 0.1
  []
  [temperature]
    initial_condition = 70
    scaling = 1e-4
  []
[]

[Kernels]
  [mass0]
    type = PorousFlowMassTimeDerivative
    fluid_component = 0
    variable = pgas
  []
  [flux0]
    type = PorousFlowAdvectiveFlux
    fluid_component = 0
    variable = pgas
  []
  [mass1]
    type = PorousFlowMassTimeDerivative
    fluid_component = 1
    variable = zi
  []
  [flux1]
    type = PorousFlowAdvectiveFlux
    fluid_component = 1
    variable = zi
  []
  [mass2]
    type = PorousFlowMassTimeDerivative
    fluid_component = 2
    variable = xnacl
  []
  [flux2]
    type = PorousFlowAdvectiveFlux
    fluid_component = 2
    variable = xnacl
  []
  [energy]
    type = PorousFlowEnergyTimeDerivative
    variable = temperature
  []
  [heatadv]
    type = PorousFlowHeatAdvection
    variable = temperature
  []
  [conduction]
    type = PorousFlowHeatConduction
    variable = temperature
  []
[]

[UserObjects]
  [dictator]
    type = PorousFlowDictator
    porous_flow_vars = 'pgas zi xnacl temperature'
    number_fluid_phases = 2
    number_fluid_components = 3
  []
  [pc]
    type = PorousFlowCapillaryPressureConst
    pc = 0
  []
  [fs]
    type = PorousFlowBrineCO2
    brine_fp = brine
    co2_fp = co2
    capillary_pressure = pc
  []
[]

[FluidProperties]
  [co2]
    type = CO2FluidProperties
  []
  [brine]
    type = BrineFluidProperties
  []
[]

[Materials]
  [temperature]
    type = PorousFlowTemperature
    temperature = temperature
  []
  [brineco2]
    type = PorousFlowFluidState
    gas_porepressure = pgas
    z = zi
    temperature = temperature
    temperature_unit = Celsius
    xnacl = xnacl
    capillary_pressure = pc
    fluid_state = fs
  []
  [porosity]
    type = PorousFlowPorosityConst
    porosity = 0.2
  []
  [permeability]
    type = PorousFlowPermeabilityConst
    permeability = '1e-12 0 0 0 1e-12 0 0 0 1e-12'
  []
  [relperm_water]
    type = PorousFlowRelativePermeabilityCorey
    n = 2
    phase = 0
    s_res = 0.1
    sum_s_res = 0.1
  []
  [relperm_gas]
    type = PorousFlowRelativePermeabilityCorey
    n = 2
    phase = 1
  []
  [rockheat]
    type = PorousFlowMatrixInternalEnergy
    specific_heat_capacity = 1000
    density = 2500
  []
  [rock_thermal_conductivity]
    type = PorousFlowThermalConductivityIdeal
    dry_thermal_conductivity = '50 0 0  0 50 0  0 0 50'
  []
[]

[BCs]
  [cold_gas]
    type = DirichletBC
    boundary = left
    variable = temperature
    value = 20
  []
  [gas_injecton]
    type = PorousFlowSink
    boundary = left
    variable = zi
    flux_function = -0.159155
  []
  [rightwater]
    type = DirichletBC
    boundary = right
    value = 20e6
    variable = pgas
  []
  [righttemp]
    type = DirichletBC
    boundary = right
    value = 70
    variable = temperature
  []
[]

[Preconditioning]
  [smp]
    type = SMP
    full = true
    petsc_options_iname = '-ksp_type -pc_type -sub_pc_type -sub_pc_factor_shift_type -pc_asm_overlap'
    petsc_options_value = 'gmres      asm      lu           NONZERO                   2'
  []
[]

[Executioner]
  type = Transient
  solve_type = NEWTON
  end_time = 1e4
  nl_abs_tol = 1e-7
  nl_rel_tol = 1e-5
  # Avoids failing first time step in parallel
  line_search = 'none'

  [TimeStepper]
    type = IterationAdaptiveDT
    dt = 1
    growth_factor = 1.5
  []
[]

[Postprocessors]
  [pgas]
    type = PointValue
    point = '2 0 0'
    variable = pgas
  []
  [sgas]
    type = PointValue
    point = '2 0 0'
    variable = saturation_gas
  []
  [zi]
    type = PointValue
    point = '2 0 0'
    variable = zi
  []
  [temperature]
    type = PointValue
    point = '2 0 0'
    variable = temperature
  []
  [massgas]
    type = PorousFlowFluidMass
    fluid_component = 1
  []
  [x1]
    type = PointValue
    point = '2 0 0'
    variable = x1
  []
  [y0]
    type = PointValue
    point = '2 0 0'
    variable = y0
  []
[]

[Outputs]
  print_linear_residuals = false
  perf_graph = true
  csv = true
[]

(modules/porous_flow/test/tests/fluidstate/brineco2_nonisothermal.i)

[Mesh]
  [mesh]
    type = GeneratedMeshGenerator
    dim = 2
  []
[]

[GlobalParams]
  PorousFlowDictator = dictator
[]

[Variables]
  [pgas]
    initial_condition = 20e6
  []
  [z]
     initial_condition = 0.2
  []
  [temperature]
    initial_condition = 70
  []
[]

[AuxVariables]
  [xnacl]
    initial_condition = 0.1
  []
  [pressure_gas]
    order = CONSTANT
    family = MONOMIAL
  []
  [pressure_water]
    order = CONSTANT
    family = MONOMIAL
  []
  [saturation_gas]
    order = CONSTANT
    family = MONOMIAL
  []
  [saturation_water]
    order = CONSTANT
    family = MONOMIAL
  []
  [density_water]
    order = CONSTANT
    family = MONOMIAL
  []
  [density_gas]
    order = CONSTANT
    family = MONOMIAL
  []
  [viscosity_water]
    order = CONSTANT
    family = MONOMIAL
  []
  [viscosity_gas]
    order = CONSTANT
    family = MONOMIAL
  []
  [enthalpy_water]
    order = CONSTANT
    family = MONOMIAL
  []
  [enthalpy_gas]
    order = CONSTANT
    family = MONOMIAL
  []
  [internal_energy_water]
    order = CONSTANT
    family = MONOMIAL
  []
  [internal_energy_gas]
    order = CONSTANT
    family = MONOMIAL
  []
  [x0_water]
    order = CONSTANT
    family = MONOMIAL
  []
  [x0_gas]
    order = CONSTANT
    family = MONOMIAL
  []
  [x1_water]
    order = CONSTANT
    family = MONOMIAL
  []
  [x1_gas]
    order = CONSTANT
    family = MONOMIAL
  []
[]

[AuxKernels]
  [pressure_water]
    type = PorousFlowPropertyAux
    variable = pressure_water
    property = pressure
    phase = 0
    execute_on = timestep_end
  []
  [pressure_gas]
    type = PorousFlowPropertyAux
    variable = pressure_gas
    property = pressure
    phase = 1
    execute_on = timestep_end
  []
  [saturation_water]
    type = PorousFlowPropertyAux
    variable = saturation_water
    property = saturation
    phase = 0
    execute_on = timestep_end
  []
  [saturation_gas]
    type = PorousFlowPropertyAux
    variable = saturation_gas
    property = saturation
    phase = 1
    execute_on = timestep_end
  []
  [density_water]
    type = PorousFlowPropertyAux
    variable = density_water
    property = density
    phase = 0
    execute_on = timestep_end
  []
  [density_gas]
    type = PorousFlowPropertyAux
    variable = density_gas
    property = density
    phase = 1
    execute_on = timestep_end
  []
  [viscosity_water]
    type = PorousFlowPropertyAux
    variable = viscosity_water
    property = viscosity
    phase = 0
    execute_on = timestep_end
  []
  [viscosity_gas]
    type = PorousFlowPropertyAux
    variable = viscosity_gas
    property = viscosity
    phase = 1
    execute_on = timestep_end
  []
  [enthalpy_water]
    type = PorousFlowPropertyAux
    variable = enthalpy_water
    property = enthalpy
    phase = 0
    execute_on = timestep_end
  []
  [enthalpy_gas]
    type = PorousFlowPropertyAux
    variable = enthalpy_gas
    property = enthalpy
    phase = 1
    execute_on = timestep_end
  []
  [internal_energy_water]
    type = PorousFlowPropertyAux
    variable = internal_energy_water
    property = internal_energy
    phase = 0
    execute_on = timestep_end
  []
  [internal_energy_gas]
    type = PorousFlowPropertyAux
    variable = internal_energy_gas
    property = internal_energy
    phase = 1
    execute_on = timestep_end
  []
  [x1_water]
    type = PorousFlowPropertyAux
    variable = x1_water
    property = mass_fraction
    phase = 0
    fluid_component = 1
    execute_on = timestep_end
  []
  [x1_gas]
    type = PorousFlowPropertyAux
    variable = x1_gas
    property = mass_fraction
    phase = 1
    fluid_component = 1
    execute_on = timestep_end
  []
  [x0_water]
    type = PorousFlowPropertyAux
    variable = x0_water
    property = mass_fraction
    phase = 0
    fluid_component = 0
    execute_on = timestep_end
  []
  [x0_gas]
    type = PorousFlowPropertyAux
    variable = x0_gas
    property = mass_fraction
    phase = 1
    fluid_component = 0
    execute_on = timestep_end
  []
[]

[Kernels]
  [mass0]
    type = PorousFlowMassTimeDerivative
    variable = pgas
    fluid_component = 0
  []
  [mass1]
    type = PorousFlowMassTimeDerivative
    variable = z
    fluid_component = 1
  []
  [heat]
    type = TimeDerivative
    variable = temperature
  []
[]

[UserObjects]
  [dictator]
    type = PorousFlowDictator
    porous_flow_vars = 'pgas z temperature'
    number_fluid_phases = 2
    number_fluid_components = 2
  []
  [pc]
    type = PorousFlowCapillaryPressureConst
    pc = 0
  []
  [fs]
    type = PorousFlowBrineCO2
    brine_fp = brine
    co2_fp = co2
    capillary_pressure = pc
  []
[]

[FluidProperties]
  [co2]
    type = CO2FluidProperties
  []
  [brine]
    type = BrineFluidProperties
  []
[]

[Materials]
  [temperature]
    type = PorousFlowTemperature
  []
  [brineco2]
    type = PorousFlowFluidState
    gas_porepressure = pgas
    z = z
    temperature = temperature
    temperature_unit = Celsius
    xnacl = xnacl
    capillary_pressure = pc
    fluid_state = fs
  []
  [permeability]
    type = PorousFlowPermeabilityConst
    permeability = '1e-12 0 0 0 1e-12 0 0 0 1e-12'
  []
  [relperm0]
    type = PorousFlowRelativePermeabilityCorey
    n = 2
    phase = 0
  []
  [relperm1]
    type = PorousFlowRelativePermeabilityCorey
    n = 3
    phase = 1
  []
  [porosity]
    type = PorousFlowPorosityConst
    porosity = 0.1
  []
[]

[Executioner]
  type = Transient
  solve_type = NEWTON
  dt = 1
  end_time = 1
  nl_abs_tol = 1e-12
[]

[Preconditioning]
  [smp]
    type = SMP
    full = true
  []
[]

[Postprocessors]
  [density_water]
    type = ElementIntegralVariablePostprocessor
    variable = density_water
  []
  [density_gas]
    type = ElementIntegralVariablePostprocessor
    variable = density_gas
  []
  [viscosity_water]
    type = ElementIntegralVariablePostprocessor
    variable = viscosity_water
  []
  [viscosity_gas]
    type = ElementIntegralVariablePostprocessor
    variable = viscosity_gas
  []
  [enthalpy_water]
    type = ElementIntegralVariablePostprocessor
    variable = enthalpy_water
  []
  [enthalpy_gas]
    type = ElementIntegralVariablePostprocessor
    variable = enthalpy_gas
  []
  [internal_energy_water]
    type = ElementIntegralVariablePostprocessor
    variable = internal_energy_water
  []
  [internal_energy_gas]
    type = ElementIntegralVariablePostprocessor
    variable = internal_energy_gas
  []
  [x1_water]
    type = ElementIntegralVariablePostprocessor
    variable = x1_water
  []
  [x0_water]
    type = ElementIntegralVariablePostprocessor
    variable = x0_water
  []
  [x1_gas]
    type = ElementIntegralVariablePostprocessor
    variable = x1_gas
  []
  [x0_gas]
    type = ElementIntegralVariablePostprocessor
    variable = x0_gas
  []
  [sg]
    type = ElementIntegralVariablePostprocessor
    variable = saturation_gas
  []
  [sw]
    type = ElementIntegralVariablePostprocessor
    variable = saturation_water
  []
  [pwater]
    type = ElementIntegralVariablePostprocessor
    variable = pressure_water
  []
  [pgas]
    type = ElementIntegralVariablePostprocessor
    variable = pressure_gas
  []
  [x0mass]
    type = PorousFlowFluidMass
    fluid_component = 0
    phase = '0 1'
  []
  [x1mass]
    type = PorousFlowFluidMass
    fluid_component = 1
    phase = '0 1'
  []
[]

[Outputs]
  csv = true
  execute_on = timestep_end
[]

(modules/porous_flow/test/tests/fluidstate/brineco2_ic.i)

# Tests correct calculation of z (total mass fraction of NCG summed over all
# phases) using the PorousFlowFluidStateIC initial condition. Once z is
# calculated by the initial condition, the thermophysical properties are calculated
# and the resulting gas saturation should be equal to that given in the intial condition

[Mesh]
  type = GeneratedMesh
  dim = 2
[]

[GlobalParams]
  PorousFlowDictator = dictator
  temperature_unit = Celsius
[]

[Variables]
  [pgas]
    initial_condition = 1e6
  []
  [z]
  []
[]

[ICs]
  [z]
    type = PorousFlowFluidStateIC
    saturation = 0.5
    gas_porepressure = pgas
    temperature = 50
    variable = z
    xnacl = 0.1
    fluid_state = fs
  []
[]

[AuxVariables]
  [saturation_gas]
    order = CONSTANT
    family = MONOMIAL
  []
  [saturation_water]
    order = CONSTANT
    family = MONOMIAL
  []
[]

[AuxKernels]
  [saturation_water]
    type = PorousFlowPropertyAux
    variable = saturation_water
    property = saturation
    phase = 0
    execute_on = timestep_end
  []
  [saturation_gas]
    type = PorousFlowPropertyAux
    variable = saturation_gas
    property = saturation
    phase = 1
    execute_on = timestep_end
  []
[]

[Kernels]
  [mass0]
    type = PorousFlowMassTimeDerivative
    variable = pgas
    fluid_component = 0
  []
  [mass1]
    type = PorousFlowMassTimeDerivative
    variable = z
    fluid_component = 1
  []
[]

[UserObjects]
  [dictator]
    type = PorousFlowDictator
    porous_flow_vars = 'pgas z'
    number_fluid_phases = 2
    number_fluid_components = 2
  []
  [pc]
    type = PorousFlowCapillaryPressureConst
    pc = 0
  []
  [fs]
    type = PorousFlowBrineCO2
    brine_fp = brine
    co2_fp = co2
    capillary_pressure = pc
  []
[]

[FluidProperties]
  [co2]
    type = CO2FluidProperties
  []
  [brine]
    type = BrineFluidProperties
  []
[]

[Materials]
  [temperature]
    type = PorousFlowTemperature
    temperature = 50
  []
  [waterncg]
    type = PorousFlowFluidState
    gas_porepressure = pgas
    z = z
    fluid_state = fs
    capillary_pressure = pc
    xnacl = 0.1
  []
  [permeability]
    type = PorousFlowPermeabilityConst
    permeability = '1e-12 0 0 0 1e-12 0 0 0 1e-12'
  []
  [relperm0]
    type = PorousFlowRelativePermeabilityCorey
    n = 2
    phase = 0
  []
  [relperm1]
    type = PorousFlowRelativePermeabilityCorey
    n = 3
    phase = 1
  []
  [porosity]
    type = PorousFlowPorosityConst
    porosity = 0.1
  []
[]

[Executioner]
  type = Transient
  solve_type = NEWTON
  dt = 1
  end_time = 1
  nl_abs_tol = 1e-12
[]

[Preconditioning]
  [smp]
    type = SMP
    full = true
  []
[]

[Postprocessors]
  [sg]
    type = ElementIntegralVariablePostprocessor
    variable = saturation_gas
    execute_on = 'initial timestep_end'
  []
  [sw]
    type = ElementIntegralVariablePostprocessor
    variable = saturation_water
    execute_on = 'initial timestep_end'
  []
  [z]
    type = ElementIntegralVariablePostprocessor
    variable = z
    execute_on = 'initial timestep_end'
  []
[]

[Outputs]
  csv = true
[]

(modules/porous_flow/test/tests/sinks/injection_production_eg.i)

# phase = 0 is liquid phase
# phase = 1 is gas phase
# fluid_component = 0 is water
# fluid_component = 1 is CO2

# Constant rate of CO2 injection into the left boundary
# 1D mesh
# The PorousFlowPiecewiseLinearSinks remove the correct water and CO2 from the right boundary

# Note i take pretty big timesteps here so the system is quite nonlinear

[Mesh]
  type = GeneratedMesh
  dim = 1
  nx = 20
  xmax = 20
[]

[GlobalParams]
  PorousFlowDictator = dictator
  gravity = '0 0 0'
[]

[AuxVariables]
  [saturation_gas]
    order = CONSTANT
    family = MONOMIAL
  []
  [frac_water_in_liquid]
    initial_condition = 1.0
  []
  [frac_water_in_gas]
    initial_condition = 0.0
  []
[]

[AuxKernels]
  [saturation_gas]
    type = PorousFlowPropertyAux
    variable = saturation_gas
    property = saturation
    phase = 1
    execute_on = timestep_end
  []
[]

[Variables]
  [pwater]
    initial_condition = 20E6
  []
  [pgas]
    initial_condition = 20.1E6
  []
[]

[Kernels]
  [mass0]
    type = PorousFlowMassTimeDerivative
    fluid_component = 0
    variable = pwater
  []
  [flux0]
    type = PorousFlowAdvectiveFlux
    fluid_component = 0
    variable = pwater
  []
  [mass1]
    type = PorousFlowMassTimeDerivative
    fluid_component = 1
    variable = pgas
  []
  [flux1]
    type = PorousFlowAdvectiveFlux
    fluid_component = 1
    variable = pgas
  []
[]

[UserObjects]
  [dictator]
    type = PorousFlowDictator
    porous_flow_vars = 'pgas pwater'
    number_fluid_phases = 2
    number_fluid_components = 2
  []
  [pc]
    type = PorousFlowCapillaryPressureVG
    alpha = 1E-6
    m = 0.6
  []
[]

[FluidProperties]
  [true_water]
    type = Water97FluidProperties
  []
  [tabulated_water]
    type = TabulatedBicubicFluidProperties
    fp = true_water
    temperature_min = 275
    pressure_max = 1E8
    interpolated_properties = 'density viscosity enthalpy internal_energy'
    fluid_property_output_file = water97_tabulated_11.csv
    # Comment out the fp parameter and uncomment below to use the newly generated tabulation
    # fluid_property_file = water97_tabulated_11.csv
  []
  [true_co2]
    type = CO2FluidProperties
  []
  [tabulated_co2]
    type = TabulatedBicubicFluidProperties
    fp = true_co2
    temperature_min = 275
    pressure_max = 1E8
    interpolated_properties = 'density viscosity enthalpy internal_energy'
    fluid_property_output_file = co2_tabulated_11.csv
    # Comment out the fp parameter and uncomment below to use the newly generated tabulation
    # fluid_property_file = co2_tabulated_11.csv
  []
[]

[Materials]
  [temperature]
    type = PorousFlowTemperature
    temperature = 293.15
  []
  [saturation_calculator]
    type = PorousFlow2PhasePP
    phase0_porepressure = pwater
    phase1_porepressure = pgas
    capillary_pressure = pc
  []
  [massfrac]
    type = PorousFlowMassFraction
    mass_fraction_vars = 'frac_water_in_liquid frac_water_in_gas'
  []
  [water]
    type = PorousFlowSingleComponentFluid
    fp = tabulated_water
    phase = 0
  []
  [co2]
    type = PorousFlowSingleComponentFluid
    fp = tabulated_co2
    phase = 1
  []
  [porosity]
    type = PorousFlowPorosityConst
    porosity = 0.2
  []
  [permeability]
    type = PorousFlowPermeabilityConst
    permeability = '1e-12 0 0 0 1e-12 0 0 0 1e-12'
  []
  [relperm_water]
    type = PorousFlowRelativePermeabilityCorey
    n = 2
    phase = 0
    s_res = 0.1
    sum_s_res = 0.2
  []
  [relperm_gas]
    type = PorousFlowRelativePermeabilityBC
    nw_phase = true
    lambda = 2
    s_res = 0.1
    sum_s_res = 0.2
    phase = 1
  []
[]

[BCs]
  [co2_injection]
    type = PorousFlowSink
    boundary = left
    variable = pgas # pgas is associated with the CO2 mass balance (fluid_component = 1 in its Kernels)
    flux_function = -1E-2 # negative means a source, rather than a sink
  []

  [right_water]
    type = PorousFlowPiecewiseLinearSink
    boundary = right

    # a sink of water, since the Kernels given to pwater are for fluid_component = 0 (the water)
    variable = pwater

    # this Sink is a function of liquid porepressure
    # Also, all the mass_fraction, mobility and relperm are referenced to the liquid phase now
    fluid_phase = 0

    # Sink strength = (Pwater - 20E6)
    pt_vals = '0 1E9'
    multipliers = '0 1E9'
    PT_shift = 20E6

    # multiply Sink strength computed above by mass fraction of water at the boundary
    mass_fraction_component = 0

    # also multiply Sink strength by mobility of the liquid
    use_mobility = true

    # also multiply Sink strength by the relperm of the liquid
    use_relperm = true

    # also multiplly Sink strength by 1/L, where L is the distance to the fixed-porepressure external environment
    flux_function = 10 # 1/L
  []

  [right_co2]
    type = PorousFlowPiecewiseLinearSink
    boundary = right
    variable = pgas
    fluid_phase = 1
    pt_vals = '0 1E9'
    multipliers = '0 1E9'
    PT_shift = 20.1E6
    mass_fraction_component = 1
    use_mobility = true
    use_relperm = true
    flux_function = 10 # 1/L
  []
[]

[Preconditioning]
  active = 'basic'
  [basic]
    type = SMP
    full = true
    petsc_options = '-snes_converged_reason -ksp_diagonal_scale -ksp_diagonal_scale_fix -ksp_gmres_modifiedgramschmidt -snes_linesearch_monitor'
    petsc_options_iname = '-ksp_type -pc_type -sub_pc_type -sub_pc_factor_shift_type -pc_asm_overlap'
    petsc_options_value = 'gmres asm lu NONZERO 2'
  []
  [preferred]
    type = SMP
    full = true
    petsc_options_iname = '-pc_type -pc_factor_mat_solver_package'
    petsc_options_value = 'lu mumps'
  []
[]

[Executioner]
  type = Transient
  solve_type = NEWTON
  nl_abs_tol = 1E-13
  nl_rel_tol = 1E-10
  end_time = 1e4
  [TimeStepper]
    type = IterationAdaptiveDT
    dt = 1E4
    growth_factor = 1.1
  []
[]

[VectorPostprocessors]
  [pps]
    type = LineValueSampler
    warn_discontinuous_face_values = false
    start_point = '0 0 0'
    end_point = '20 0 0'
    num_points = 20
    sort_by = x
    variable = 'pgas pwater saturation_gas'
  []
[]

[Outputs]
  print_linear_residuals = false
  perf_graph = true
  [out]
    type = CSV
    execute_on = final
  []
[]

(modules/porous_flow/test/tests/recover/theis.i)

# Tests that PorousFlow can successfully recover using a checkpoint file.
# This test contains stateful material properties, adaptivity and integrated
# boundary conditions with nodal-sized materials.
#
# This test file is run three times:
# 1) The full input file is run to completion
# 2) The input file is run for half the time and checkpointing is included
# 3) The input file is run in recovery using the checkpoint data
#
# The final output of test 3 is compared to the final output of test 1 to verify
# that recovery was successful.

[Mesh]
  [mesh]
    type = GeneratedMeshGenerator
    dim = 1
    nx = 20
    xmax = 100
    bias_x = 1.05
  []
  coord_type = RZ
  rz_coord_axis = Y
  # To get consistent ordering of results with distributed meshes
  allow_renumbering = false
[]

[GlobalParams]
  PorousFlowDictator = dictator
  gravity = '0 0 0'
[]

[Adaptivity]
  marker = marker
  max_h_level = 4
  [Indicators]
    [front]
      type = GradientJumpIndicator
      variable = zi
    []
  []
  [Markers]
    [marker]
      type = ErrorFractionMarker
      indicator = front
      refine = 0.8
      coarsen = 0.2
    []
  []
[]

[AuxVariables]
  [saturation_gas]
    order = CONSTANT
    family = MONOMIAL
  []
  [x1]
    order = CONSTANT
    family = MONOMIAL
  []
  [y0]
    order = CONSTANT
    family = MONOMIAL
  []
[]

[AuxKernels]
  [saturation_gas]
    type = PorousFlowPropertyAux
    variable = saturation_gas
    property = saturation
    phase = 1
    execute_on = timestep_end
  []
  [x1]
    type = PorousFlowPropertyAux
    variable = x1
    property = mass_fraction
    phase = 0
    fluid_component = 1
    execute_on = timestep_end
  []
  [y0]
    type = PorousFlowPropertyAux
    variable = y0
    property = mass_fraction
    phase = 1
    fluid_component = 0
    execute_on = timestep_end
  []
[]

[Variables]
  [pgas]
    initial_condition = 20e6
  []
  [zi]
    initial_condition = 0
  []
[]

[Kernels]
  [mass0]
    type = PorousFlowMassTimeDerivative
    fluid_component = 0
    variable = pgas
  []
  [flux0]
    type = PorousFlowAdvectiveFlux
    fluid_component = 0
    variable = pgas
  []
  [mass1]
    type = PorousFlowMassTimeDerivative
    fluid_component = 1
    variable = zi
  []
  [flux1]
    type = PorousFlowAdvectiveFlux
    fluid_component = 1
    variable = zi
  []
[]

[UserObjects]
  [dictator]
    type = PorousFlowDictator
    porous_flow_vars = 'pgas zi'
    number_fluid_phases = 2
    number_fluid_components = 2
  []
  [pc]
    type = PorousFlowCapillaryPressureConst
    pc = 0
  []
  [fs]
    type = PorousFlowWaterNCG
    water_fp = water
    gas_fp = co2
    capillary_pressure = pc
  []
[]

[FluidProperties]
  [co2]
    type = CO2FluidProperties
  []
  [water]
    type = Water97FluidProperties
  []
[]

[Materials]
  [temperature]
    type = PorousFlowTemperature
    temperature = 20
  []
  [waterncg]
    type = PorousFlowFluidState
    gas_porepressure = pgas
    z = zi
    temperature_unit = Celsius
    capillary_pressure = pc
    fluid_state = fs
  []
  [porosity]
    type = PorousFlowPorosityConst
    porosity = 0.2
  []
  [permeability]
    type = PorousFlowPermeabilityConst
    permeability = '1e-12 0 0 0 1e-12 0 0 0 1e-12'
  []
  [relperm_water]
    type = PorousFlowRelativePermeabilityCorey
    n = 2
    phase = 0
    s_res = 0.1
    sum_s_res = 0.1
  []
  [relperm_gas]
    type = PorousFlowRelativePermeabilityCorey
    n = 2
    phase = 1
  []
[]

[BCs]
  [aquifer]
    type = PorousFlowPiecewiseLinearSink
    variable = pgas
    boundary = right
    pt_vals = '0 1e8'
    multipliers = '0 1e8'
    flux_function = 1e-6
    PT_shift = 20e6
  []
[]

[DiracKernels]
  [source]
    type = PorousFlowSquarePulsePointSource
    point = '0 0 0'
    mass_flux = 2
    variable = zi
  []
[]

[Preconditioning]
  [smp]
    type = SMP
    full = true
  []
[]

[Executioner]
  type = Transient
  solve_type = NEWTON
  end_time = 2e2
  dt = 50
[]

[VectorPostprocessors]
  [line]
    type = NodalValueSampler
    sort_by = x
    variable = 'pgas zi'
  []
[]

[Outputs]
  print_linear_residuals = false
  perf_graph = true
  csv = true
[]

(modules/porous_flow/test/tests/fluidstate/brineco2.i)

# Tests correct calculation of properties in PorousFlowBrineCO2

[Mesh]
  [mesh]
    type = GeneratedMeshGenerator
    dim = 2
  []
[]

[GlobalParams]
  PorousFlowDictator = dictator
  temperature = 30
[]

[Variables]
  [pgas]
    initial_condition = 20e6
  []
  [z]
     initial_condition = 0.2
  []
[]

[AuxVariables]
  [xnacl]
    initial_condition = 0.1
  []
  [pressure_gas]
    order = CONSTANT
    family = MONOMIAL
  []
  [pressure_water]
    order = CONSTANT
    family = MONOMIAL
  []
  [saturation_gas]
    order = CONSTANT
    family = MONOMIAL
  []
  [saturation_water]
    order = CONSTANT
    family = MONOMIAL
  []
  [density_water]
    order = CONSTANT
    family = MONOMIAL
  []
  [density_gas]
    order = CONSTANT
    family = MONOMIAL
  []
  [viscosity_water]
    order = CONSTANT
    family = MONOMIAL
  []
  [viscosity_gas]
    order = CONSTANT
    family = MONOMIAL
  []
  [enthalpy_water]
    order = CONSTANT
    family = MONOMIAL
  []
  [enthalpy_gas]
    order = CONSTANT
    family = MONOMIAL
  []
  [internal_energy_water]
    order = CONSTANT
    family = MONOMIAL
  []
  [internal_energy_gas]
    order = CONSTANT
    family = MONOMIAL
  []
  [x0_water]
    order = CONSTANT
    family = MONOMIAL
  []
  [x0_gas]
    order = CONSTANT
    family = MONOMIAL
  []
  [x1_water]
    order = CONSTANT
    family = MONOMIAL
  []
  [x1_gas]
    order = CONSTANT
    family = MONOMIAL
  []
[]

[AuxKernels]
  [pressure_water]
    type = PorousFlowPropertyAux
    variable = pressure_water
    property = pressure
    phase = 0
    execute_on = timestep_end
  []
  [pressure_gas]
    type = PorousFlowPropertyAux
    variable = pressure_gas
    property = pressure
    phase = 1
    execute_on = timestep_end
  []
  [saturation_water]
    type = PorousFlowPropertyAux
    variable = saturation_water
    property = saturation
    phase = 0
    execute_on = timestep_end
  []
  [saturation_gas]
    type = PorousFlowPropertyAux
    variable = saturation_gas
    property = saturation
    phase = 1
    execute_on = timestep_end
  []
  [density_water]
    type = PorousFlowPropertyAux
    variable = density_water
    property = density
    phase = 0
    execute_on = timestep_end
  []
  [density_gas]
    type = PorousFlowPropertyAux
    variable = density_gas
    property = density
    phase = 1
    execute_on = timestep_end
  []
  [viscosity_water]
    type = PorousFlowPropertyAux
    variable = viscosity_water
    property = viscosity
    phase = 0
    execute_on = timestep_end
  []
  [viscosity_gas]
    type = PorousFlowPropertyAux
    variable = viscosity_gas
    property = viscosity
    phase = 1
    execute_on = timestep_end
  []
  [enthalpy_water]
    type = PorousFlowPropertyAux
    variable = enthalpy_water
    property = enthalpy
    phase = 0
    execute_on = timestep_end
  []
  [enthalpy_gas]
    type = PorousFlowPropertyAux
    variable = enthalpy_gas
    property = enthalpy
    phase = 1
    execute_on = timestep_end
  []
  [internal_energy_water]
    type = PorousFlowPropertyAux
    variable = internal_energy_water
    property = internal_energy
    phase = 0
    execute_on = timestep_end
  []
  [internal_energy_gas]
    type = PorousFlowPropertyAux
    variable = internal_energy_gas
    property = internal_energy
    phase = 1
    execute_on = timestep_end
  []
  [x1_water]
    type = PorousFlowPropertyAux
    variable = x1_water
    property = mass_fraction
    phase = 0
    fluid_component = 1
    execute_on = timestep_end
  []
  [x1_gas]
    type = PorousFlowPropertyAux
    variable = x1_gas
    property = mass_fraction
    phase = 1
    fluid_component = 1
    execute_on = timestep_end
  []
  [x0_water]
    type = PorousFlowPropertyAux
    variable = x0_water
    property = mass_fraction
    phase = 0
    fluid_component = 0
    execute_on = timestep_end
  []
  [x0_gas]
    type = PorousFlowPropertyAux
    variable = x0_gas
    property = mass_fraction
    phase = 1
    fluid_component = 0
    execute_on = timestep_end
  []
[]

[Kernels]
  [mass0]
    type = NullKernel
    variable = pgas
  []
  [mass1]
    type = NullKernel
    variable = z
  []
[]

[UserObjects]
  [dictator]
    type = PorousFlowDictator
    porous_flow_vars = 'pgas z'
    number_fluid_phases = 2
    number_fluid_components = 2
  []
  [pc]
    type = PorousFlowCapillaryPressureConst
    pc = 0
  []
  [fs]
    type = PorousFlowBrineCO2
    brine_fp = brine
    co2_fp = co2
    capillary_pressure = pc
  []
[]

[FluidProperties]
  [co2]
    type = CO2FluidProperties
  []
  [brine]
    type = BrineFluidProperties
  []
[]

[Materials]
  [temperature]
    type = PorousFlowTemperature
  []
  [brineco2]
    type = PorousFlowFluidState
    gas_porepressure = pgas
    z = z
    temperature_unit = Celsius
    xnacl = xnacl
    capillary_pressure = pc
    fluid_state = fs
  []
  [porosity]
    type = PorousFlowPorosityConst
    porosity = 0.1
  []
[]

[Executioner]
  type = Transient
  solve_type = NEWTON
  dt = 1
  end_time = 1
  nl_abs_tol = 1e-12
[]

[Preconditioning]
  [smp]
    type = SMP
    full = true
  []
[]

[Postprocessors]
  [density_water]
    type = ElementIntegralVariablePostprocessor
    variable = density_water
  []
  [density_gas]
    type = ElementIntegralVariablePostprocessor
    variable = density_gas
  []
  [viscosity_water]
    type = ElementIntegralVariablePostprocessor
    variable = viscosity_water
  []
  [viscosity_gas]
    type = ElementIntegralVariablePostprocessor
    variable = viscosity_gas
  []
  [enthalpy_water]
    type = ElementIntegralVariablePostprocessor
    variable = enthalpy_water
  []
  [enthalpy_gas]
    type = ElementIntegralVariablePostprocessor
    variable = enthalpy_gas
  []
  [internal_energy_water]
    type = ElementIntegralVariablePostprocessor
    variable = internal_energy_water
  []
  [internal_energy_gas]
    type = ElementIntegralVariablePostprocessor
    variable = internal_energy_gas
  []
  [x1_water]
    type = ElementIntegralVariablePostprocessor
    variable = x1_water
  []
  [x0_water]
    type = ElementIntegralVariablePostprocessor
    variable = x0_water
  []
  [x1_gas]
    type = ElementIntegralVariablePostprocessor
    variable = x1_gas
  []
  [x0_gas]
    type = ElementIntegralVariablePostprocessor
    variable = x0_gas
  []
  [sg]
    type = ElementIntegralVariablePostprocessor
    variable = saturation_gas
  []
  [sw]
    type = ElementIntegralVariablePostprocessor
    variable = saturation_water
  []
  [pwater]
    type = ElementIntegralVariablePostprocessor
    variable = pressure_water
  []
  [pgas]
    type = ElementIntegralVariablePostprocessor
    variable = pressure_gas
  []
  [x0mass]
    type = PorousFlowFluidMass
    fluid_component = 0
    phase = '0 1'
  []
  [x1mass]
    type = PorousFlowFluidMass
    fluid_component = 1
    phase = '0 1'
  []
[]

[Outputs]
  csv = true
  file_base = brineco2
  execute_on = 'TIMESTEP_END'
  perf_graph = false
[]

(modules/porous_flow/test/tests/jacobian/waterncg_gas.i)

# Tests correct calculation of properties derivatives in PorousFlowWaterNCG
# for conditions that give a single gas phase

[Mesh]
  type = GeneratedMesh
  dim = 2
  nx = 2
  ny = 2
[]

[GlobalParams]
  PorousFlowDictator = dictator
  gravity = '0 0 0'
[]

[Variables]
  [pgas]
  []
  [z]
  []
[]

[ICs]
  [pgas]
    type = RandomIC
    min = 1e4
    max = 4e4
    variable = pgas
  []
  [z]
    type = RandomIC
    min = 0.88
    max = 0.98
    variable = z
  []
[]

[Kernels]
  [mass0]
    type = PorousFlowMassTimeDerivative
    variable = pgas
    fluid_component = 0
  []
  [mass1]
    type = PorousFlowMassTimeDerivative
    variable = z
    fluid_component = 1
  []
  [adv0]
    type = PorousFlowAdvectiveFlux
    variable = pgas
    fluid_component = 0
  []
  [adv1]
    type = PorousFlowAdvectiveFlux
    variable = z
    fluid_component = 1
  []
[]

[UserObjects]
  [dictator]
    type = PorousFlowDictator
    porous_flow_vars = 'pgas z'
    number_fluid_phases = 2
    number_fluid_components = 2
  []
  [pc]
    type = PorousFlowCapillaryPressureVG
    m = 0.5
    alpha = 1
    pc_max = 1e3
  []
  [fs]
    type = PorousFlowWaterNCG
    water_fp = water
    gas_fp = co2
    capillary_pressure = pc
  []
[]

[FluidProperties]
  [co2]
    type = CO2FluidProperties
  []
  [water]
    type = Water97FluidProperties
  []
[]

[Materials]
  [temperature]
    type = PorousFlowTemperature
    temperature = 50
  []
  [waterncg]
    type = PorousFlowFluidState
    gas_porepressure = pgas
    z = z
    temperature_unit = Celsius
    capillary_pressure = pc
    fluid_state = fs
  []
  [permeability]
    type = PorousFlowPermeabilityConst
    permeability = '1e-12 0 0 0 1e-12 0 0 0 1e-12'
  []
  [relperm0]
    type = PorousFlowRelativePermeabilityCorey
    n = 2
    phase = 0
  []
  [relperm1]
    type = PorousFlowRelativePermeabilityCorey
    n = 3
    phase = 1
  []
  [porosity]
    type = PorousFlowPorosityConst
    porosity = 0.1
  []
[]

[Executioner]
  type = Transient
  solve_type = NEWTON
  dt = 1
  end_time = 1
  nl_abs_tol = 1e-12
[]

[Preconditioning]
  [smp]
    type = SMP
    full = true
  []
[]

[AuxVariables]
  [sgas]
    family = MONOMIAL
    order = CONSTANT
  []
[]

[AuxKernels]
  [sgas]
    type = PorousFlowPropertyAux
    property = saturation
    phase = 1
    variable = sgas
  []
[]

[Postprocessors]
  [sgas_min]
    type = ElementExtremeValue
    variable = sgas
    value_type = min
  []
  [sgas_max]
    type = ElementExtremeValue
    variable = sgas
    value_type = max
  []
[]

(modules/porous_flow/test/tests/jacobian/waterncg_liquid.i)

# Tests correct calculation of properties derivatives in PorousFlowWaterNCG
# for conditions that give a single liquid phase

[Mesh]
  type = GeneratedMesh
  dim = 2
  nx = 2
  ny = 2
[]

[GlobalParams]
  PorousFlowDictator = dictator
  gravity = '0 0 0'
[]

[Variables]
  [pgas]
  []
  [z]
  []
[]

[ICs]
  [pgas]
    type = RandomIC
    min = 6e6
    max = 8e6
    variable = pgas
  []
  [z]
    type = RandomIC
    min = 0.01
    max = 0.05
    variable = z
  []
[]

[Kernels]
  [mass0]
    type = PorousFlowMassTimeDerivative
    variable = pgas
    fluid_component = 0
  []
  [mass1]
    type = PorousFlowMassTimeDerivative
    variable = z
    fluid_component = 1
  []
  [adv0]
    type = PorousFlowAdvectiveFlux
    variable = pgas
    fluid_component = 0
  []
  [adv1]
    type = PorousFlowAdvectiveFlux
    variable = z
    fluid_component = 1
  []
[]

[UserObjects]
  [dictator]
    type = PorousFlowDictator
    porous_flow_vars = 'pgas z'
    number_fluid_phases = 2
    number_fluid_components = 2
  []
  [pc]
    type = PorousFlowCapillaryPressureVG
    m = 0.5
    alpha = 1
    pc_max = 1e4
  []
  [fs]
    type = PorousFlowWaterNCG
    water_fp = water
    gas_fp = co2
    capillary_pressure = pc
  []
[]

[FluidProperties]
  [co2]
    type = CO2FluidProperties
  []
  [water]
    type = Water97FluidProperties
  []
[]

[Materials]
  [temperature]
    type = PorousFlowTemperature
    temperature = 50
  []
  [waterncg]
    type = PorousFlowFluidState
    gas_porepressure = pgas
    z = z
    temperature_unit = Celsius
    capillary_pressure = pc
    fluid_state = fs
  []
  [permeability]
    type = PorousFlowPermeabilityConst
    permeability = '1e-12 0 0 0 1e-12 0 0 0 1e-12'
  []
  [relperm0]
    type = PorousFlowRelativePermeabilityCorey
    n = 2
    phase = 0
  []
  [relperm1]
    type = PorousFlowRelativePermeabilityCorey
    n = 3
    phase = 1
  []
  [porosity]
    type = PorousFlowPorosityConst
    porosity = 0.1
  []
[]

[Executioner]
  type = Transient
  solve_type = NEWTON
  dt = 1
  end_time = 1
  nl_abs_tol = 1e-12
[]

[Preconditioning]
  [smp]
    type = SMP
    full = true
  []
[]

[AuxVariables]
  [sgas]
    family = MONOMIAL
    order = CONSTANT
  []
[]

[AuxKernels]
  [sgas]
    type = PorousFlowPropertyAux
    property = saturation
    phase = 1
    variable = sgas
  []
[]

[Postprocessors]
  [sgas_min]
    type = ElementExtremeValue
    variable = sgas
    value_type = min
  []
  [sgas_max]
    type = ElementExtremeValue
    variable = sgas
    value_type = max
  []
[]

(modules/porous_flow/test/tests/fluidstate/brineco2_hightemp.i)

# Tests correct calculation of properties in PorousFlowBrineCO2 in the elevated
# temperature regime (T > 110C)

[Mesh]
  type = GeneratedMesh
  dim = 2
[]

[GlobalParams]
  PorousFlowDictator = dictator
  temperature = 250
[]

[Variables]
  [pgas]
    initial_condition = 20e6
  []
  [z]
     initial_condition = 0.2
  []
[]

[AuxVariables]
  [xnacl]
    initial_condition = 0.1
  []
  [pressure_gas]
    order = CONSTANT
    family = MONOMIAL
  []
  [pressure_water]
    order = CONSTANT
    family = MONOMIAL
  []
  [saturation_gas]
    order = CONSTANT
    family = MONOMIAL
  []
  [saturation_water]
    order = CONSTANT
    family = MONOMIAL
  []
  [density_water]
    order = CONSTANT
    family = MONOMIAL
  []
  [density_gas]
    order = CONSTANT
    family = MONOMIAL
  []
  [viscosity_water]
    order = CONSTANT
    family = MONOMIAL
  []
  [viscosity_gas]
    order = CONSTANT
    family = MONOMIAL
  []
  [x0_water]
    order = CONSTANT
    family = MONOMIAL
  []
  [x0_gas]
    order = CONSTANT
    family = MONOMIAL
  []
  [x1_water]
    order = CONSTANT
    family = MONOMIAL
  []
  [x1_gas]
    order = CONSTANT
    family = MONOMIAL
  []
[]

[AuxKernels]
  [pressure_water]
    type = PorousFlowPropertyAux
    variable = pressure_water
    property = pressure
    phase = 0
    execute_on = timestep_end
  []
  [pressure_gas]
    type = PorousFlowPropertyAux
    variable = pressure_gas
    property = pressure
    phase = 1
    execute_on = timestep_end
  []
  [saturation_water]
    type = PorousFlowPropertyAux
    variable = saturation_water
    property = saturation
    phase = 0
    execute_on = timestep_end
  []
  [saturation_gas]
    type = PorousFlowPropertyAux
    variable = saturation_gas
    property = saturation
    phase = 1
    execute_on = timestep_end
  []
  [density_water]
    type = PorousFlowPropertyAux
    variable = density_water
    property = density
    phase = 0
    execute_on = timestep_end
  []
  [density_gas]
    type = PorousFlowPropertyAux
    variable = density_gas
    property = density
    phase = 1
    execute_on = timestep_end
  []
  [viscosity_water]
    type = PorousFlowPropertyAux
    variable = viscosity_water
    property = viscosity
    phase = 0
    execute_on = timestep_end
  []
  [viscosity_gas]
    type = PorousFlowPropertyAux
    variable = viscosity_gas
    property = viscosity
    phase = 1
    execute_on = timestep_end
  []
  [x1_water]
    type = PorousFlowPropertyAux
    variable = x1_water
    property = mass_fraction
    phase = 0
    fluid_component = 1
    execute_on = timestep_end
  []
  [x1_gas]
    type = PorousFlowPropertyAux
    variable = x1_gas
    property = mass_fraction
    phase = 1
    fluid_component = 1
    execute_on = timestep_end
  []
  [x0_water]
    type = PorousFlowPropertyAux
    variable = x0_water
    property = mass_fraction
    phase = 0
    fluid_component = 0
    execute_on = timestep_end
  []
  [x0_gas]
    type = PorousFlowPropertyAux
    variable = x0_gas
    property = mass_fraction
    phase = 1
    fluid_component = 0
    execute_on = timestep_end
  []
[]

[Kernels]
  [mass0]
    type = PorousFlowMassTimeDerivative
    variable = pgas
    fluid_component = 0
  []
  [mass1]
    type = PorousFlowMassTimeDerivative
    variable = z
    fluid_component = 1
  []
[]

[UserObjects]
  [dictator]
    type = PorousFlowDictator
    porous_flow_vars = 'pgas z'
    number_fluid_phases = 2
    number_fluid_components = 2
  []
  [pc]
    type = PorousFlowCapillaryPressureConst
    pc = 0
  []
  [fs]
    type = PorousFlowBrineCO2
    brine_fp = brine
    co2_fp = co2
    capillary_pressure = pc
  []
[]

[FluidProperties]
  [co2]
    type = CO2FluidProperties
  []
  [brine]
    type = BrineFluidProperties
  []
[]

[Materials]
  [temperature]
    type = PorousFlowTemperature
  []
  [brineco2]
    type = PorousFlowFluidState
    gas_porepressure = pgas
    z = z
    temperature_unit = Celsius
    xnacl = xnacl
    capillary_pressure = pc
    fluid_state = fs
  []
  [permeability]
    type = PorousFlowPermeabilityConst
    permeability = '1e-12 0 0 0 1e-12 0 0 0 1e-12'
  []
  [relperm0]
    type = PorousFlowRelativePermeabilityCorey
    n = 2
    phase = 0
  []
  [relperm1]
    type = PorousFlowRelativePermeabilityCorey
    n = 3
    phase = 1
  []
  [porosity]
    type = PorousFlowPorosityConst
    porosity = 0.1
  []
[]

[Executioner]
  type = Transient
  solve_type = NEWTON
  dt = 1
  end_time = 1
  nl_abs_tol = 1e-12
[]

[Preconditioning]
  [smp]
    type = SMP
    full = true
  []
[]

[Postprocessors]
  [density_water]
    type = ElementIntegralVariablePostprocessor
    variable = density_water
  []
  [density_gas]
    type = ElementIntegralVariablePostprocessor
    variable = density_gas
  []
  [viscosity_water]
    type = ElementIntegralVariablePostprocessor
    variable = viscosity_water
  []
  [viscosity_gas]
    type = ElementIntegralVariablePostprocessor
    variable = viscosity_gas
  []
  [x1_water]
    type = ElementIntegralVariablePostprocessor
    variable = x1_water
  []
  [x0_water]
    type = ElementIntegralVariablePostprocessor
    variable = x0_water
  []
  [x1_gas]
    type = ElementIntegralVariablePostprocessor
    variable = x1_gas
  []
  [x0_gas]
    type = ElementIntegralVariablePostprocessor
    variable = x0_gas
  []
  [sg]
    type = ElementIntegralVariablePostprocessor
    variable = saturation_gas
  []
  [sw]
    type = ElementIntegralVariablePostprocessor
    variable = saturation_water
  []
  [pwater]
    type = ElementIntegralVariablePostprocessor
    variable = pressure_water
  []
  [pgas]
    type = ElementIntegralVariablePostprocessor
    variable = pressure_gas
  []
  [x0mass]
    type = PorousFlowFluidMass
    fluid_component = 0
    phase = '0 1'
  []
  [x1mass]
    type = PorousFlowFluidMass
    fluid_component = 1
    phase = '0 1'
  []
[]

[Outputs]
  csv = true
  execute_on = 'TIMESTEP_END'
  perf_graph = false
[]

(modules/porous_flow/test/tests/jacobian/brineco2_twophase.i)

# Tests correct calculation of properties derivatives in PorousFlowFluidState
# for conditions that are appropriate for two phases

[Mesh]
  type = GeneratedMesh
  dim = 2
  nx = 2
  ny = 2
[]

[GlobalParams]
  PorousFlowDictator = dictator
  gravity = '0 0 0'
[]

[AuxVariables]
  [xnacl]
    initial_condition = 0.05
  []
[]

[Variables]
  [pgas]
  []
  [zi]
  []
[]

[ICs]
  [pgas]
    type = RandomIC
    min = 1e6
    max = 4e6
    variable = pgas
    seed = 1
  []
  [z]
    type = RandomIC
    min = 0.2
    max = 0.8
    variable = zi
    seed = 2
  []
[]

[Kernels]
  [mass0]
    type = PorousFlowMassTimeDerivative
    variable = pgas
    fluid_component = 0
  []
  [mass1]
    type = PorousFlowMassTimeDerivative
    variable = zi
    fluid_component = 1
  []
  [adv0]
    type = PorousFlowAdvectiveFlux
    variable = pgas
    fluid_component = 0
  []
  [adv1]
    type = PorousFlowAdvectiveFlux
    variable = zi
    fluid_component = 1
  []
[]

[UserObjects]
  [dictator]
    type = PorousFlowDictator
    porous_flow_vars = 'pgas zi'
    number_fluid_phases = 2
    number_fluid_components = 2
  []
  [pc]
    type = PorousFlowCapillaryPressureVG
    m = 0.5
    alpha = 1e1
    pc_max = 1e4
  []
  [fs]
    type = PorousFlowBrineCO2
    brine_fp = brine
    co2_fp = co2
    capillary_pressure = pc
  []
[]

[FluidProperties]
  [co2]
    type = CO2FluidProperties
  []
  [brine]
    type = BrineFluidProperties
  []
  [water]
    type = Water97FluidProperties
  []
[]

[Materials]
  [temperature]
    type = PorousFlowTemperature
    temperature = 50
  []
  [brineco2]
    type = PorousFlowFluidState
    gas_porepressure = pgas
    z = zi
    temperature_unit = Celsius
    xnacl = xnacl
    capillary_pressure = pc
    fluid_state = fs
  []
  [permeability]
    type = PorousFlowPermeabilityConst
    permeability = '1e-12 0 0 0 1e-12 0 0 0 1e-12'
  []
  [relperm0]
    type = PorousFlowRelativePermeabilityCorey
    n = 2
    phase = 0
  []
  [relperm1]
    type = PorousFlowRelativePermeabilityCorey
    n = 3
    phase = 1
  []
  [porosity]
    type = PorousFlowPorosityConst
    porosity = 0.1
  []
[]

[Executioner]
  type = Transient
  solve_type = NEWTON
  dt = 1
  end_time = 1
  nl_abs_tol = 1e-12
[]

[Preconditioning]
  [smp]
    type = SMP
    full = true
  []
[]

[AuxVariables]
  [sgas]
    family = MONOMIAL
    order = CONSTANT
  []
[]

[AuxKernels]
  [sgas]
    type = PorousFlowPropertyAux
    property = saturation
    phase = 1
    variable = sgas
  []
[]

[Postprocessors]
  [sgas_min]
    type = ElementExtremeValue
    variable = sgas
    value_type = min
  []
  [sgas_max]
    type = ElementExtremeValue
    variable = sgas
    value_type = max
  []
[]

(modules/porous_flow/test/tests/jacobian/brineco2_liquid.i)

# Tests correct calculation of properties derivatives in PorousFlowFluidState
# for conditions that give a single liquid phase

[Mesh]
  type = GeneratedMesh
  dim = 2
  nx = 2
  ny = 2
[]

[GlobalParams]
  PorousFlowDictator = dictator
  gravity = '0 0 0'
[]

[AuxVariables]
  [xnacl]
    initial_condition = 0.05
  []
[]

[Variables]
  [pgas]
  []
  [zi]
  []
[]

[ICs]
  [pgas]
    type = RandomIC
    min = 5e6
    max = 8e6
    variable = pgas
  []
  [z_liquid]
    type = RandomIC
    min = 0.01
    max = 0.03
    variable = zi
  []
[]

[Kernels]
  [mass0]
    type = PorousFlowMassTimeDerivative
    variable = pgas
    fluid_component = 0
  []
  [mass1]
    type = PorousFlowMassTimeDerivative
    variable = zi
    fluid_component = 1
  []
  [adv0]
    type = PorousFlowAdvectiveFlux
    variable = pgas
    fluid_component = 0
  []
  [adv1]
    type = PorousFlowAdvectiveFlux
    variable = zi
    fluid_component = 1
  []
[]

[UserObjects]
  [dictator]
    type = PorousFlowDictator
    porous_flow_vars = 'pgas zi'
    number_fluid_phases = 2
    number_fluid_components = 2
  []
  [pc]
    type = PorousFlowCapillaryPressureVG
    m = 0.5
    alpha = 1
    pc_max = 1e4
  []
  [fs]
    type = PorousFlowBrineCO2
    brine_fp = brine
    co2_fp = co2
    capillary_pressure = pc
  []
[]

[FluidProperties]
  [co2]
    type = CO2FluidProperties
  []
  [brine]
    type = BrineFluidProperties
  []
  [water]
    type = Water97FluidProperties
  []
[]

[Materials]
  [temperature]
    type = PorousFlowTemperature
    temperature = 50
  []
  [brineco2]
    type = PorousFlowFluidState
    gas_porepressure = pgas
    z = zi
    temperature_unit = Celsius
    xnacl = xnacl
    capillary_pressure = pc
    fluid_state = fs
  []
  [permeability]
    type = PorousFlowPermeabilityConst
    permeability = '1e-12 0 0 0 1e-12 0 0 0 1e-12'
  []
  [relperm0]
    type = PorousFlowRelativePermeabilityCorey
    n = 2
    phase = 0
  []
  [relperm1]
    type = PorousFlowRelativePermeabilityCorey
    n = 3
    phase = 1
  []
  [porosity]
    type = PorousFlowPorosityConst
    porosity = 0.1
  []
[]

[Executioner]
  type = Transient
  solve_type = NEWTON
  dt = 1
  end_time = 1
  nl_abs_tol = 1e-12
[]

[Preconditioning]
  [smp]
    type = SMP
    full = true
  []
[]

[AuxVariables]
  [sgas]
    family = MONOMIAL
    order = CONSTANT
  []
[]

[AuxKernels]
  [sgas]
    type = PorousFlowPropertyAux
    property = saturation
    phase = 1
    variable = sgas
  []
[]

[Postprocessors]
  [sgas_min]
    type = ElementExtremeValue
    variable = sgas
    value_type = min
  []
  [sgas_max]
    type = ElementExtremeValue
    variable = sgas
    value_type = max
  []
[]

(modules/porous_flow/examples/co2_intercomparison/1Dradial/properties.i)

# Liquid and gas properties for code intercomparison problem 3
#
# From Pruess et al, Code intercomparison builds confidence in
# numerical simulation models for geologic disposal of CO2, Energy 29 (2004)
#
# This test simply calculates density and viscosity of each phase for
# various pressures and salinities, as well as mass fractions of CO2 in the
# liquid phase and H2O in the gas phase.
#
# Four versions of this are run:
# 1) No CO2, 0 salt mass fraction (pure water)
# 2) Enough CO2 to form gas phase, 0 salt mass fraction (pure water)
# 3) No CO2, 0.15 salt mass fraction
# 4) Enough CO2 to form gas phase, 0.15 salt mass fraction
#
# These results compare well with detailed results presented in Pruess et al,
# Intercomparison of numerical simulation codes for geologic disposal of CO2,
# LBNL-51813 (2002)

[Mesh]
  type = GeneratedMesh
  dim = 2
  nx = 4
  xmax = 4

  # To get consistent ordering of results with distributed meshes
  allow_renumbering = false
[]

[GlobalParams]
  PorousFlowDictator = dictator
[]

[AuxVariables]
  [density_liquid]
    order = CONSTANT
    family = MONOMIAL
  []
  [density_gas]
    order = CONSTANT
    family = MONOMIAL
  []
  [viscosity_liquid]
    order = CONSTANT
    family = MONOMIAL
  []
  [viscosity_gas]
    order = CONSTANT
    family = MONOMIAL
  []
  [x1]
    order = CONSTANT
    family = MONOMIAL
  []
  [y0]
    order = CONSTANT
    family = MONOMIAL
  []
  [xnacl]
    initial_condition = 0.0
  []
[]

[AuxKernels]
  [density_liquid]
    type = PorousFlowPropertyAux
    variable = density_liquid
    property = density
    phase = 0
    execute_on = timestep_end
  []
  [density_gas]
    type = PorousFlowPropertyAux
    variable = density_gas
    property = density
    phase = 1
    execute_on = timestep_end
  []
  [viscosity_liquid]
    type = PorousFlowPropertyAux
    variable = viscosity_liquid
    property = viscosity
    phase = 0
    execute_on = timestep_end
  []
  [viscosity_gas]
    type = PorousFlowPropertyAux
    variable = viscosity_gas
    property = viscosity
    phase = 1
    execute_on = timestep_end
  []
  [x1]
    type = PorousFlowPropertyAux
    variable = x1
    property = mass_fraction
    phase = 0
    fluid_component = 1
    execute_on = timestep_end
  []
  [y0]
    type = PorousFlowPropertyAux
    variable = y0
    property = mass_fraction
    phase = 1
    fluid_component = 0
    execute_on = timestep_end
  []
[]

[Variables]
  [pgas]
    order = CONSTANT
    family = MONOMIAL
  []
  [zi]
    initial_condition = 0.0
  []
[]

[Functions]
  [pic]
    type = ParsedFunction
    expression = 'if(x<1,12e6,if(x<2,16e6,if(x<3,20e6,24e6)))'
  []
[]

[ICs]
  [pic]
    type = FunctionIC
    function = pic
    variable = pgas
  []
[]

[Kernels]
  [diffusionp]
    type = NullKernel
    variable = pgas
  []
  [diffusionz]
    type = NullKernel
    variable = zi
  []
[]

[UserObjects]
  [dictator]
    type = PorousFlowDictator
    porous_flow_vars = 'pgas zi'
    number_fluid_phases = 2
    number_fluid_components = 2
  []
  [pc]
    type = PorousFlowCapillaryPressureConst
    pc = 0
  []
  [fs]
    type = PorousFlowBrineCO2
    brine_fp = brine
    co2_fp = co2
    capillary_pressure = pc
  []
[]

[FluidProperties]
  [co2]
    type = CO2FluidProperties
  []
  [brine]
    type = BrineFluidProperties
  []
[]

[Materials]
  [temperature]
    type = PorousFlowTemperature
    temperature = 45
  []
  [brineco2]
    type = PorousFlowFluidState
    gas_porepressure = pgas
    z = zi
    temperature_unit = Celsius
    xnacl = xnacl
    capillary_pressure = pc
    fluid_state = fs
  []
[]

[Preconditioning]
  [smp]
    type = SMP
    full = true
    petsc_options_iname = '-ksp_type -pc_type -sub_pc_type -sub_pc_factor_shift_type -pc_asm_overlap'
    petsc_options_value = 'gmres      asm      lu           NONZERO                   2             '
  []
[]

[Executioner]
  type = Steady
  solve_type = NEWTON
[]

[Outputs]
  perf_graph = true
  csv = true
  execute_on = timestep_end
  file_base = properties_water
[]

[VectorPostprocessors]
  [vpp]
    type = ElementValueSampler
    variable = 'pgas density_liquid density_gas viscosity_liquid viscosity_gas x1 y0'
    sort_by = x
  []
[]

(modules/porous_flow/test/tests/jacobian/brineco2_twophase_nonisothermal.i)

# Tests correct calculation of properties derivatives in PorousFlowFluidState
# for nonisothermal two phase conditions, including salt as a nonlinear variable

[Mesh]
  [mesh]
    type = GeneratedMeshGenerator
    dim = 2
    nx = 2
    ny = 2
    xmax = 10
    ymax = 10
  []
[]

[GlobalParams]
  PorousFlowDictator = dictator
  gravity = '0 0 0'
[]

[Variables]
  [pgas]
  []
  [zi]
    scaling = 1e-4
  []
  [xnacl]
  []
  [temperature]
    scaling = 1e-7
  []
[]

[ICs]
  [pgas]
    type = RandomIC
    min = 1e6
    max = 4e6
    variable = pgas
    seed = 1
  []
  [z]
    type = RandomIC
    min = 0.2
    max = 0.8
    variable = zi
    seed = 1
  []
  [xnacl]
    type = RandomIC
    min = 0.01
    max = 0.15
    variable = xnacl
    seed = 1
  []
  [temperature]
    type = RandomIC
    min = 20
    max = 80
    variable = temperature
  []
[]

[Kernels]
  [mass0]
    type = PorousFlowMassTimeDerivative
    variable = pgas
    fluid_component = 0
  []
  [mass1]
    type = PorousFlowMassTimeDerivative
    variable = zi
    fluid_component = 1
  []
  [mass2]
    type = PorousFlowMassTimeDerivative
    variable = xnacl
    fluid_component = 2
  []
  [adv0]
    type = PorousFlowAdvectiveFlux
    variable = pgas
    fluid_component = 0
  []
  [adv1]
    type = PorousFlowAdvectiveFlux
    variable = zi
    fluid_component = 1
  []
  [adv2]
    type = PorousFlowAdvectiveFlux
    variable = xnacl
    fluid_component = 2
  []
  [energy]
    type = PorousFlowEnergyTimeDerivative
    variable = temperature
  []
  [heat]
    type = PorousFlowHeatAdvection
    variable = temperature
  []
[]

[UserObjects]
  [dictator]
    type = PorousFlowDictator
    porous_flow_vars = 'pgas zi xnacl temperature'
    number_fluid_phases = 2
    number_fluid_components = 3
  []
  [pc]
    type = PorousFlowCapillaryPressureVG
    m = 0.5
    alpha = 1
    pc_max = 1e3
  []
  [fs]
    type = PorousFlowBrineCO2
    brine_fp = brine
    co2_fp = co2
    capillary_pressure = pc
  []
[]

[FluidProperties]
  [co2]
    type = CO2FluidProperties
  []
  [brine]
    type = BrineFluidProperties
  []
[]

[Materials]
  [temperature]
    type = PorousFlowTemperature
    temperature = temperature
  []
  [brineco2]
    type = PorousFlowFluidState
    gas_porepressure = pgas
    z = zi
    temperature = temperature
    temperature_unit = Celsius
    xnacl = xnacl
    capillary_pressure = pc
    fluid_state = fs
  []
  [permeability]
    type = PorousFlowPermeabilityConst
    permeability = '1e-12 0 0 0 1e-12 0 0 0 1e-12'
  []
  [relperm0]
    type = PorousFlowRelativePermeabilityCorey
    n = 2
    phase = 0
  []
  [relperm1]
    type = PorousFlowRelativePermeabilityCorey
    n = 3
    phase = 1
  []
  [porosity]
    type = PorousFlowPorosityConst
    porosity = 0.1
  []
  [rock_heat]
    type = PorousFlowMatrixInternalEnergy
    specific_heat_capacity = 1000
    density = 2500
  []
[]

[Executioner]
  type = Transient
  solve_type = NEWTON
  dt = 1
  end_time = 1
  nl_abs_tol = 1e-12
[]

[Preconditioning]
  [smp]
    type = SMP
    full = true
  []
[]

(modules/porous_flow/test/tests/jacobian/brineco2_liquid_2.i)

# Tests correct calculation of properties derivatives in PorousFlowFluidState
# for conditions that give a single liquid phase, including salt as a nonlinear variable

[Mesh]
  type = GeneratedMesh
  dim = 2
  nx = 2
  ny = 2
[]

[GlobalParams]
  PorousFlowDictator = dictator
  gravity = '0 0 0'
[]

[Variables]
  [pgas]
  []
  [zi]
  []
  [xnacl]
  []
[]

[ICs]
  [pgas]
    type = RandomIC
    min = 5e6
    max = 8e6
    variable = pgas
  []
  [z]
    type = RandomIC
    min = 0.01
    max = 0.03
    variable = zi
  []
  [xnacl]
    type = RandomIC
    min = 0.01
    max = 0.15
    variable = xnacl
  []
[]

[Kernels]
  [mass0]
    type = PorousFlowMassTimeDerivative
    variable = pgas
    fluid_component = 0
  []
  [mass1]
    type = PorousFlowMassTimeDerivative
    variable = zi
    fluid_component = 1
  []
  [mass2]
    type = PorousFlowMassTimeDerivative
    variable = xnacl
    fluid_component = 2
  []
  [adv0]
    type = PorousFlowAdvectiveFlux
    variable = pgas
    fluid_component = 0
  []
  [adv1]
    type = PorousFlowAdvectiveFlux
    variable = zi
    fluid_component = 1
  []
  [adv2]
    type = PorousFlowAdvectiveFlux
    variable = xnacl
    fluid_component = 2
  []
[]

[UserObjects]
  [dictator]
    type = PorousFlowDictator
    porous_flow_vars = 'pgas zi xnacl'
    number_fluid_phases = 2
    number_fluid_components = 3
  []
  [pc]
    type = PorousFlowCapillaryPressureVG
    m = 0.5
    alpha = 1
    pc_max = 1e3
  []
  [fs]
    type = PorousFlowBrineCO2
    brine_fp = brine
    co2_fp = co2
    capillary_pressure = pc
  []
[]

[FluidProperties]
  [co2]
    type = CO2FluidProperties
  []
  [brine]
    type = BrineFluidProperties
  []
[]

[Materials]
  [temperature]
    type = PorousFlowTemperature
    temperature = 50
  []
  [brineco2]
    type = PorousFlowFluidState
    gas_porepressure = pgas
    z = zi
    temperature_unit = Celsius
    xnacl = xnacl
    capillary_pressure = pc
    fluid_state = fs
  []
  [permeability]
    type = PorousFlowPermeabilityConst
    permeability = '1e-12 0 0 0 1e-12 0 0 0 1e-12'
  []
  [relperm0]
    type = PorousFlowRelativePermeabilityCorey
    n = 2
    phase = 0
  []
  [relperm1]
    type = PorousFlowRelativePermeabilityCorey
    n = 3
    phase = 1
  []
  [porosity]
    type = PorousFlowPorosityConst
    porosity = 0.1
  []
[]

[Executioner]
  type = Transient
  solve_type = NEWTON
  dt = 1
  end_time = 1
  nl_abs_tol = 1e-12
[]

[Preconditioning]
  [smp]
    type = SMP
    full = true
  []
[]

(modules/porous_flow/test/tests/fluidstate/waterncg_nonisothermal.i)

[Mesh]
  [mesh]
    type = GeneratedMeshGenerator
    dim = 2
  []
[]

[GlobalParams]
  PorousFlowDictator = dictator
[]

[Variables]
  [pgas]
    initial_condition = 1e6
  []
  [z]
    initial_condition = 0.25
  []
  [temperature]
    initial_condition = 70
  []
[]

[AuxVariables]
  [pressure_gas]
    order = CONSTANT
    family = MONOMIAL
  []
  [pressure_water]
    order = CONSTANT
    family = MONOMIAL
  []
  [saturation_gas]
    order = CONSTANT
    family = MONOMIAL
  []
  [saturation_water]
    order = CONSTANT
    family = MONOMIAL
  []
  [density_water]
    order = CONSTANT
    family = MONOMIAL
  []
  [density_gas]
    order = CONSTANT
    family = MONOMIAL
  []
  [viscosity_water]
    order = CONSTANT
    family = MONOMIAL
  []
  [viscosity_gas]
    order = CONSTANT
    family = MONOMIAL
  []
  [enthalpy_water]
    order = CONSTANT
    family = MONOMIAL
  []
  [enthalpy_gas]
    order = CONSTANT
    family = MONOMIAL
  []
  [internal_energy_water]
    order = CONSTANT
    family = MONOMIAL
  []
  [internal_energy_gas]
    order = CONSTANT
    family = MONOMIAL
  []
  [x0_water]
    order = CONSTANT
    family = MONOMIAL
  []
  [x0_gas]
    order = CONSTANT
    family = MONOMIAL
  []
  [x1_water]
    order = CONSTANT
    family = MONOMIAL
  []
  [x1_gas]
    order = CONSTANT
    family = MONOMIAL
  []
[]

[AuxKernels]
  [pressure_water]
    type = PorousFlowPropertyAux
    variable = pressure_water
    property = pressure
    phase = 0
    execute_on = timestep_end
  []
  [pressure_gas]
    type = PorousFlowPropertyAux
    variable = pressure_gas
    property = pressure
    phase = 1
    execute_on = timestep_end
  []
  [saturation_water]
    type = PorousFlowPropertyAux
    variable = saturation_water
    property = saturation
    phase = 0
    execute_on = timestep_end
  []
  [saturation_gas]
    type = PorousFlowPropertyAux
    variable = saturation_gas
    property = saturation
    phase = 1
    execute_on = timestep_end
  []
  [density_water]
    type = PorousFlowPropertyAux
    variable = density_water
    property = density
    phase = 0
    execute_on = timestep_end
  []
  [density_gas]
    type = PorousFlowPropertyAux
    variable = density_gas
    property = density
    phase = 1
    execute_on = timestep_end
  []
  [viscosity_water]
    type = PorousFlowPropertyAux
    variable = viscosity_water
    property = viscosity
    phase = 0
    execute_on = timestep_end
  []
  [viscosity_gas]
    type = PorousFlowPropertyAux
    variable = viscosity_gas
    property = viscosity
    phase = 1
    execute_on = timestep_end
  []
  [enthalpy_water]
    type = PorousFlowPropertyAux
    variable = enthalpy_water
    property = enthalpy
    phase = 0
    execute_on = timestep_end
  []
  [enthalpy_gas]
    type = PorousFlowPropertyAux
    variable = enthalpy_gas
    property = enthalpy
    phase = 1
    execute_on = timestep_end
  []
  [internal_energy_water]
    type = PorousFlowPropertyAux
    variable = internal_energy_water
    property = internal_energy
    phase = 0
    execute_on = timestep_end
  []
  [internal_energy_gas]
    type = PorousFlowPropertyAux
    variable = internal_energy_gas
    property = internal_energy
    phase = 1
    execute_on = timestep_end
  []
  [x1_water]
    type = PorousFlowPropertyAux
    variable = x1_water
    property = mass_fraction
    phase = 0
    fluid_component = 1
    execute_on = timestep_end
  []
  [x1_gas]
    type = PorousFlowPropertyAux
    variable = x1_gas
    property = mass_fraction
    phase = 1
    fluid_component = 1
    execute_on = timestep_end
  []
  [x0_water]
    type = PorousFlowPropertyAux
    variable = x0_water
    property = mass_fraction
    phase = 0
    fluid_component = 0
    execute_on = timestep_end
  []
  [x0_gas]
    type = PorousFlowPropertyAux
    variable = x0_gas
    property = mass_fraction
    phase = 1
    fluid_component = 0
    execute_on = timestep_end
  []
[]

[Kernels]
  [mass0]
    type = PorousFlowMassTimeDerivative
    variable = pgas
    fluid_component = 0
  []
  [mass1]
    type = PorousFlowMassTimeDerivative
    variable = z
    fluid_component = 1
  []
  [heat]
    type = TimeDerivative
    variable = temperature
  []
[]

[UserObjects]
  [dictator]
    type = PorousFlowDictator
    porous_flow_vars = 'pgas z '
    number_fluid_phases = 2
    number_fluid_components = 2
  []
  [pc]
    type = PorousFlowCapillaryPressureConst
    pc = 0
  []
  [fs]
    type = PorousFlowWaterNCG
    water_fp = water
    gas_fp = co2
    capillary_pressure = pc
  []
[]

[FluidProperties]
  [co2]
    type = CO2FluidProperties
  []
  [water]
    type = Water97FluidProperties
  []
[]

[Materials]
  [temperature]
    type = PorousFlowTemperature
    temperature = temperature
  []
  [waterncg]
    type = PorousFlowFluidState
    gas_porepressure = pgas
    z = z
    temperature = temperature
    temperature_unit = Celsius
    capillary_pressure = pc
    fluid_state = fs
  []
  [permeability]
    type = PorousFlowPermeabilityConst
    permeability = '1e-12 0 0 0 1e-12 0 0 0 1e-12'
  []
  [relperm0]
    type = PorousFlowRelativePermeabilityCorey
    n = 2
    phase = 0
  []
  [relperm1]
    type = PorousFlowRelativePermeabilityCorey
    n = 3
    phase = 1
  []
  [porosity]
    type = PorousFlowPorosityConst
    porosity = 0.1
  []
[]

[Executioner]
  type = Transient
  solve_type = NEWTON
  dt = 1
  end_time = 1
  nl_abs_tol = 1e-12
[]

[Preconditioning]
  [smp]
    type = SMP
    full = true
  []
[]

[Postprocessors]
  [density_water]
    type = ElementIntegralVariablePostprocessor
    variable = density_water
  []
  [density_gas]
    type = ElementIntegralVariablePostprocessor
    variable = density_gas
  []
  [viscosity_water]
    type = ElementIntegralVariablePostprocessor
    variable = viscosity_water
  []
  [viscosity_gas]
    type = ElementIntegralVariablePostprocessor
    variable = viscosity_gas
  []
  [enthalpy_water]
    type = ElementIntegralVariablePostprocessor
    variable = enthalpy_water
  []
  [enthalpy_gas]
    type = ElementIntegralVariablePostprocessor
    variable = enthalpy_gas
  []
  [internal_energy_water]
    type = ElementIntegralVariablePostprocessor
    variable = internal_energy_water
  []
  [internal_energy_gas]
    type = ElementIntegralVariablePostprocessor
    variable = internal_energy_gas
  []
  [x0_water]
    type = ElementIntegralVariablePostprocessor
    variable = x0_water
  []
  [x1_gas]
    type = ElementIntegralVariablePostprocessor
    variable = x1_gas
  []
  [x0_gas]
    type = ElementIntegralVariablePostprocessor
    variable = x0_gas
  []
  [sg]
    type = ElementIntegralVariablePostprocessor
    variable = saturation_gas
  []
  [sw]
    type = ElementIntegralVariablePostprocessor
    variable = saturation_water
  []
  [pwater]
    type = ElementIntegralVariablePostprocessor
    variable = pressure_water
  []
  [pgas]
    type = ElementIntegralVariablePostprocessor
    variable = pressure_gas
  []
  [x0mass]
    type = PorousFlowFluidMass
    fluid_component = 0
    phase = '0 1'
  []
  [x1mass]
    type = PorousFlowFluidMass
    fluid_component = 1
    phase = '0 1'
  []
[]

[Outputs]
  csv = true
  execute_on = timestep_end
[]

(modules/fluid_properties/test/tests/co2/co2.i)

# Test thermophysical property calculations in CO2FluidProperties
#
# Comparison with values from Span and Wagner, "A New Equation of State for
# Carbon Dioxide Covering the Fluid Region from the Triple-Point Temperature
# to 1100K at Pressures up to 800 MPa", J. Phys. Chem. Ref. Data, 25 (1996)
#
# Viscosity values from Fenghour et al., "The viscosity of carbon dioxide",
# J. Phys. Chem. Ref. Data, 27, 31-44 (1998)
#
#
#  --------------------------------------------------------------
#  Pressure (Mpa)             |   1       |    1      |   1
#  Temperature (K)            |  280      |  360      |  500
#  --------------------------------------------------------------
#  Expected values
#  --------------------------------------------------------------
#  Density (kg/m^3)           |  20.199   |  15.105   |  10.664
#  Internal energy (kJ/kg/K)  |  -75.892  |  -18.406  |  91.829
#  Enthalpy (kJ/kg)           |  -26.385  |  47.797   |  185.60
#  Entropy (kJ/kg/K)          |  -0.51326 |  -0.28033 |  0.04225
#  cv (kJ/kg/K)               |  0.67092  |  0.72664  |  0.82823
#  cp (kJ/kg/K)               |  0.92518  |  0.94206  |  1.0273
#  Speed of sound (m/s)       |  252.33   |  289.00   |  339.81
#  Viscosity (1e-6Pa.s)       |  14.15    |  17.94    |  24.06
#  --------------------------------------------------------------
#  Calculated values
#  --------------------------------------------------------------
#  Density (kg/m^3)           |  20.199   |  15.105   |  10.664
#  Internal energy (kJ/kg/K)  |  -75.892  |  -18.406  |  91.829
#  Enthalpy (kJ/kg)           |  -26.385  |  47.797   |  185.60
#  Entropy (kJ/kg/K)          |  -0.51326 |  -0.28033 |  0.04225
#  cv (kJ/kg/K)               |  0.67092  |  0.72664  |  0.82823
#  cp (kJ/kg/K)               |  0.92518  |  0.94206  |  1.0273
#  Speed of sound (m/s)       |  252.33   |  289.00   |  339.81
#  Viscosity (1e-6 Pa.s)      |  14.15    |  17.94    |  24.06
#  --------------------------------------------------------------

[Mesh]
  type = GeneratedMesh
  dim = 2
  nx = 3
  xmax = 3
  # This test uses ElementalVariableValue postprocessors on specific
  # elements, so element numbering needs to stay unchanged
  allow_renumbering = false
[]

[Variables]
  [./dummy]
  [../]
[]

[AuxVariables]
  [./pressure]
    initial_condition = 1e6
    family = MONOMIAL
    order = CONSTANT
  [../]
  [./temperature]
    family = MONOMIAL
    order = CONSTANT
  [../]
  [./rho]
    family = MONOMIAL
    order = CONSTANT
  [../]
  [./mu]
    family = MONOMIAL
    order = CONSTANT
  [../]
  [./e]
    family = MONOMIAL
    order = CONSTANT
  [../]
  [./h]
    family = MONOMIAL
    order = CONSTANT
  [../]
  [./s]
    family = MONOMIAL
    order = CONSTANT
  [../]
  [./cv]
    family = MONOMIAL
    order = CONSTANT
  [../]
  [./cp]
    family = MONOMIAL
    order = CONSTANT
  [../]
  [./c]
    family = MONOMIAL
    order = CONSTANT
  [../]
[]

[Functions]
  [./tic]
    type = ParsedFunction
    expression = if(x<1,280,if(x<2,360,500))
  [../]
[]

[ICs]
  [./t_ic]
    type = FunctionIC
    function = tic
    variable = temperature
  [../]
[]

[AuxKernels]
  [./rho]
    type = MaterialRealAux
    variable = rho
    property = density
  [../]
  [./my]
    type = MaterialRealAux
    variable = mu
    property = viscosity
  [../]
  [./internal_energy]
    type = MaterialRealAux
    variable = e
    property = e
  [../]
  [./enthalpy]
    type = MaterialRealAux
    variable = h
    property = h
  [../]
  [./entropy]
    type = MaterialRealAux
    variable = s
    property = s
  [../]
  [./cv]
    type = MaterialRealAux
    variable = cv
    property = cv
  [../]
  [./cp]
    type = MaterialRealAux
    variable = cp
    property = cp
  [../]
  [./c]
    type = MaterialRealAux
    variable = c
    property = c
  [../]
[]

[FluidProperties]
  [./co2]
    type = CO2FluidProperties
  [../]
[]

[Materials]
  [./fp_mat]
    type = FluidPropertiesMaterialPT
    pressure = pressure
    temperature = temperature
    fp = co2
  [../]
[]

[Kernels]
  [./diff]
    type = Diffusion
    variable = dummy
  [../]
[]

[Executioner]
  type = Steady
  solve_type = NEWTON
[]

[Postprocessors]
  [./rho0]
    type = ElementalVariableValue
    elementid = 0
    variable = rho
  [../]
  [./rho1]
    type = ElementalVariableValue
    elementid = 1
    variable = rho
  [../]
  [./rho2]
    type = ElementalVariableValue
    elementid = 2
    variable = rho
  [../]
  [./mu0]
    type = ElementalVariableValue
    elementid = 0
    variable = mu
  [../]
  [./mu1]
    type = ElementalVariableValue
    elementid = 1
    variable = mu
  [../]
  [./mu2]
    type = ElementalVariableValue
    elementid = 2
    variable = mu
  [../]
  [./e0]
    type = ElementalVariableValue
    elementid = 0
    variable = e
  [../]
  [./e1]
    type = ElementalVariableValue
    elementid = 1
    variable = e
  [../]
  [./e2]
    type = ElementalVariableValue
    elementid = 2
    variable = e
  [../]
  [./h0]
    type = ElementalVariableValue
    elementid = 0
    variable = h
  [../]
  [./h1]
    type = ElementalVariableValue
    elementid = 1
    variable = h
  [../]
  [./h2]
    type = ElementalVariableValue
    elementid = 2
    variable = h
  [../]
  [./s0]
    type = ElementalVariableValue
    elementid = 0
    variable = s
  [../]
  [./s1]
    type = ElementalVariableValue
    elementid = 1
    variable = s
  [../]
  [./s2]
    type = ElementalVariableValue
    elementid = 2
    variable = s
  [../]
  [./cv0]
    type = ElementalVariableValue
    elementid = 0
    variable = cv
  [../]
  [./cv1]
    type = ElementalVariableValue
    elementid = 1
    variable = cv
  [../]
  [./cv2]
    type = ElementalVariableValue
    elementid = 2
    variable = cv
  [../]
  [./cp0]
    type = ElementalVariableValue
    elementid = 0
    variable = cp
  [../]
  [./cp1]
    type = ElementalVariableValue
    elementid = 1
    variable = cp
  [../]
  [./cp2]
    type = ElementalVariableValue
    elementid = 2
    variable = cp
  [../]
  [./c0]
    type = ElementalVariableValue
    elementid = 0
    variable = c
  [../]
  [./c1]
    type = ElementalVariableValue
    elementid = 1
    variable = c
  [../]
  [./c2]
    type = ElementalVariableValue
    elementid = 2
    variable = c
  [../]
[]

[Outputs]
  csv = true
  execute_on = 'TIMESTEP_END'
[]

(modules/porous_flow/test/tests/fluidstate/theis_brineco2.i)

# Two phase Theis problem: Flow from single source.
# Constant rate injection 2 kg/s
# 1D cylindrical mesh
# Initially, system has only a liquid phase, until enough gas is injected
# to form a gas phase, in which case the system becomes two phase.
#
# This test takes a few minutes to run, so is marked heavy

[Mesh]
  type = GeneratedMesh
  dim = 1
  nx = 2000
  xmax = 2000
  rz_coord_axis = Y
  coord_type = RZ
[]

[Problem]
  type = FEProblem
[]

[GlobalParams]
  PorousFlowDictator = dictator
  gravity = '0 0 0'
[]

[AuxVariables]
  [saturation_gas]
    order = CONSTANT
    family = MONOMIAL
  []
  [x1]
    order = CONSTANT
    family = MONOMIAL
  []
  [y0]
    order = CONSTANT
    family = MONOMIAL
  []
[]

[AuxKernels]
  [saturation_gas]
    type = PorousFlowPropertyAux
    variable = saturation_gas
    property = saturation
    phase = 1
    execute_on = timestep_end
  []
  [x1]
    type = PorousFlowPropertyAux
    variable = x1
    property = mass_fraction
    phase = 0
    fluid_component = 1
    execute_on = timestep_end
  []
  [y0]
    type = PorousFlowPropertyAux
    variable = y0
    property = mass_fraction
    phase = 1
    fluid_component = 0
    execute_on = timestep_end
  []
[]

[Variables]
  [pgas]
    initial_condition = 20e6
  []
  [zi]
    initial_condition = 0
  []
  [xnacl]
    initial_condition = 0.1
  []
[]

[Kernels]
  [mass0]
    type = PorousFlowMassTimeDerivative
    fluid_component = 0
    variable = pgas
  []
  [flux0]
    type = PorousFlowAdvectiveFlux
    fluid_component = 0
    variable = pgas
  []
  [mass1]
    type = PorousFlowMassTimeDerivative
    fluid_component = 1
    variable = zi
  []
  [flux1]
    type = PorousFlowAdvectiveFlux
    fluid_component = 1
    variable = zi
  []
  [mass2]
    type = PorousFlowMassTimeDerivative
    fluid_component = 2
    variable = xnacl
  []
  [flux2]
    type = PorousFlowAdvectiveFlux
    fluid_component = 2
    variable = xnacl
  []
[]

[UserObjects]
  [dictator]
    type = PorousFlowDictator
    porous_flow_vars = 'pgas zi xnacl'
    number_fluid_phases = 2
    number_fluid_components = 3
  []
  [pc]
    type = PorousFlowCapillaryPressureConst
    pc = 0
  []
  [fs]
    type = PorousFlowBrineCO2
    brine_fp = brine
    co2_fp = co2
    capillary_pressure = pc
  []
[]

[FluidProperties]
  [co2sw]
    type = CO2FluidProperties
  []
  [co2]
    type = TabulatedFluidProperties
    fp = co2sw
    fluid_property_file = 'fluid_properties.csv'
    allow_fp_and_tabulation = true
    error_on_out_of_bounds = false
  []
  [water]
    type = Water97FluidProperties
  []
  [watertab]
    type = TabulatedFluidProperties
    fp = water
    temperature_min = 273.15
    temperature_max = 573.15
    fluid_property_output_file = water_fluid_properties.csv
    # Comment out the fp parameter and uncomment below to use the newly generated tabulation
    # fluid_property_file = water_fluid_properties.csv
  []
  [brine]
    type = BrineFluidProperties
    water_fp = watertab
  []
[]

[Materials]
  [temperature]
    type = PorousFlowTemperature
    temperature = 20
  []
  [brineco2]
    type = PorousFlowFluidState
    gas_porepressure = pgas
    z = zi
    temperature_unit = Celsius
    xnacl = xnacl
    capillary_pressure = pc
    fluid_state = fs
  []
  [porosity]
    type = PorousFlowPorosityConst
    porosity = 0.2
  []
  [permeability]
    type = PorousFlowPermeabilityConst
    permeability = '1e-12 0 0 0 1e-12 0 0 0 1e-12'
  []
  [relperm_water]
    type = PorousFlowRelativePermeabilityCorey
    n = 2
    phase = 0
    s_res = 0.1
    sum_s_res = 0.1
  []
  [relperm_gas]
    type = PorousFlowRelativePermeabilityCorey
    n = 2
    phase = 1
  []
[]

[BCs]
  [rightwater]
    type = DirichletBC
    boundary = right
    value = 20e6
    variable = pgas
  []
[]

[DiracKernels]
  [source]
    type = PorousFlowSquarePulsePointSource
    point = '0 0 0'
    mass_flux = 2
    variable = zi
  []
[]

[Preconditioning]
  [smp]
    type = SMP
    full = true
  []
[]

[Executioner]
  type = Transient
  solve_type = NEWTON
  end_time = 1e5
  [TimeStepper]
    type = IterationAdaptiveDT
    dt = 1
    growth_factor = 1.5
  []
[]

[VectorPostprocessors]
  [line]
    type = LineValueSampler
    warn_discontinuous_face_values = false
    sort_by = x
    start_point = '0 0 0'
    end_point = '2000 0 0'
    num_points = 10000
    variable = 'pgas zi xnacl x1 saturation_gas'
    execute_on = 'timestep_end'
  []
[]

[Postprocessors]
  [pgas]
    type = PointValue
    point = '4 0 0'
    variable = pgas
  []
  [sgas]
    type = PointValue
    point = '4 0 0'
    variable = saturation_gas
  []
  [zi]
    type = PointValue
    point = '4 0 0'
    variable = zi
  []
  [massgas]
    type = PorousFlowFluidMass
    fluid_component = 1
  []
  [x1]
    type = PointValue
    point = '4 0 0'
    variable = x1
  []
  [y0]
    type = PointValue
    point = '4 0 0'
    variable = y0
  []
  [xnacl]
    type = PointValue
    point = '4 0 0'
    variable = xnacl
  []
[]

[Outputs]
  print_linear_residuals = false
  perf_graph = true
  [csvout]
    type = CSV
    execute_on = timestep_end
    execute_vector_postprocessors_on = final
  []
[]

(modules/porous_flow/test/tests/jacobian/waterncg_twophase_nonisothermal.i)

# Tests correct calculation of properties derivatives in PorousFlowWaterNCG
# for nonisothermal two phase conditions

[Mesh]
  [mesh]
    type = GeneratedMeshGenerator
    dim = 2
    nx = 2
    ny = 2
  []
[]

[GlobalParams]
  PorousFlowDictator = dictator
  gravity = '0 0 0'
[]

[Variables]
  [pgas]
  []
  [z]
  []
  [temperature]
  []
[]

[ICs]
  [pgas]
    type = RandomIC
    min = 1e5
    max = 5e5
    variable = pgas
  []
  [z]
    type = RandomIC
    min = 0.01
    max = 0.06
    variable = z
  []
  [temperature]
    type = RandomIC
    min = 20
    max = 80
    variable = temperature
  []
[]

[Kernels]
  [mass0]
    type = PorousFlowMassTimeDerivative
    variable = pgas
    fluid_component = 0
  []
  [mass1]
    type = PorousFlowMassTimeDerivative
    variable = z
    fluid_component = 1
  []
  [adv0]
    type = PorousFlowAdvectiveFlux
    variable = pgas
    fluid_component = 0
  []
  [adv1]
    type = PorousFlowAdvectiveFlux
    variable = z
    fluid_component = 1
  []
  [energy]
    type = PorousFlowEnergyTimeDerivative
    variable = temperature
  []
  [heat]
    type = PorousFlowHeatAdvection
    variable = temperature
  []
[]

[UserObjects]
  [dictator]
    type = PorousFlowDictator
    porous_flow_vars = 'pgas z temperature'
    number_fluid_phases = 2
    number_fluid_components = 2
  []
  [pc]
    type = PorousFlowCapillaryPressureVG
    m = 0.5
    alpha = 1e1
    pc_max = 1e4
  []
  [fs]
    type = PorousFlowWaterNCG
    water_fp = water
    gas_fp = co2
    capillary_pressure = pc
  []
[]

[FluidProperties]
  [co2]
    type = CO2FluidProperties
  []
  [water]
    type = Water97FluidProperties
  []
[]

[Materials]
  [temperature]
    type = PorousFlowTemperature
    temperature = temperature
  []
  [waterncg]
    type = PorousFlowFluidState
    gas_porepressure = pgas
    z = z
    temperature = temperature
    temperature_unit = Celsius
    capillary_pressure = pc
    fluid_state = fs
  []
  [permeability]
    type = PorousFlowPermeabilityConst
    permeability = '1e-12 0 0 0 1e-12 0 0 0 1e-12'
  []
  [relperm0]
    type = PorousFlowRelativePermeabilityCorey
    n = 2
    phase = 0
  []
  [relperm1]
    type = PorousFlowRelativePermeabilityCorey
    n = 2
    phase = 1
  []
  [porosity]
    type = PorousFlowPorosityConst
    porosity = 0.1
  []
  [rock_heat]
    type = PorousFlowMatrixInternalEnergy
    specific_heat_capacity = 1000
    density = 2500
  []
[]

[Executioner]
  type = Transient
  solve_type = NEWTON
  dt = 1
  end_time = 1
  nl_abs_tol = 1e-12
[]

[Preconditioning]
  [smp]
    type = SMP
    full = true
  []
[]

[AuxVariables]
  [sgas]
    family = MONOMIAL
    order = CONSTANT
  []
[]

[AuxKernels]
  [sgas]
    type = PorousFlowPropertyAux
    property = saturation
    phase = 1
    variable = sgas
  []
[]

[Postprocessors]
  [sgas_min]
    type = ElementExtremeValue
    variable = sgas
    value_type = min
  []
  [sgas_max]
    type = ElementExtremeValue
    variable = sgas
    value_type = max
  []
[]

(modules/porous_flow/test/tests/fluidstate/brineco2_fv.i)

# Tests correct calculation of properties in PorousFlowBrineCO2 using FV variables

[Mesh]
  [mesh]
    type = GeneratedMeshGenerator
    dim = 2
  []
[]

[GlobalParams]
  PorousFlowDictator = dictator
  temperature = 30
[]

[Variables]
  [pg]
    type = MooseVariableFVReal
    initial_condition = 20e6
  []
  [z]
    type = MooseVariableFVReal
    initial_condition = 0.2
  []
[]

[AuxVariables]
  [xnacl]
    type = MooseVariableFVReal
    initial_condition = 0.1
  []
  [pressure_gas]
    type = MooseVariableFVReal
  []
  [pressure_water]
    type = MooseVariableFVReal
  []
  [saturation_gas]
    type = MooseVariableFVReal
  []
  [saturation_water]
    type = MooseVariableFVReal
  []
  [density_water]
    type = MooseVariableFVReal
  []
  [density_gas]
    type = MooseVariableFVReal
  []
  [viscosity_water]
    type = MooseVariableFVReal
  []
  [viscosity_gas]
    type = MooseVariableFVReal
  []
  [enthalpy_water]
    type = MooseVariableFVReal
  []
  [enthalpy_gas]
    type = MooseVariableFVReal
  []
  [internal_energy_water]
    type = MooseVariableFVReal
  []
  [internal_energy_gas]
    type = MooseVariableFVReal
  []
  [x0_water]
    type = MooseVariableFVReal
  []
  [x0_gas]
    type = MooseVariableFVReal
  []
  [x1_water]
    type = MooseVariableFVReal
  []
  [x1_gas]
    type = MooseVariableFVReal
  []
[]

[AuxKernels]
  [pressure_water]
    type = ADPorousFlowPropertyAux
    variable = pressure_water
    property = pressure
    phase = 0
    execute_on = 'timestep_end'
  []
  [pressure_gas]
    type = ADPorousFlowPropertyAux
    variable = pressure_gas
    property = pressure
    phase = 1
    execute_on = 'timestep_end'
  []
  [saturation_water]
    type = ADPorousFlowPropertyAux
    variable = saturation_water
    property = saturation
    phase = 0
    execute_on = 'timestep_end'
  []
  [saturation_gas]
    type = ADPorousFlowPropertyAux
    variable = saturation_gas
    property = saturation
    phase = 1
    execute_on = 'timestep_end'
  []
  [density_water]
    type = ADPorousFlowPropertyAux
    variable = density_water
    property = density
    phase = 0
    execute_on = 'timestep_end'
  []
  [density_gas]
    type = ADPorousFlowPropertyAux
    variable = density_gas
    property = density
    phase = 1
    execute_on = 'timestep_end'
  []
  [viscosity_water]
    type = ADPorousFlowPropertyAux
    variable = viscosity_water
    property = viscosity
    phase = 0
    execute_on = 'timestep_end'
  []
  [viscosity_gas]
    type = ADPorousFlowPropertyAux
    variable = viscosity_gas
    property = viscosity
    phase = 1
    execute_on = 'timestep_end'
  []
  [enthalpy_water]
    type = ADPorousFlowPropertyAux
    variable = enthalpy_water
    property = enthalpy
    phase = 0
    execute_on = 'timestep_end'
  []
  [enthalpy_gas]
    type = ADPorousFlowPropertyAux
    variable = enthalpy_gas
    property = enthalpy
    phase = 1
    execute_on = 'timestep_end'
  []
  [internal_energy_water]
    type = ADPorousFlowPropertyAux
    variable = internal_energy_water
    property = internal_energy
    phase = 0
    execute_on = 'timestep_end'
  []
  [internal_energy_gas]
    type = ADPorousFlowPropertyAux
    variable = internal_energy_gas
    property = internal_energy
    phase = 1
    execute_on = 'timestep_end'
  []
  [x1_water]
    type = ADPorousFlowPropertyAux
    variable = x1_water
    property = mass_fraction
    phase = 0
    fluid_component = 1
    execute_on = 'timestep_end'
  []
  [x1_gas]
    type = ADPorousFlowPropertyAux
    variable = x1_gas
    property = mass_fraction
    phase = 1
    fluid_component = 1
    execute_on = 'timestep_end'
  []
  [x0_water]
    type = ADPorousFlowPropertyAux
    variable = x0_water
    property = mass_fraction
    phase = 0
    fluid_component = 0
    execute_on = 'timestep_end'
  []
  [x0_gas]
    type = ADPorousFlowPropertyAux
    variable = x0_gas
    property = mass_fraction
    phase = 1
    fluid_component = 0
    execute_on = 'timestep_end'
  []
[]

[FVKernels]
  [mass0]
    type = FVPorousFlowMassTimeDerivative
    variable = pg
    fluid_component = 0
  []
  [mass1]
    type = FVPorousFlowMassTimeDerivative
    variable = z
    fluid_component = 1
  []
[]

[UserObjects]
  [dictator]
    type = PorousFlowDictator
    porous_flow_vars = 'pg z'
    number_fluid_phases = 2
    number_fluid_components = 2
  []
  [pc]
    type = PorousFlowCapillaryPressureConst
    pc = 0
  []
  [fs]
    type = PorousFlowBrineCO2
    brine_fp = brine
    co2_fp = co2
    capillary_pressure = pc
  []
[]

[FluidProperties]
  [co2]
    type = CO2FluidProperties
  []
  [brine]
    type = BrineFluidProperties
  []
[]

[Materials]
  [temperature]
    type = ADPorousFlowTemperature
  []
  [brineco2]
    type = ADPorousFlowFluidState
    gas_porepressure = pg
    z = z
    temperature_unit = Celsius
    xnacl = xnacl
    capillary_pressure = pc
    fluid_state = fs
  []
  [permeability]
    type = ADPorousFlowPermeabilityConst
    permeability = '1e-12 0 0 0 1e-12 0 0 0 1e-12'
  []
  [relperm0]
    type = ADPorousFlowRelativePermeabilityCorey
    n = 2
    phase = 0
  []
  [relperm1]
    type = ADPorousFlowRelativePermeabilityCorey
    n = 3
    phase = 1
  []
  [porosity]
    type = ADPorousFlowPorosityConst
    porosity = 0.1
  []
[]

[Executioner]
  type = Transient
  solve_type = NEWTON
  dt = 1
  end_time = 1
  nl_abs_tol = 1e-12
[]

[Preconditioning]
  [smp]
    type = SMP
    full = true
  []
[]

[Postprocessors]
  [density_water]
    type = ElementIntegralVariablePostprocessor
    variable = density_water
    execute_on = 'timestep_end'
  []
  [density_gas]
    type = ElementIntegralVariablePostprocessor
    variable = density_gas
    execute_on = 'timestep_end'
  []
  [viscosity_water]
    type = ElementIntegralVariablePostprocessor
    variable = viscosity_water
    execute_on = 'timestep_end'
  []
  [viscosity_gas]
    type = ElementIntegralVariablePostprocessor
    variable = viscosity_gas
    execute_on = 'timestep_end'
  []
  [enthalpy_water]
    type = ElementIntegralVariablePostprocessor
    variable = enthalpy_water
    execute_on = 'timestep_end'
  []
  [enthalpy_gas]
    type = ElementIntegralVariablePostprocessor
    variable = enthalpy_gas
    execute_on = 'timestep_end'
  []
  [internal_energy_water]
    type = ElementIntegralVariablePostprocessor
    variable = internal_energy_water
    execute_on = 'timestep_end'
  []
  [internal_energy_gas]
    type = ElementIntegralVariablePostprocessor
    variable = internal_energy_gas
    execute_on = 'timestep_end'
  []
  [x1_water]
    type = ElementIntegralVariablePostprocessor
    variable = x1_water
    execute_on = 'timestep_end'
  []
  [x0_water]
    type = ElementIntegralVariablePostprocessor
    variable = x0_water
    execute_on = 'timestep_end'
  []
  [x1_gas]
    type = ElementIntegralVariablePostprocessor
    variable = x1_gas
    execute_on = 'timestep_end'
  []
  [x0_gas]
    type = ElementIntegralVariablePostprocessor
    variable = x0_gas
    execute_on = 'timestep_end'
  []
  [sg]
    type = ElementIntegralVariablePostprocessor
    variable = saturation_gas
    execute_on = 'timestep_end'
  []
  [sw]
    type = ElementIntegralVariablePostprocessor
    variable = saturation_water
    execute_on = 'timestep_end'
  []
  [pwater]
    type = ElementIntegralVariablePostprocessor
    variable = pressure_water
    execute_on = 'timestep_end'
  []
  [pgas]
    type = ElementIntegralVariablePostprocessor
    variable = pressure_gas
    execute_on = 'timestep_end'
  []
  [x0mass]
    type = FVPorousFlowFluidMass
    fluid_component = 0
    phase = '0 1'
  []
  [x1mass]
    type = FVPorousFlowFluidMass
    fluid_component = 1
    phase = '0 1'
  []
[]

[Outputs]
  csv = true
  file_base = brineco2
  execute_on = 'timestep_end'
  perf_graph = false
[]

(modules/porous_flow/examples/tutorial/11.i)

# Two-phase borehole injection problem
[Mesh]
  [annular]
    type = AnnularMeshGenerator
    nr = 10
    rmin = 1.0
    rmax = 10
    growth_r = 1.4
    nt = 4
    dmin = 0
    dmax = 90
  []
  [make3D]
    input = annular
    type = MeshExtruderGenerator
    extrusion_vector = '0 0 12'
    num_layers = 3
    bottom_sideset = 'bottom'
    top_sideset = 'top'
  []
  [shift_down]
    type = TransformGenerator
    transform = TRANSLATE
    vector_value = '0 0 -6'
    input = make3D
  []
  [aquifer]
    type = SubdomainBoundingBoxGenerator
    block_id = 1
    bottom_left = '0 0 -2'
    top_right = '10 10 2'
    input = shift_down
  []
  [injection_area]
    type = ParsedGenerateSideset
    combinatorial_geometry = 'x*x+y*y<1.01'
    included_subdomains = 1
    new_sideset_name = 'injection_area'
    input = 'aquifer'
  []
  [rename]
    type = RenameBlockGenerator
    old_block = '0 1'
    new_block = 'caps aquifer'
    input = 'injection_area'
  []
[]

[UserObjects]
  [dictator]
    type = PorousFlowDictator
    porous_flow_vars = 'pwater pgas T disp_x disp_y'
    number_fluid_phases = 2
    number_fluid_components = 2
  []
  [pc]
    type = PorousFlowCapillaryPressureVG
    alpha = 1E-6
    m = 0.6
  []
[]

[GlobalParams]
  displacements = 'disp_x disp_y disp_z'
  gravity = '0 0 0'
  biot_coefficient = 1.0
  PorousFlowDictator = dictator
[]

[Variables]
  [pwater]
    initial_condition = 20E6
  []
  [pgas]
    initial_condition = 20.1E6
  []
  [T]
    initial_condition = 330
    scaling = 1E-5
  []
  [disp_x]
    scaling = 1E-5
  []
  [disp_y]
    scaling = 1E-5
  []
[]

[Kernels]
  [mass_water_dot]
    type = PorousFlowMassTimeDerivative
    fluid_component = 0
    variable = pwater
  []
  [flux_water]
    type = PorousFlowAdvectiveFlux
    fluid_component = 0
    use_displaced_mesh = false
    variable = pwater
  []
  [vol_strain_rate_water]
    type = PorousFlowMassVolumetricExpansion
    fluid_component = 0
    variable = pwater
  []
  [mass_co2_dot]
    type = PorousFlowMassTimeDerivative
    fluid_component = 1
    variable = pgas
  []
  [flux_co2]
    type = PorousFlowAdvectiveFlux
    fluid_component = 1
    use_displaced_mesh = false
    variable = pgas
  []
  [vol_strain_rate_co2]
    type = PorousFlowMassVolumetricExpansion
    fluid_component = 1
    variable = pgas
  []
  [energy_dot]
    type = PorousFlowEnergyTimeDerivative
    variable = T
  []
  [advection]
    type = PorousFlowHeatAdvection
    use_displaced_mesh = false
    variable = T
  []
  [conduction]
    type = PorousFlowHeatConduction
    use_displaced_mesh = false
    variable = T
  []
  [vol_strain_rate_heat]
    type = PorousFlowHeatVolumetricExpansion
    variable = T
  []
  [grad_stress_x]
    type = StressDivergenceTensors
    temperature = T
    variable = disp_x
    eigenstrain_names = thermal_contribution
    use_displaced_mesh = false
    component = 0
  []
  [poro_x]
    type = PorousFlowEffectiveStressCoupling
    variable = disp_x
    use_displaced_mesh = false
    component = 0
  []
  [grad_stress_y]
    type = StressDivergenceTensors
    temperature = T
    variable = disp_y
    eigenstrain_names = thermal_contribution
    use_displaced_mesh = false
    component = 1
  []
  [poro_y]
    type = PorousFlowEffectiveStressCoupling
    variable = disp_y
    use_displaced_mesh = false
    component = 1
  []
[]

[AuxVariables]
  [disp_z]
  []
  [effective_fluid_pressure]
    family = MONOMIAL
    order = CONSTANT
  []
  [mass_frac_phase0_species0]
    initial_condition = 1 # all water in phase=0
  []
  [mass_frac_phase1_species0]
    initial_condition = 0 # no water in phase=1
  []
  [sgas]
    family = MONOMIAL
    order = CONSTANT
  []
  [swater]
    family = MONOMIAL
    order = CONSTANT
  []
  [stress_rr]
    family = MONOMIAL
    order = CONSTANT
  []
  [stress_tt]
    family = MONOMIAL
    order = CONSTANT
  []
  [stress_zz]
    family = MONOMIAL
    order = CONSTANT
  []
  [porosity]
    family = MONOMIAL
    order = CONSTANT
  []
[]

[AuxKernels]
  [effective_fluid_pressure]
    type = ParsedAux
    coupled_variables = 'pwater pgas swater sgas'
    expression = 'pwater * swater + pgas * sgas'
    variable = effective_fluid_pressure
  []
  [swater]
    type = PorousFlowPropertyAux
    variable = swater
    property = saturation
    phase = 0
    execute_on = timestep_end
  []
  [sgas]
    type = PorousFlowPropertyAux
    variable = sgas
    property = saturation
    phase = 1
    execute_on = timestep_end
  []
  [stress_rr]
    type = RankTwoScalarAux
    variable = stress_rr
    rank_two_tensor = stress
    scalar_type = RadialStress
    point1 = '0 0 0'
    point2 = '0 0 1'
    execute_on = timestep_end
  []
  [stress_tt]
    type = RankTwoScalarAux
    variable = stress_tt
    rank_two_tensor = stress
    scalar_type = HoopStress
    point1 = '0 0 0'
    point2 = '0 0 1'
    execute_on = timestep_end
  []
  [stress_zz]
    type = RankTwoAux
    variable = stress_zz
    rank_two_tensor = stress
    index_i = 2
    index_j = 2
    execute_on = timestep_end
  []
  [porosity]
    type = PorousFlowPropertyAux
    variable = porosity
    property = porosity
    execute_on = timestep_end
  []
[]

[BCs]
  [roller_tmax]
    type = DirichletBC
    variable = disp_x
    value = 0
    boundary = dmax
  []
  [roller_tmin]
    type = DirichletBC
    variable = disp_y
    value = 0
    boundary = dmin
  []
  [pinned_top_bottom_x]
    type = DirichletBC
    variable = disp_x
    value = 0
    boundary = 'top bottom'
  []
  [pinned_top_bottom_y]
    type = DirichletBC
    variable = disp_y
    value = 0
    boundary = 'top bottom'
  []
  [cavity_pressure_x]
    type = Pressure
    boundary = injection_area
    variable = disp_x
    component = 0
    postprocessor = constrained_effective_fluid_pressure_at_wellbore
    use_displaced_mesh = false
  []
  [cavity_pressure_y]
    type = Pressure
    boundary = injection_area
    variable = disp_y
    component = 1
    postprocessor = constrained_effective_fluid_pressure_at_wellbore
    use_displaced_mesh = false
  []

  [cold_co2]
    type = DirichletBC
    boundary = injection_area
    variable = T
    value = 290 # injection temperature
    use_displaced_mesh = false
  []
  [constant_co2_injection]
    type = PorousFlowSink
    boundary = injection_area
    variable = pgas
    fluid_phase = 1
    flux_function = -1E-4
    use_displaced_mesh = false
  []

  [outer_water_removal]
    type = PorousFlowPiecewiseLinearSink
    boundary = rmax
    variable = pwater
    fluid_phase = 0
    pt_vals = '0 1E9'
    multipliers = '0 1E8'
    PT_shift = 20E6
    use_mobility = true
    use_relperm = true
    use_displaced_mesh = false
  []
  [outer_co2_removal]
    type = PorousFlowPiecewiseLinearSink
    boundary = rmax
    variable = pgas
    fluid_phase = 1
    pt_vals = '0 1E9'
    multipliers = '0 1E8'
    PT_shift = 20.1E6
    use_mobility = true
    use_relperm = true
    use_displaced_mesh = false
  []
[]

[FluidProperties]
  [true_water]
    type = Water97FluidProperties
  []
  [tabulated_water]
    type = TabulatedFluidProperties
    fp = true_water
    temperature_min = 275
    pressure_max = 1E8
    interpolated_properties = 'density viscosity enthalpy internal_energy'
    fluid_property_output_file = water97_tabulated_11.csv
    # Comment out the fp parameter and uncomment below to use the newly generated tabulation
    # fluid_property_file = water97_tabulated_11.csv
  []
  [true_co2]
    type = CO2FluidProperties
  []
  [tabulated_co2]
    type = TabulatedFluidProperties
    fp = true_co2
    temperature_min = 275
    pressure_max = 1E8
    interpolated_properties = 'density viscosity enthalpy internal_energy'
    fluid_property_output_file = co2_tabulated_11.csv
    # Comment out the fp parameter and uncomment below to use the newly generated tabulation
    # fluid_property_file = co2_tabulated_11.csv
  []
[]

[Materials]
  [temperature]
    type = PorousFlowTemperature
    temperature = T
  []
  [saturation_calculator]
    type = PorousFlow2PhasePP
    phase0_porepressure = pwater
    phase1_porepressure = pgas
    capillary_pressure = pc
  []
  [massfrac]
    type = PorousFlowMassFraction
    mass_fraction_vars = 'mass_frac_phase0_species0 mass_frac_phase1_species0'
  []
  [water]
    type = PorousFlowSingleComponentFluid
    fp = tabulated_water
    phase = 0
  []
  [co2]
    type = PorousFlowSingleComponentFluid
    fp = tabulated_co2
    phase = 1
  []
  [relperm_water]
    type = PorousFlowRelativePermeabilityCorey
    n = 4
    s_res = 0.1
    sum_s_res = 0.2
    phase = 0
  []
  [relperm_co2]
    type = PorousFlowRelativePermeabilityBC
    nw_phase = true
    lambda = 2
    s_res = 0.1
    sum_s_res = 0.2
    phase = 1
  []
  [porosity_mat]
    type = PorousFlowPorosity
    fluid = true
    mechanical = true
    thermal = true
    porosity_zero = 0.1
    reference_temperature = 330
    reference_porepressure = 20E6
    thermal_expansion_coeff = 15E-6 # volumetric
    solid_bulk = 8E9 # unimportant since biot = 1
  []
  [permeability_aquifer]
    type = PorousFlowPermeabilityKozenyCarman
    block = aquifer
    poroperm_function = kozeny_carman_phi0
    phi0 = 0.1
    n = 2
    m = 2
    k0 = 1E-12
  []
  [permeability_caps]
    type = PorousFlowPermeabilityKozenyCarman
    block = caps
    poroperm_function = kozeny_carman_phi0
    phi0 = 0.1
    n = 2
    m = 2
    k0 = 1E-15
    k_anisotropy = '1 0 0  0 1 0  0 0 0.1'
  []
  [rock_thermal_conductivity]
    type = PorousFlowThermalConductivityIdeal
    dry_thermal_conductivity = '2 0 0  0 2 0  0 0 2'
  []
  [rock_internal_energy]
    type = PorousFlowMatrixInternalEnergy
    specific_heat_capacity = 1100
    density = 2300
  []

  [elasticity_tensor]
    type = ComputeIsotropicElasticityTensor
    youngs_modulus = 5E9
    poissons_ratio = 0.0
  []
  [strain]
    type = ComputeSmallStrain
    eigenstrain_names = 'thermal_contribution initial_stress'
  []
  [thermal_contribution]
    type = ComputeThermalExpansionEigenstrain
    temperature = T
    thermal_expansion_coeff = 5E-6 # this is the linear thermal expansion coefficient
    eigenstrain_name = thermal_contribution
    stress_free_temperature = 330
  []
  [initial_strain]
    type = ComputeEigenstrainFromInitialStress
    initial_stress = '20E6 0 0  0 20E6 0  0 0 20E6'
    eigenstrain_name = initial_stress
  []
  [stress]
    type = ComputeLinearElasticStress
  []

  [effective_fluid_pressure_mat]
    type = PorousFlowEffectiveFluidPressure
  []
  [volumetric_strain]
    type = PorousFlowVolumetricStrain
  []
[]

[Postprocessors]
  [effective_fluid_pressure_at_wellbore]
    type = PointValue
    variable = effective_fluid_pressure
    point = '1 0 0'
    execute_on = timestep_begin
    use_displaced_mesh = false
  []
  [constrained_effective_fluid_pressure_at_wellbore]
    type = FunctionValuePostprocessor
    function = constrain_effective_fluid_pressure
    execute_on = timestep_begin
  []
[]

[Functions]
  [constrain_effective_fluid_pressure]
    type = ParsedFunction
    symbol_names = effective_fluid_pressure_at_wellbore
    symbol_values = effective_fluid_pressure_at_wellbore
    expression = 'max(effective_fluid_pressure_at_wellbore, 20E6)'
  []
[]

[Preconditioning]
  active = basic
  [basic]
    type = SMP
    full = true
    petsc_options = '-ksp_diagonal_scale -ksp_diagonal_scale_fix'
    petsc_options_iname = '-pc_type -sub_pc_type -sub_pc_factor_shift_type -pc_asm_overlap'
    petsc_options_value = ' asm      lu           NONZERO                   2'
  []
  [preferred_but_might_not_be_installed]
    type = SMP
    full = true
    petsc_options_iname = '-pc_type -pc_factor_mat_solver_package'
    petsc_options_value = ' lu       mumps'
  []
[]

[Executioner]
  type = Transient
  solve_type = Newton
  end_time = 1E3
  [TimeStepper]
    type = IterationAdaptiveDT
    dt = 1E3
    growth_factor = 1.2
    optimal_iterations = 10
  []
  nl_abs_tol = 1E-7
[]

[Outputs]
  exodus = true
[]

(modules/porous_flow/examples/fluidflower/fluidflower.i)

# FluidFlower International Benchmark study model
# CSIRO 2023
#
# This example can be used to reproduce the results presented by the
# CSIRO team as part of this benchmark study. See
# Green, C., Jackson, S.J., Gunning, J., Wilkins, A. and Ennis-King, J.,
# 2023. Modelling the FluidFlower: Insights from Characterisation and
# Numerical Predictions. Transport in Porous Media.
#
# This example takes a long time to run! The large density contrast
# between the gas phase CO2 and the water makes convergence very hard,
# so small timesteps must be taken during injection.
#
# This example uses a simplified mesh in order to be run during the
# automated testing. To reproduce the results of the benchmark study,
# replace the simple layered input mesh with the one located in the
# large_media submodule.
#
# The mesh file contains:
# - porosity as given by FluidFlower description
# - permeability as given by FluidFlower description
# - subdomain ids for each sand type
#
# The nominal thickness of the FluidFlower tank is 19mm. To keep masses consistent
# with the experiment, porosity and permeability are multiplied by the thickness
thickness = 0.019
#
# Properties associated with each sand type associated with mesh block ids
#
# block 0 - ESF (very fine sand)
sandESF = '0 10 20'
sandESF_pe = 1471.5
sandESF_krg = 0.09
sandESF_swi = 0.32
sandESF_krw = 0.71
sandESF_sgi = 0.14

# block 1 - C - Coarse lower
sandC = '1 21'
sandC_pe = 294.3
sandC_krg = 0.05
sandC_swi = 0.14
sandC_krw = 0.93
sandC_sgi = 0.1

# block 2 - D - Coarse upper
sandD = '2 22'
sandD_pe = 98.1
sandD_krg = 0.02
sandD_swi = 0.12
sandD_krw = 0.95
sandD_sgi = 0.08

# block 3 - E - Very Coarse lower
sandE = '3 13 23'
sandE_pe = 10
sandE_krg = 0.1
sandE_swi = 0.12
sandE_krw = 0.93
sandE_sgi = 0.06

# block 4 - F - Very Coarse upper
sandF = '4 14 24 34'
sandF_pe = 10
sandF_krg = 0.11
sandF_swi = 0.12
sandF_krw = 0.72
sandF_sgi = 0.13

# block 5 - G - Flush Zone
sandG = '5 15 35'
sandG_pe = 10
sandG_krg = 0.16
sandG_swi = 0.1
sandG_krw = 0.75
sandG_sgi = 0.06

# block 6 - Fault 1 - Heterogeneous
fault1 = '6 26'
fault1_pe = 10
fault1_krg = 0.16
fault1_swi = 0.1
fault1_krw = 0.75
fault1_sgi = 0.06

# block 7 - Fault 2 - Impermeable
# Note: this fault has been removed from the mesh (no elements in this region)

# block 8 - Fault 3 - Homogeneous
fault3 = '8'
fault3_pe = 10
fault3_krg = 0.16
fault3_swi = 0.1
fault3_krw = 0.75
fault3_sgi = 0.06

# Top layer
top_layer = '9'

# Boxes A, B an C used to report values (sg, sgr, xco2, etc)
boxA = '10 13 14 15 34 35'
boxB = '20 21 22 23 24 26'
boxC = '34 35'

# Furthermore, the seal sand unit in boxes A and B
seal_boxA = '10'
seal_boxB = '20'

# CO2 injection details:
# CO2 density ~1.8389 kg/m3 at 293.15 K, 1.01325e5 Pa
# Injection in Port (9, 3) for 5 hours.
# Injection in Port (17, 7) for 2:45 hours.
# Injection of 10 ml/min = 0.1666 ml/s = 1.666e-7 m3/s = ~3.06e-7 kg/s.
# Total mass of CO2 injected ~ 8.5g.
inj_rate = 3.06e-7

[Mesh]
  [mesh]
    type = FileMeshGenerator
    file = 'fluidflower_test.e'
    # file = '../../../../large_media/porous_flow/examples/fluidflower/fluidflower.e'
    use_for_exodus_restart = true
  []
[]

[Debug]
  show_var_residual_norms = true
[]

[GlobalParams]
  PorousFlowDictator = dictator
  gravity = '0 -9.81 0'
  temperature = temperature
  log_extension = false
[]

[Variables]
  [pgas]
    family = MONOMIAL
    order = CONSTANT
    fv = true
  []
  [z]
    family = MONOMIAL
    order = CONSTANT
    fv = true
    scaling = 1e4
  []
[]

[AuxVariables]
  [xnacl]
    family = MONOMIAL
    order = CONSTANT
    fv = true
    initial_condition = 0.0055
  []
  [temperature]
    family = MONOMIAL
    order = CONSTANT
    fv = true
    initial_condition = 20
  []
  [porosity]
    family = MONOMIAL
    order = CONSTANT
    fv = true
    initial_from_file_var = porosity
  []
  [porosity_times_thickness]
    family = MONOMIAL
    order = CONSTANT
    fv = true
  []
  [permeability]
    family = MONOMIAL
    order = CONSTANT
    fv = true
    initial_from_file_var = permeability
  []
  [permeability_times_thickness]
    family = MONOMIAL
    order = CONSTANT
    fv = true
  []
  [saturation_water]
    family = MONOMIAL
    order = CONSTANT
  []
  [saturation_gas]
    family = MONOMIAL
    order = CONSTANT
  []
  [pressure_water]
    family = MONOMIAL
    order = CONSTANT
  []
  [pc]
    family = MONOMIAL
    order = CONSTANT
  []
  [x0_water]
    order = CONSTANT
    family = MONOMIAL
  []
  [x0_gas]
    order = CONSTANT
    family = MONOMIAL
  []
  [x1_water]
    order = CONSTANT
    family = MONOMIAL
  []
  [x1_gas]
    order = CONSTANT
    family = MONOMIAL
  []
  [density_water]
    order = CONSTANT
    family = MONOMIAL
  []
  [density_gas]
    order = CONSTANT
    family = MONOMIAL
  []
[]

[AuxKernels]
  [porosity_times_thickness]
    type = ParsedAux
    variable = porosity_times_thickness
    coupled_variables = porosity
    expression = 'porosity * ${thickness}'
    execute_on = 'initial'
  []
  [permeability_times_thickness]
    type = ParsedAux
    variable = permeability_times_thickness
    coupled_variables = permeability
    expression = 'permeability * ${thickness}'
    execute_on = 'initial'
  []
  [pressure_water]
    type = ADPorousFlowPropertyAux
    variable = pressure_water
    property = pressure
    phase = 0
    execute_on = 'initial timestep_end'
  []
  [saturation_water]
    type = ADPorousFlowPropertyAux
    variable = saturation_water
    property = saturation
    phase = 0
    execute_on = 'initial timestep_end'
  []
  [saturation_gas]
    type = ADPorousFlowPropertyAux
    variable = saturation_gas
    property = saturation
    phase = 1
    execute_on = 'initial timestep_end'
  []
  [density_water]
    type = ADPorousFlowPropertyAux
    variable = density_water
    property = density
    phase = 0
    execute_on = 'initial timestep_end'
  []
  [density_gas]
    type = ADPorousFlowPropertyAux
    variable = density_gas
    property = density
    phase = 1
    execute_on = 'initial timestep_end'
  []
  [x1_water]
    type = ADPorousFlowPropertyAux
    variable = x1_water
    property = mass_fraction
    phase = 0
    fluid_component = 1
    execute_on = 'initial timestep_end'
  []
  [x1_gas]
    type = ADPorousFlowPropertyAux
    variable = x1_gas
    property = mass_fraction
    phase = 1
    fluid_component = 1
    execute_on = 'initial timestep_end'
  []
  [x0_water]
    type = ADPorousFlowPropertyAux
    variable = x0_water
    property = mass_fraction
    phase = 0
    fluid_component = 0
    execute_on = 'initial timestep_end'
  []
  [x0_gas]
    type = ADPorousFlowPropertyAux
    variable = x0_gas
    property = mass_fraction
    phase = 1
    fluid_component = 0
    execute_on = 'initial timestep_end'
  []
  [pc]
    type = ADPorousFlowPropertyAux
    variable = pc
    property = capillary_pressure
    execute_on = 'initial timestep_end'
  []
[]

[FVKernels]
  [mass0]
    type = FVPorousFlowMassTimeDerivative
    variable = pgas
    fluid_component = 0
  []
  [flux0]
    type = FVPorousFlowAdvectiveFlux
    variable = pgas
    fluid_component = 0
  []
  [diff0]
    type = FVPorousFlowDispersiveFlux
    variable = pgas
    fluid_component = 0
    disp_long = '0 0'
    disp_trans = '0 0'
  []
  [mass1]
    type = FVPorousFlowMassTimeDerivative
    variable = z
    fluid_component = 1
  []
  [flux1]
    type = FVPorousFlowAdvectiveFlux
    variable = z
    fluid_component = 1
  []
  [diff1]
    type = FVPorousFlowDispersiveFlux
    variable = z
    fluid_component = 1
    disp_long = '0 0'
    disp_trans = '0 0'
  []
[]

[DiracKernels]
  [injector1]
    type = ConstantPointSource
    point = '0.9 0.3 0'
    value = ${inj_rate}
    variable = z
  []
  [injector2]
    type = ConstantPointSource
    point = '1.7 0.7 0'
    value = ${inj_rate}
    variable = z
  []
[]

[Controls]
  [injection1]
    type = ConditionalFunctionEnableControl
    enable_objects = 'DiracKernels::injector1'
    conditional_function = injection_schedule1
  []
  [injection2]
    type = ConditionalFunctionEnableControl
    enable_objects = 'DiracKernels::injector2'
    conditional_function = injection_schedule2
  []
[]

[Functions]
  [initial_p]
    type = ParsedFunction
    symbol_names = 'p0 g H rho0'
    symbol_values = '101.325e3 9.81 1.5 1002'
    expression = 'p0 + rho0 * g * (H - y)'
  []
  [injection_schedule1]
    type = ParsedFunction
    expression = 'if(t >= 0 & t <= 1.8e4, 1, 0)'
  []
  [injection_schedule2]
    type = ParsedFunction
    expression = 'if(t >= 8.1e3 & t <= 1.8e4, 1, 0)'
  []
[]

[ICs]
  [p]
    type = FunctionIC
    variable = pgas
    function = initial_p
  []
[]

[FVBCs]
  [pressure_top]
    type = FVPorousFlowAdvectiveFluxBC
    boundary = top
    porepressure_value = 1.01325e5
    variable = pgas
  []
[]

[FluidProperties]
  [water]
    type = Water97FluidProperties
  []
  [watertab]
    type = TabulatedBicubicFluidProperties
    fp = water
    save_file = false
    pressure_min = 1e5
    pressure_max = 1e6
    temperature_min = 290
    temperature_max = 300
    num_p = 20
    num_T = 10
  []
  [co2]
    type = CO2FluidProperties
  []
  [co2tab]
    type = TabulatedBicubicFluidProperties
    fp = co2
    save_file = false
    pressure_min = 1e5
    pressure_max = 1e6
    temperature_min = 290
    temperature_max = 300
    num_p = 20
    num_T = 10
  []
  [brine]
    type = BrineFluidProperties
    water_fp = watertab
  []
[]

[UserObjects]
  [dictator]
    type = PorousFlowDictator
    porous_flow_vars = 'pgas z'
    number_fluid_phases = 2
    number_fluid_components = 2
  []
  [sandESF_pc]
    type = PorousFlowCapillaryPressureBC
    pe = ${sandESF_pe}
    lambda = 2
    block = ${sandESF}
    pc_max = 1e4
    sat_lr = ${sandESF_swi}
  []
  [sandC_pc]
    type = PorousFlowCapillaryPressureBC
    pe = ${sandC_pe}
    lambda = 2
    block = ${sandC}
    pc_max = 1e4
    sat_lr = ${sandC_swi}
  []
  [sandD_pc]
    type = PorousFlowCapillaryPressureBC
    pe = ${sandD_pe}
    lambda = 2
    block = ${sandD}
    pc_max = 1e4
    sat_lr = ${sandD_swi}
  []
  [sandE_pc]
    type = PorousFlowCapillaryPressureBC
    pe = ${sandE_pe}
    lambda = 2
    block = ${sandE}
    pc_max = 1e4
    sat_lr = ${sandE_swi}
  []
  [sandF_pc]
    type = PorousFlowCapillaryPressureBC
    pe = ${sandF_pe}
    lambda = 2
    block = ${sandF}
    pc_max = 1e4
    sat_lr = ${sandF_swi}
  []
  [sandG_pc]
    type = PorousFlowCapillaryPressureBC
    pe = ${sandG_pe}
    lambda = 2
    block = ${sandG}
    pc_max = 1e4
    sat_lr = ${sandG_swi}
  []
  [fault1_pc]
    type = PorousFlowCapillaryPressureBC
    pe = ${fault1_pe}
    lambda = 2
    block = ${fault1}
    pc_max = 1e4
    sat_lr = ${fault1_swi}
  []
  [fault3_pc]
    type = PorousFlowCapillaryPressureBC
    pe = ${fault3_pe}
    lambda = 2
    block = ${fault3}
    pc_max = 1e4
    sat_lr = ${fault3_swi}
  []
  [top_layer_pc]
    type = PorousFlowCapillaryPressureConst
    pc = 0
    block =  ${top_layer}
  []
  [sandESF_fs]
    type = PorousFlowBrineCO2
    brine_fp = brine
    co2_fp = co2tab
    capillary_pressure = sandESF_pc
  []
  [sandC_fs]
    type = PorousFlowBrineCO2
    brine_fp = brine
    co2_fp = co2tab
    capillary_pressure = sandC_pc
  []
  [sandD_fs]
    type = PorousFlowBrineCO2
    brine_fp = brine
    co2_fp = co2tab
    capillary_pressure = sandD_pc
  []
  [sandE_fs]
    type = PorousFlowBrineCO2
    brine_fp = brine
    co2_fp = co2tab
    capillary_pressure = sandE_pc
  []
  [sandF_fs]
    type = PorousFlowBrineCO2
    brine_fp = brine
    co2_fp = co2tab
    capillary_pressure = sandF_pc
  []
  [sandG_fs]
    type = PorousFlowBrineCO2
    brine_fp = brine
    co2_fp = co2tab
    capillary_pressure = sandG_pc
  []
  [fault1_fs]
    type = PorousFlowBrineCO2
    brine_fp = brine
    co2_fp = co2tab
    capillary_pressure = fault1_pc
  []
  [fault3_fs]
    type = PorousFlowBrineCO2
    brine_fp = brine
    co2_fp = co2tab
    capillary_pressure = fault3_pc
  []
  [top_layer_fs]
    type = PorousFlowBrineCO2
    brine_fp = brine
    co2_fp = co2tab
    capillary_pressure = top_layer_pc
  []
[]

[Materials]
  [temperature]
    type = ADPorousFlowTemperature
    temperature = temperature
  []
  [sandESF_brineco2]
    type = ADPorousFlowFluidState
    gas_porepressure = pgas
    z = z
    temperature_unit = Celsius
    xnacl = xnacl
    fluid_state = sandESF_fs
    capillary_pressure = sandESF_pc
    block = ${sandESF}
  []
  [sandC_brineco2]
    type = ADPorousFlowFluidState
    gas_porepressure = pgas
    z = z
    temperature_unit = Celsius
    xnacl = xnacl
    fluid_state = sandC_fs
    capillary_pressure = sandC_pc
    block = ${sandC}
  []
  [sandD_brineco2]
    type = ADPorousFlowFluidState
    gas_porepressure = pgas
    z = z
    temperature_unit = Celsius
    xnacl = xnacl
    fluid_state = sandD_fs
    capillary_pressure = sandD_pc
    block = ${sandD}
  []
  [sandE_brineco2]
    type = ADPorousFlowFluidState
    gas_porepressure = pgas
    z = z
    temperature_unit = Celsius
    xnacl = xnacl
    fluid_state = sandE_fs
    capillary_pressure = sandE_pc
    block = ${sandE}
  []
  [sandF_brineco2]
    type = ADPorousFlowFluidState
    gas_porepressure = pgas
    z = z
    temperature_unit = Celsius
    xnacl = xnacl
    fluid_state = sandF_fs
    capillary_pressure = sandF_pc
    block = ${sandF}
  []
  [sandG_brineco2]
    type = ADPorousFlowFluidState
    gas_porepressure = pgas
    z = z
    temperature_unit = Celsius
    xnacl = xnacl
    fluid_state = sandG_fs
    capillary_pressure = sandG_pc
    block = ${sandG}
  []
  [fault1_brineco2]
    type = ADPorousFlowFluidState
    gas_porepressure = pgas
    z = z
    temperature_unit = Celsius
    xnacl = xnacl
    fluid_state = fault1_fs
    capillary_pressure = fault1_pc
    block = ${fault1}
  []
  [fault3_brineco2]
    type = ADPorousFlowFluidState
    gas_porepressure = pgas
    z = z
    temperature_unit = Celsius
    xnacl = xnacl
    fluid_state = fault3_fs
    capillary_pressure = fault3_pc
    block = ${fault3}
  []
  [top_layer_brineco2]
    type = ADPorousFlowFluidState
    gas_porepressure = pgas
    z = z
    temperature_unit = Celsius
    xnacl = xnacl
    fluid_state = top_layer_fs
    capillary_pressure = top_layer_pc
    block = ${top_layer}
  []
  [porosity]
    type = ADPorousFlowPorosityConst
    porosity = porosity_times_thickness
  []
  [permeability]
    type = ADPorousFlowPermeabilityConstFromVar
    perm_xx = permeability_times_thickness
    perm_yy = permeability_times_thickness
    perm_zz = permeability_times_thickness
  []
  [diffcoeff]
    type = ADPorousFlowDiffusivityConst
    tortuosity = '1 1'
    diffusion_coeff = '2e-9 2e-9 0 0'
  []
  [sandESF_relperm0]
    type = ADPorousFlowRelativePermeabilityBC
    phase = 0
    lambda = 2
    s_res = ${sandESF_swi}
    sum_s_res = ${fparse sandESF_sgi + sandESF_swi}
    scaling = ${sandESF_krw}
    block = ${sandESF}
  []
  [sandESF_relperm1]
    type = ADPorousFlowRelativePermeabilityBC
    phase = 1
    nw_phase = true
    lambda = 2
    s_res = ${sandESF_sgi}
    sum_s_res = ${fparse sandESF_sgi + sandESF_swi}
    scaling = ${sandESF_krg}
    block = ${sandESF}
  []
  [sandC_relperm0]
    type = ADPorousFlowRelativePermeabilityBC
    phase = 0
    lambda = 2
    s_res = ${sandC_swi}
    sum_s_res = ${fparse sandC_sgi + sandC_swi}
    scaling = ${sandC_krw}
    block = ${sandC}
  []
  [sandC_relperm1]
    type = ADPorousFlowRelativePermeabilityBC
    phase = 1
    nw_phase = true
    lambda = 2
    s_res = ${sandC_sgi}
    sum_s_res = ${fparse sandC_sgi + sandC_swi}
    scaling = ${sandC_krg}
    block = ${sandC}
  []
  [sandD_relperm0]
    type = ADPorousFlowRelativePermeabilityBC
    phase = 0
    lambda = 2
    s_res = ${sandD_swi}
    sum_s_res = ${fparse sandD_sgi + sandD_swi}
    scaling = ${sandD_krw}
    block = ${sandD}
  []
  [sandD_relperm1]
    type = ADPorousFlowRelativePermeabilityBC
    phase = 1
    nw_phase = true
    lambda = 2
    s_res = ${sandD_sgi}
    sum_s_res = ${fparse sandD_sgi + sandD_swi}
    scaling = ${sandD_krg}
    block = ${sandD}
  []
  [sandE_relperm0]
    type = ADPorousFlowRelativePermeabilityBC
    phase = 0
    lambda = 2
    s_res = ${sandE_swi}
    sum_s_res = ${fparse sandE_sgi + sandE_swi}
    scaling = ${sandE_krw}
    block = ${sandE}
  []
  [sandE_relperm1]
    type = ADPorousFlowRelativePermeabilityBC
    phase = 1
    nw_phase = true
    lambda = 2
    s_res = ${sandE_sgi}
    sum_s_res = ${fparse sandE_sgi + sandE_swi}
    scaling = ${sandE_krg}
    block = ${sandE}
  []
  [sandF_relperm0]
    type = ADPorousFlowRelativePermeabilityBC
    phase = 0
    lambda = 2
    s_res = ${sandF_swi}
    sum_s_res = ${fparse sandF_sgi + sandF_swi}
    scaling = ${sandF_krw}
    block = ${sandF}
  []
  [sandF_relperm1]
    type = ADPorousFlowRelativePermeabilityBC
    phase = 1
    nw_phase = true
    lambda = 2
    s_res = ${sandF_sgi}
    sum_s_res = ${fparse sandF_sgi + sandF_swi}
    scaling = ${sandF_krg}
    block = ${sandF}
  []
  [sandG_relperm0]
    type = ADPorousFlowRelativePermeabilityBC
    phase = 0
    lambda = 2
    s_res = ${sandG_swi}
    sum_s_res = ${fparse sandG_sgi + sandG_swi}
    scaling = ${sandG_krw}
    block = ${sandG}
  []
  [sandG_relperm1]
    type = ADPorousFlowRelativePermeabilityBC
    phase = 1
    nw_phase = true
    lambda = 2
    s_res = ${sandG_sgi}
    sum_s_res = ${fparse sandG_sgi + sandG_swi}
    scaling = ${sandG_krg}
    block = ${sandG}
  []
  [fault1_relperm0]
    type = ADPorousFlowRelativePermeabilityBC
    phase = 0
    lambda = 2
    s_res = ${fault1_swi}
    sum_s_res = ${fparse fault1_sgi + fault1_swi}
    scaling = ${fault1_krw}
    block = ${fault1}
  []
  [fault1_relperm1]
    type = ADPorousFlowRelativePermeabilityBC
    phase = 1
    nw_phase = true
    lambda = 2
    s_res = ${fault1_sgi}
    sum_s_res = ${fparse fault1_sgi + fault1_swi}
    scaling = ${fault1_krg}
    block = ${fault1}
  []
  [fault3_relperm0]
    type = ADPorousFlowRelativePermeabilityBC
    phase = 0
    lambda = 2
    s_res = ${fault3_swi}
    sum_s_res = ${fparse fault3_sgi + fault3_swi}
    scaling = ${fault3_krw}
    block = ${fault3}
  []
  [fault3_relperm1]
    type = ADPorousFlowRelativePermeabilityBC
    phase = 1
    nw_phase = true
    lambda = 2
    s_res = ${fault3_sgi}
    sum_s_res = ${fparse fault3_sgi + fault3_swi}
    scaling = ${fault3_krg}
    block = ${fault3}
  []
  [top_layer_relperm0]
    type = ADPorousFlowRelativePermeabilityBC
    phase = 0
    lambda = 2
    block = ${top_layer}
  []
  [top_layer_relperm1]
    type = ADPorousFlowRelativePermeabilityBC
    phase = 1
    nw_phase = true
    lambda = 2
    block = ${top_layer}
  []
[]

[Preconditioning]
  [smp]
    type = SMP
    full = true
    petsc_options = '-ksp_snes_ew'
    petsc_options_iname = '-ksp_type -pc_type -pc_factor_mat_solver_package -sub_pc_factor_shift_type'
    petsc_options_value = 'gmres lu mumps NONZERO'
    # petsc_options_iname = '-ksp_type -pc_type -pc_hypre_type -sub_pc_type -sub_pc_factor_shift_type -sub_pc_factor_levels -ksp_gmres_restart'
    # petsc_options_value = 'gmres hypre boomeramg lu NONZERO 4 301'
  []
[]

[Executioner]
  type = Transient
  solve_type = NEWTON
  dtmax = 60
  start_time = 0
  end_time = 4.32e5
  nl_rel_tol = 1e-6
  nl_abs_tol = 1e-8
  nl_max_its = 15
  l_tol = 1e-5
  l_abs_tol = 1e-8
  # line_search = none # Can be a useful option for this problem
  [TimeSteppers]
    [time]
      type = FunctionDT
      growth_factor = 2
      cutback_factor_at_failure = 0.5
      function = 'if(t<1.8e4, 2, if(t<3.6e4, 20, 60))'
    []
  []
[]

[Postprocessors]
  [p_5_3]
    type = PointValue
    variable = pgas
    point = '0.5 0.3 0'
    execute_on = 'initial timestep_end'
  []
  [p_5_3_w]
    type = PointValue
    variable = pressure_water
    point = '0.5 0.3 0'
    execute_on = 'initial timestep_end'
  []
  [p_5_7]
    type = PointValue
    variable = pgas
    point = '0.5 0.7 0'
    execute_on = 'initial timestep_end'
  []
  [p_5_7_w]
    type = PointValue
    variable = pressure_water
    point = '0.5 0.7 0'
    execute_on = 'initial timestep_end'
  []
  [p_9_3]
    type = PointValue
    variable = pgas
    point = '0.9 0.3 0'
    execute_on = 'initial timestep_end'
  []
  [p_9_3_w]
    type = PointValue
    variable = pressure_water
    point = '0.9 0.3 0'
    execute_on = 'initial timestep_end'
  []
  [p_15_5]
    type = PointValue
    variable = pgas
    point = '1.5 0.5 0'
    execute_on = 'initial timestep_end'
  []
  [p_15_5_w]
    type = PointValue
    variable = pressure_water
    point = '1.5 0.5 0'
    execute_on = 'initial timestep_end'
  []
  [p_17_7]
    type = PointValue
    variable = pgas
    point = '1.7 0.7 0'
    execute_on = 'initial timestep_end'
  []
  [p_17_7_w]
    type = PointValue
    variable = pressure_water
    point = '1.7 0.7 0'
    execute_on = 'initial timestep_end'
  []
  [p_17_11]
    type = PointValue
    variable = pgas
    point = '1.7 1.1 0'
    execute_on = 'initial timestep_end'
  []
  [p_17_11_w]
    type = PointValue
    variable = pressure_water
    point = '1.7 1.1 0'
    execute_on = 'initial timestep_end'
  []
  [x0mass]
    type = FVPorousFlowFluidMass
    fluid_component = 0
    phase = '0 1'
    execute_on = 'initial timestep_end'
  []
  [x1mass]
    type = FVPorousFlowFluidMass
    fluid_component = 1
    phase = '0 1'
    execute_on = 'initial timestep_end'
  []
  [x1gas]
    type = FVPorousFlowFluidMass
    fluid_component = 1
    phase = '1'
    execute_on = 'initial timestep_end'
  []
  [boxA]
    type = FVPorousFlowFluidMass
    fluid_component = 1
    phase = '0 1'
    block = ${boxA}
    execute_on = 'initial timestep_end'
  []
  [imm_A_sandESF]
    type = FVPorousFlowFluidMass
    fluid_component = 1
    phase = 1
    saturation_threshold = ${sandESF_sgi}
    block = 10
    execute_on = 'initial timestep_end'
  []
  [imm_A_sandE]
    type = FVPorousFlowFluidMass
    fluid_component = 1
    phase = 1
    saturation_threshold = ${sandE_sgi}
    block = 13
    execute_on = 'initial timestep_end'
  []
  [imm_A_sandF]
    type = FVPorousFlowFluidMass
    fluid_component = 1
    phase = 1
    saturation_threshold = ${sandF_sgi}
    block = '14 34'
    execute_on = 'initial timestep_end'
  []
  [imm_A_sandG]
    type = FVPorousFlowFluidMass
    fluid_component = 1
    phase = 1
    saturation_threshold = ${sandG_sgi}
    block = '15 35'
    execute_on = 'initial timestep_end'
  []
  [imm_A]
    type = LinearCombinationPostprocessor
    pp_names = 'imm_A_sandESF imm_A_sandE imm_A_sandF imm_A_sandG'
    pp_coefs = '1 1 1 1'
    execute_on = 'initial timestep_end'
  []
  [diss_A]
    type = FVPorousFlowFluidMass
    fluid_component = 1
    phase = 0
    block = ${boxA}
    execute_on = 'initial timestep_end'
  []
  [seal_A]
    type = FVPorousFlowFluidMass
    fluid_component = 1
    phase = '0 1'
    block = ${seal_boxA}
    execute_on = 'initial timestep_end'
  []
  [boxB]
    type = FVPorousFlowFluidMass
    fluid_component = 1
    phase = '0 1'
    block = ${boxB}
    execute_on = 'initial timestep_end'
  []
  [imm_B_sandESF]
    type = FVPorousFlowFluidMass
    fluid_component = 1
    phase = 1
    saturation_threshold = ${sandESF_sgi}
    block = 20
    execute_on = 'initial timestep_end'
  []
  [imm_B_sandC]
    type = FVPorousFlowFluidMass
    fluid_component = 1
    phase = 1
    saturation_threshold = ${sandC_sgi}
    block = 21
    execute_on = 'initial timestep_end'
  []
  [imm_B_sandD]
    type = FVPorousFlowFluidMass
    fluid_component = 1
    phase = 1
    saturation_threshold = ${sandD_sgi}
    block = 22
    execute_on = 'initial timestep_end'
  []
  [imm_B_sandE]
    type = FVPorousFlowFluidMass
    fluid_component = 1
    phase = 1
    saturation_threshold = ${sandE_sgi}
    block = 23
    execute_on = 'initial timestep_end'
  []
  [imm_B_sandF]
    type = FVPorousFlowFluidMass
    fluid_component = 1
    phase = 1
    saturation_threshold = ${sandF_sgi}
    block = 24
    execute_on = 'initial timestep_end'
  []
  [imm_B_fault1]
    type = FVPorousFlowFluidMass
    fluid_component = 1
    phase = 1
    saturation_threshold = ${fault1_sgi}
    block = 26
    execute_on = 'initial timestep_end'
  []
  [imm_B]
    type = LinearCombinationPostprocessor
    pp_names = 'imm_B_sandESF imm_B_sandC imm_B_sandD imm_B_sandE imm_B_sandF imm_B_fault1'
    pp_coefs = '1 1 1 1 1 1'
    execute_on = 'initial timestep_end'
  []
  [diss_B]
    type = FVPorousFlowFluidMass
    fluid_component = 1
    phase = 0
    block = ${boxB}
    execute_on = 'initial timestep_end'
  []
  [seal_B]
    type = FVPorousFlowFluidMass
    fluid_component = 1
    phase = '0 1'
    block = ${seal_boxB}
    execute_on = 'initial timestep_end'
  []
  [boxC]
    type = FVPorousFlowFluidMass
    fluid_component = 1
    phase = '0'
    block = ${boxC}
    execute_on = 'initial timestep_end'
  []
[]

[Outputs]
  print_linear_residuals = false
  perf_graph = true
  # exodus = true
  [csv]
     type = CSV
  []
[]

(modules/fluid_properties/test/tests/tabulated/tabulated.i)

# Test thermophysical property calculations using TabulatedBiCubic/LinearFluidProperties.
# Calculations for density, internal energy and enthalpy using bicubic spline
# interpolation of data generated using CO2FluidProperties.

[Mesh]
  type = GeneratedMesh
  dim = 2
  # This test uses ElementalVariableValue postprocessors on specific
  # elements, so element numbering needs to stay unchanged
  allow_renumbering = false
[]

[Variables]
  [dummy]
  []
[]

[AuxVariables]
  [pressure]
    initial_condition = 2e6
    family = MONOMIAL
    order = CONSTANT
  []
  [temperature]
    initial_condition = 350
    family = MONOMIAL
    order = CONSTANT
  []
  [rho]
    family = MONOMIAL
    order = CONSTANT
  []
  [mu]
    family = MONOMIAL
    order = CONSTANT
  []
  [e]
    family = MONOMIAL
    order = CONSTANT
  []
  [h]
    family = MONOMIAL
    order = CONSTANT
  []
  [s]
    family = MONOMIAL
    order = CONSTANT
  []
  [cv]
    family = MONOMIAL
    order = CONSTANT
  []
  [cp]
    family = MONOMIAL
    order = CONSTANT
  []
  [c]
    family = MONOMIAL
    order = CONSTANT
  []
[]

[AuxKernels]
  [rho]
    type = MaterialRealAux
    variable = rho
    property = density
  []
  [my]
    type = MaterialRealAux
    variable = mu
    property = viscosity
  []
  [internal_energy]
    type = MaterialRealAux
    variable = e
    property = e
  []
  [enthalpy]
    type = MaterialRealAux
    variable = h
    property = h
  []
  [entropy]
    type = MaterialRealAux
    variable = s
    property = s
  []
  [cv]
    type = MaterialRealAux
    variable = cv
    property = cv
  []
  [cp]
    type = MaterialRealAux
    variable = cp
    property = cp
  []
  [c]
    type = MaterialRealAux
    variable = c
    property = c
  []
[]

[FluidProperties]
  [co2]
    type = CO2FluidProperties
  []
  [tabulated]
    type = TabulatedBicubicFluidProperties
    fp = co2
    interpolated_properties = 'density enthalpy viscosity internal_energy k c cv cp entropy'
    # fluid_property_file = fluid_properties.csv
    construct_pT_from_ve = false
    construct_pT_from_vh = false

    # Tabulation range
    temperature_min = 280
    temperature_max = 600
    pressure_min = 1e5
    pressure_max = 3e6

    # Newton parameters
    tolerance = 1e-8
    T_initial_guess = 350
    p_initial_guess = 1.5e5
  []
[]

[Materials]
  [fp_mat]
    type = FluidPropertiesMaterialPT
    pressure = pressure
    temperature = temperature
    fp = tabulated
  []
[]

[Kernels]
  [diff]
    type = Diffusion
    variable = dummy
  []
[]

[Executioner]
  type = Steady
  solve_type = NEWTON
[]

[Problem]
  solve = false
[]

[Postprocessors]
  [rho]
    type = ElementalVariableValue
    elementid = 0
    variable = rho
  []
  [mu]
    type = ElementalVariableValue
    elementid = 0
    variable = mu
  []
  [e]
    type = ElementalVariableValue
    elementid = 0
    variable = e
  []
  [h]
    type = ElementalVariableValue
    elementid = 0
    variable = h
  []
  [s]
    type = ElementalVariableValue
    elementid = 0
    variable = s
  []
  [cv]
    type = ElementalVariableValue
    elementid = 0
    variable = cv
  []
  [cp]
    type = ElementalVariableValue
    elementid = 0
    variable = cp
  []
  [c]
    type = ElementalVariableValue
    elementid = 0
    variable = c
  []
[]

[Outputs]
  csv = true
  file_base = tabulated_out
  execute_on = 'TIMESTEP_END'
  perf_graph = true
[]

(modules/porous_flow/test/tests/fluids/co2.i)

# Test the density and viscosity calculated by the simple CO2 Material
# Pressure 5 MPa
# Temperature 50C
# These conditions correspond to the gas phase
# CO2 density should equal 104 kg/m^3 (NIST webbook)
# CO2 viscosity should equal 0.000017345 Pa.s (NIST webbook)
# Results are within expected accuracy

[Mesh]
  type = GeneratedMesh
  dim = 1
  nx = 1
[]

[GlobalParams]
  PorousFlowDictator = dictator
[]

[UserObjects]
  [dictator]
    type = PorousFlowDictator
    porous_flow_vars = 'pp'
    number_fluid_phases = 1
    number_fluid_components = 1
  []
[]

[Variables]
  [pp]
    initial_condition = 5e6
  []
[]

[Kernels]
  [dummy]
    type = Diffusion
    variable = pp
  []
[]

[AuxVariables]
  [temp]
    initial_condition = 50
  []
[]

[Materials]
  [temperature]
    type = PorousFlowTemperature
    temperature = temp
  []
  [ppss]
    type = PorousFlow1PhaseFullySaturated
    porepressure = pp
  []
  [co2]
    type = PorousFlowSingleComponentFluid
    temperature_unit = Celsius
    fp = co2
    phase = 0
  []
[]

[FluidProperties]
  [co2]
    type = CO2FluidProperties
  []
[]

[Executioner]
  type = Steady
  solve_type = Newton
[]

[Postprocessors]
  [pressure]
    type = ElementIntegralVariablePostprocessor
    variable = pp
  []
  [temperature]
    type = ElementIntegralVariablePostprocessor
    variable = temp
  []
  [density]
    type = ElementIntegralMaterialProperty
    mat_prop = 'PorousFlow_fluid_phase_density_qp0'
  []
  [viscosity]
    type = ElementIntegralMaterialProperty
    mat_prop = 'PorousFlow_viscosity_qp0'
  []
[]

[Outputs]
  execute_on = 'timestep_end'
  file_base = co2
  csv = true
[]

(modules/porous_flow/test/tests/sinks/injection_production_eg_outflowBC.i)

# phase = 0 is liquid phase
# phase = 1 is gas phase
# fluid_component = 0 is water
# fluid_component = 1 is CO2

# Constant rates of water and CO2 injection into the left boundary
# 1D mesh
# The PorousFlowOutflowBCs remove the correct water and CO2 from the right boundary

[Mesh]
  type = GeneratedMesh
  dim = 1
  nx = 20
  xmax = 20
[]

[GlobalParams]
  PorousFlowDictator = dictator
  gravity = '0 0 0'
[]

[AuxVariables]
  [saturation_gas]
    order = CONSTANT
    family = MONOMIAL
  []
  [frac_water_in_liquid]
    initial_condition = 1.0
  []
  [frac_water_in_gas]
    initial_condition = 0.0
  []
  [water_kg_per_s]
  []
  [co2_kg_per_s]
  []
[]

[AuxKernels]
  [saturation_gas]
    type = PorousFlowPropertyAux
    variable = saturation_gas
    property = saturation
    phase = 1
    execute_on = timestep_end
  []
[]

[Variables]
  [pwater]
    initial_condition = 20E6
  []
  [pgas]
    initial_condition = 21E6
  []
[]

[Kernels]
  [mass0]
    type = PorousFlowMassTimeDerivative
    fluid_component = 0
    variable = pwater
  []
  [flux0]
    type = PorousFlowAdvectiveFlux
    fluid_component = 0
    variable = pwater
  []
  [mass1]
    type = PorousFlowMassTimeDerivative
    fluid_component = 1
    variable = pgas
  []
  [flux1]
    type = PorousFlowAdvectiveFlux
    fluid_component = 1
    variable = pgas
  []
[]

[UserObjects]
  [dictator]
    type = PorousFlowDictator
    porous_flow_vars = 'pgas pwater'
    number_fluid_phases = 2
    number_fluid_components = 2
  []
  [pc]
    type = PorousFlowCapillaryPressureVG
    alpha = 1E-6
    m = 0.6
  []
[]

[FluidProperties]
  [true_water]
    type = Water97FluidProperties
  []
  [tabulated_water]
    type = TabulatedBicubicFluidProperties
    fp = true_water
    temperature_min = 275
    pressure_max = 1E8
    interpolated_properties = 'density viscosity enthalpy internal_energy'
    fluid_property_output_file = water97_tabulated_11.csv
    # Comment out the fp parameter and uncomment below to use the newly generated tabulation
    # fluid_property_file = water97_tabulated_11.csv
  []
  [true_co2]
    type = CO2FluidProperties
  []
  [tabulated_co2]
    type = TabulatedBicubicFluidProperties
    fp = true_co2
    temperature_min = 275
    pressure_max = 1E8
    interpolated_properties = 'density viscosity enthalpy internal_energy'
    fluid_property_output_file = co2_tabulated_11.csv
    # Comment out the fp parameter and uncomment below to use the newly generated tabulation
    # fluid_property_file = co2_tabulated_11.csv
  []
[]

[Materials]
  [temperature]
    type = PorousFlowTemperature
    temperature = 293.15
  []
  [saturation_calculator]
    type = PorousFlow2PhasePP
    phase0_porepressure = pwater
    phase1_porepressure = pgas
    capillary_pressure = pc
  []
  [massfrac]
    type = PorousFlowMassFraction
    mass_fraction_vars = 'frac_water_in_liquid frac_water_in_gas'
  []
  [water]
    type = PorousFlowSingleComponentFluid
    fp = tabulated_water
    phase = 0
  []
  [co2]
    type = PorousFlowSingleComponentFluid
    fp = tabulated_co2
    phase = 1
  []
  [porosity]
    type = PorousFlowPorosityConst
    porosity = 0.2
  []
  [permeability]
    type = PorousFlowPermeabilityConst
    permeability = '1e-12 0 0 0 1e-12 0 0 0 1e-12'
  []
  [relperm_water]
    type = PorousFlowRelativePermeabilityCorey
    n = 2
    phase = 0
    s_res = 0.1
    sum_s_res = 0.2
  []
  [relperm_gas]
    type = PorousFlowRelativePermeabilityBC
    nw_phase = true
    lambda = 2
    s_res = 0.1
    sum_s_res = 0.2
    phase = 1
  []
[]

[BCs]
  [water_injection]
    type = PorousFlowSink
    boundary = left
    variable = pwater # pwater is associated with the water mass balance (fluid_component = 0 in its Kernels)
    flux_function = -1E-5 # negative means a source, rather than a sink
  []
  [co2_injection]
    type = PorousFlowSink
    boundary = left
    variable = pgas # pgas is associated with the CO2 mass balance (fluid_component = 1 in its Kernels)
    flux_function = -2E-5 # negative means a source, rather than a sink
  []

  [right_water_component0]
    type = PorousFlowOutflowBC
    boundary = right
    variable = pwater
    mass_fraction_component = 0
    save_in = water_kg_per_s
  []
  [right_co2_component1]
    type = PorousFlowOutflowBC
    boundary = right
    variable = pgas
    mass_fraction_component = 1
    save_in = co2_kg_per_s
  []
[]

[Preconditioning]
  active = 'basic'
  [basic]
    type = SMP
    full = true
    petsc_options = '-snes_converged_reason -ksp_diagonal_scale -ksp_diagonal_scale_fix -ksp_gmres_modifiedgramschmidt'
    petsc_options_iname = '-ksp_type -pc_type -sub_pc_type -sub_pc_factor_shift_type -pc_asm_overlap'
    petsc_options_value = 'gmres asm lu NONZERO 2'
  []
  [preferred]
    type = SMP
    full = true
    petsc_options_iname = '-pc_type -pc_factor_mat_solver_package'
    petsc_options_value = 'lu mumps'
  []
[]

[Executioner]
  type = Transient
  solve_type = NEWTON
  nl_abs_tol = 1E-10
  nl_rel_tol = 1E-10
  end_time = 1E5
  [TimeStepper]
    type = IterationAdaptiveDT
    dt = 1E5
    growth_factor = 1.1
  []
[]

[Postprocessors]
  [water_kg_per_s]
    type = NodalSum
    boundary = right
    variable = water_kg_per_s
  []
  [co2_kg_per_s]
    type = NodalSum
    boundary = right
    variable = co2_kg_per_s
  []
[]

[VectorPostprocessors]
  [pps]
    type = LineValueSampler
    start_point = '0 0 0'
    end_point = '20 0 0'
    num_points = 20
    sort_by = x
    variable = 'pgas pwater saturation_gas'
  []
[]

[Outputs]
  [out]
    type = CSV
    execute_on = final
  []
[]

(modules/porous_flow/examples/tutorial/11_2D.i)

# Two-phase borehole injection problem in RZ coordinates
[Mesh]
  [gen]
    type = GeneratedMeshGenerator
    dim = 2
    nx = 10
    xmin = 1.0
    xmax = 10
    bias_x = 1.4
    ny = 3
    ymin = -6
    ymax = 6
  []
  [aquifer]
    input = gen
    type = SubdomainBoundingBoxGenerator
    block_id = 1
    bottom_left = '0 -2 0'
    top_right = '10 2 0'
  []
  [injection_area]
    type = ParsedGenerateSideset
    combinatorial_geometry = 'x<1.0001'
    included_subdomains = 1
    new_sideset_name = 'injection_area'
    input = 'aquifer'
  []
  [rename]
    type = RenameBlockGenerator
    old_block = '0 1'
    new_block = 'caps aquifer'
    input = 'injection_area'
  []
  coord_type = RZ
[]

[UserObjects]
  [dictator]
    type = PorousFlowDictator
    porous_flow_vars = 'pwater pgas T disp_r'
    number_fluid_phases = 2
    number_fluid_components = 2
  []
  [pc]
    type = PorousFlowCapillaryPressureVG
    alpha = 1E-6
    m = 0.6
  []
[]

[GlobalParams]
  displacements = 'disp_r disp_z'
  gravity = '0 0 0'
  biot_coefficient = 1.0
  PorousFlowDictator = dictator
[]

[Variables]
  [pwater]
    initial_condition = 20E6
  []
  [pgas]
    initial_condition = 20.1E6
  []
  [T]
    initial_condition = 330
    scaling = 1E-5
  []
  [disp_r]
    scaling = 1E-5
  []
[]

[Kernels]
  [mass_water_dot]
    type = PorousFlowMassTimeDerivative
    fluid_component = 0
    variable = pwater
  []
  [flux_water]
    type = PorousFlowAdvectiveFlux
    fluid_component = 0
    use_displaced_mesh = false
    variable = pwater
  []
  [vol_strain_rate_water]
    type = PorousFlowMassVolumetricExpansion
    fluid_component = 0
    variable = pwater
  []
  [mass_co2_dot]
    type = PorousFlowMassTimeDerivative
    fluid_component = 1
    variable = pgas
  []
  [flux_co2]
    type = PorousFlowAdvectiveFlux
    fluid_component = 1
    use_displaced_mesh = false
    variable = pgas
  []
  [vol_strain_rate_co2]
    type = PorousFlowMassVolumetricExpansion
    fluid_component = 1
    variable = pgas
  []
  [energy_dot]
    type = PorousFlowEnergyTimeDerivative
    variable = T
  []
  [advection]
    type = PorousFlowHeatAdvection
    use_displaced_mesh = false
    variable = T
  []
  [conduction]
    type = PorousFlowHeatConduction
    use_displaced_mesh = false
    variable = T
  []
  [vol_strain_rate_heat]
    type = PorousFlowHeatVolumetricExpansion
    variable = T
  []
  [grad_stress_r]
    type = StressDivergenceRZTensors
    temperature = T
    variable = disp_r
    eigenstrain_names = thermal_contribution
    use_displaced_mesh = false
    component = 0
  []
  [poro_r]
    type = PorousFlowEffectiveStressCoupling
    variable = disp_r
    use_displaced_mesh = false
    component = 0
  []
[]

[AuxVariables]
  [disp_z]
  []
  [effective_fluid_pressure]
    family = MONOMIAL
    order = CONSTANT
  []
  [mass_frac_phase0_species0]
    initial_condition = 1 # all water in phase=0
  []
  [mass_frac_phase1_species0]
    initial_condition = 0 # no water in phase=1
  []
  [sgas]
    family = MONOMIAL
    order = CONSTANT
  []
  [swater]
    family = MONOMIAL
    order = CONSTANT
  []
  [stress_rr]
    family = MONOMIAL
    order = CONSTANT
  []
  [stress_tt]
    family = MONOMIAL
    order = CONSTANT
  []
  [stress_zz]
    family = MONOMIAL
    order = CONSTANT
  []
  [porosity]
    family = MONOMIAL
    order = CONSTANT
  []
[]

[AuxKernels]
  [effective_fluid_pressure]
    type = ParsedAux
    coupled_variables = 'pwater pgas swater sgas'
    expression = 'pwater * swater + pgas * sgas'
    variable = effective_fluid_pressure
  []
  [swater]
    type = PorousFlowPropertyAux
    variable = swater
    property = saturation
    phase = 0
    execute_on = timestep_end
  []
  [sgas]
    type = PorousFlowPropertyAux
    variable = sgas
    property = saturation
    phase = 1
    execute_on = timestep_end
  []
  [stress_rr_aux]
    type = RankTwoAux
    variable = stress_rr
    rank_two_tensor = stress
    index_i = 0
    index_j = 0
  []
  [stress_tt]
    type = RankTwoAux
    rank_two_tensor = stress
    variable = stress_tt
    index_i = 2
    index_j = 2
  []
  [stress_zz]
    type = RankTwoAux
    rank_two_tensor = stress
    variable = stress_zz
    index_i = 1
    index_j = 1
  []
  [porosity]
    type = PorousFlowPropertyAux
    variable = porosity
    property = porosity
    execute_on = timestep_end
  []
[]

[BCs]
  [pinned_top_bottom_r]
    type = DirichletBC
    variable = disp_r
    value = 0
    boundary = 'top bottom'
  []
  [cavity_pressure_r]
    type = Pressure
    boundary = injection_area
    variable = disp_r
    postprocessor = constrained_effective_fluid_pressure_at_wellbore
    use_displaced_mesh = false
  []

  [cold_co2]
    type = DirichletBC
    boundary = injection_area
    variable = T
    value = 290 # injection temperature
    use_displaced_mesh = false
  []
  [constant_co2_injection]
    type = PorousFlowSink
    boundary = injection_area
    variable = pgas
    fluid_phase = 1
    flux_function = -1E-4
    use_displaced_mesh = false
  []

  [outer_water_removal]
    type = PorousFlowPiecewiseLinearSink
    boundary = right
    variable = pwater
    fluid_phase = 0
    pt_vals = '0 1E9'
    multipliers = '0 1E8'
    PT_shift = 20E6
    use_mobility = true
    use_relperm = true
    use_displaced_mesh = false
  []
  [outer_co2_removal]
    type = PorousFlowPiecewiseLinearSink
    boundary = right
    variable = pgas
    fluid_phase = 1
    pt_vals = '0 1E9'
    multipliers = '0 1E8'
    PT_shift = 20.1E6
    use_mobility = true
    use_relperm = true
    use_displaced_mesh = false
  []
[]

[FluidProperties]
  [true_water]
    type = Water97FluidProperties
  []
  [tabulated_water]
    type = TabulatedBicubicFluidProperties
    fp = true_water
    temperature_min = 275
    pressure_max = 1E8
    fluid_property_output_file = water97_tabulated_11.csv
    # Comment out the fp parameter and uncomment below to use the newly generated tabulation
    # fluid_property_file = water97_tabulated_11.csv
  []
  [true_co2]
    type = CO2FluidProperties
  []
  [tabulated_co2]
    type = TabulatedBicubicFluidProperties
    fp = true_co2
    temperature_min = 275
    pressure_max = 1E8
    fluid_property_output_file = co2_tabulated_11.csv
    # Comment out the fp parameter and uncomment below to use the newly generated tabulation
    # fluid_property_file = co2_tabulated_11.csv
  []
[]

[Materials]
  [temperature]
    type = PorousFlowTemperature
    temperature = T
  []
  [saturation_calculator]
    type = PorousFlow2PhasePP
    phase0_porepressure = pwater
    phase1_porepressure = pgas
    capillary_pressure = pc
  []
  [massfrac]
    type = PorousFlowMassFraction
    mass_fraction_vars = 'mass_frac_phase0_species0 mass_frac_phase1_species0'
  []
  [water]
    type = PorousFlowSingleComponentFluid
    fp = tabulated_water
    phase = 0
  []
  [co2]
    type = PorousFlowSingleComponentFluid
    fp = tabulated_co2
    phase = 1
  []
  [relperm_water]
    type = PorousFlowRelativePermeabilityCorey
    n = 4
    s_res = 0.1
    sum_s_res = 0.2
    phase = 0
  []
  [relperm_co2]
    type = PorousFlowRelativePermeabilityBC
    nw_phase = true
    lambda = 2
    s_res = 0.1
    sum_s_res = 0.2
    phase = 1
  []
  [porosity]
    type = PorousFlowPorosity
    fluid = true
    mechanical = true
    thermal = true
    porosity_zero = 0.1
    reference_temperature = 330
    reference_porepressure = 20E6
    thermal_expansion_coeff = 15E-6 # volumetric
    solid_bulk = 8E9 # unimportant since biot = 1
  []
  [permeability_aquifer]
    type = PorousFlowPermeabilityKozenyCarman
    block = aquifer
    poroperm_function = kozeny_carman_phi0
    phi0 = 0.1
    n = 2
    m = 2
    k0 = 1E-12
  []
  [permeability_caps]
    type = PorousFlowPermeabilityKozenyCarman
    block = caps
    poroperm_function = kozeny_carman_phi0
    phi0 = 0.1
    n = 2
    m = 2
    k0 = 1E-15
    k_anisotropy = '1 0 0  0 1 0  0 0 0.1'
  []
  [rock_thermal_conductivity]
    type = PorousFlowThermalConductivityIdeal
    dry_thermal_conductivity = '2 0 0  0 2 0  0 0 2'
  []
  [rock_internal_energy]
    type = PorousFlowMatrixInternalEnergy
    specific_heat_capacity = 1100
    density = 2300
  []

  [elasticity_tensor]
    type = ComputeIsotropicElasticityTensor
    youngs_modulus = 5E9
    poissons_ratio = 0.0
  []
  [strain]
    type = ComputeAxisymmetricRZSmallStrain
    eigenstrain_names = 'thermal_contribution initial_stress'
  []
  [thermal_contribution]
    type = ComputeThermalExpansionEigenstrain
    temperature = T
    thermal_expansion_coeff = 5E-6 # this is the linear thermal expansion coefficient
    eigenstrain_name = thermal_contribution
    stress_free_temperature = 330
  []
  [initial_strain]
    type = ComputeEigenstrainFromInitialStress
    initial_stress = '20E6 0 0  0 20E6 0  0 0 20E6'
    eigenstrain_name = initial_stress
  []
  [stress]
    type = ComputeLinearElasticStress
  []

  [effective_fluid_pressure]
    type = PorousFlowEffectiveFluidPressure
  []
  [volumetric_strain]
    type = PorousFlowVolumetricStrain
  []
[]

[Postprocessors]
  [effective_fluid_pressure_at_wellbore]
    type = PointValue
    variable = effective_fluid_pressure
    point = '1 0 0'
    execute_on = timestep_begin
    use_displaced_mesh = false
  []
  [constrained_effective_fluid_pressure_at_wellbore]
    type = FunctionValuePostprocessor
    function = constrain_effective_fluid_pressure
    execute_on = timestep_begin
  []
[]

[Functions]
  [constrain_effective_fluid_pressure]
    type = ParsedFunction
    symbol_names = effective_fluid_pressure_at_wellbore
    symbol_values = effective_fluid_pressure_at_wellbore
    expression = 'max(effective_fluid_pressure_at_wellbore, 20E6)'
  []
[]

[Preconditioning]
  active = basic
  [basic]
    type = SMP
    full = true
    petsc_options = '-ksp_diagonal_scale -ksp_diagonal_scale_fix'
    petsc_options_iname = '-pc_type -sub_pc_type -sub_pc_factor_shift_type -pc_asm_overlap'
    petsc_options_value = ' asm      lu           NONZERO                   2'
  []
  [preferred_but_might_not_be_installed]
    type = SMP
    full = true
    petsc_options_iname = '-pc_type -pc_factor_mat_solver_package'
    petsc_options_value = ' lu       mumps'
  []
[]

[Executioner]
  type = Transient
  solve_type = Newton
  end_time = 1E3
  [TimeStepper]
    type = IterationAdaptiveDT
    dt = 1E3
    growth_factor = 1.2
    optimal_iterations = 10
  []
  nl_abs_tol = 1E-7
[]

[Outputs]
  exodus = true
[]

(modules/porous_flow/examples/lava_lamp/1phase_convection.i)

# Two phase density-driven convection of dissolved CO2 in brine
#
# The model starts with CO2 in the liquid phase only.  The CO2 diffuses into the brine.
# As the density of the CO2-saturated brine is greater
# than the unsaturated brine, a gravitational instability arises and density-driven
# convection of CO2-rich fingers descend into the unsaturated brine.
#
# The instability is seeded by a random perturbation to the porosity field.
# Mesh adaptivity is used to refine the mesh as the fingers form.
#
# Note: this model is computationally expensive, so should be run with multiple cores.

[GlobalParams]
  PorousFlowDictator = 'dictator'
  gravity = '0 -9.81 0'
[]

[Adaptivity]
  max_h_level = 2
  marker = marker
  initial_marker = initial
  initial_steps = 2
  [Indicators]
    [indicator]
      type = GradientJumpIndicator
      variable = zi
    []
  []
  [Markers]
    [marker]
      type = ErrorFractionMarker
      indicator = indicator
      refine = 0.8
    []
    [initial]
      type = BoxMarker
      bottom_left = '0 1.95 0'
      top_right = '2 2 0'
      inside = REFINE
      outside = DO_NOTHING
    []
  []
[]

[Mesh]
  type = GeneratedMesh
  dim = 2
  ymin = 1.5
  ymax = 2
  xmax = 2
  ny = 20
  nx = 40
  bias_y = 0.95
[]

[AuxVariables]
  [xnacl]
    initial_condition = 0.01
  []
  [saturation_gas]
    order = FIRST
    family = MONOMIAL
  []
  [xco2l]
    order = FIRST
    family = MONOMIAL
  []
  [density_liquid]
    order = FIRST
    family = MONOMIAL
  []
  [porosity]
    order = CONSTANT
    family = MONOMIAL
  []
[]

[AuxKernels]
  [saturation_gas]
    type = PorousFlowPropertyAux
    variable = saturation_gas
    property = saturation
    phase = 1
    execute_on = 'timestep_end'
  []
  [xco2l]
    type = PorousFlowPropertyAux
    variable = xco2l
    property = mass_fraction
    phase = 0
    fluid_component = 1
    execute_on = 'timestep_end'
  []
  [density_liquid]
    type = PorousFlowPropertyAux
    variable = density_liquid
    property = density
    phase = 0
    execute_on = 'timestep_end'
  []
[]

[Variables]
  [pgas]
  []
  [zi]
    scaling = 1e4
  []
[]

[ICs]
  [pressure]
    type = FunctionIC
    function = 10e6-9.81*1000*y
    variable = pgas
  []
  [zi]
    type = ConstantIC
    value = 0
    variable = zi
  []
  [porosity]
    type = RandomIC
    variable = porosity
    min = 0.25
    max = 0.275
    seed = 0
  []
[]

[BCs]
  [top]
    type = DirichletBC
    value = 0.04
    variable = zi
    boundary = top
  []
[]

[Kernels]
  [mass0]
    type = PorousFlowMassTimeDerivative
    fluid_component = 0
    variable = pgas
  []
  [flux0]
    type = PorousFlowAdvectiveFlux
    fluid_component = 0
    variable = pgas
  []
  [diff0]
    type = PorousFlowDispersiveFlux
    fluid_component = 0
    variable = pgas
    disp_long = '0 0'
    disp_trans = '0 0'
  []
  [mass1]
    type = PorousFlowMassTimeDerivative
    fluid_component = 1
    variable = zi
  []
  [flux1]
    type = PorousFlowAdvectiveFlux
    fluid_component = 1
    variable = zi
  []
  [diff1]
    type = PorousFlowDispersiveFlux
    fluid_component = 1
    variable = zi
    disp_long = '0 0'
    disp_trans = '0 0'
  []
[]

[UserObjects]
  [dictator]
    type = PorousFlowDictator
    porous_flow_vars = 'pgas zi'
    number_fluid_phases = 2
    number_fluid_components = 2
  []
  [pc]
    type = PorousFlowCapillaryPressureConst
    pc = 0
  []
  [fs]
    type = PorousFlowBrineCO2
    brine_fp = brine
    co2_fp = co2
    capillary_pressure = pc
  []
[]

[FluidProperties]
  [co2sw]
    type = CO2FluidProperties
  []
  [co2]
    type = TabulatedBicubicFluidProperties
    fp = co2sw
  []
  [brine]
    type = BrineFluidProperties
  []
[]

[Materials]
  [temperature]
    type = PorousFlowTemperature
    temperature = '45'
  []
  [brineco2]
    type = PorousFlowFluidState
    gas_porepressure = 'pgas'
    z = 'zi'
    temperature_unit = Celsius
    xnacl = 'xnacl'
    capillary_pressure = pc
    fluid_state = fs
  []
  [porosity]
    type = PorousFlowPorosityConst
    porosity = porosity
  []
  [permeability]
    type = PorousFlowPermeabilityConst
    permeability = '1e-11 0 0 0 1e-11 0 0 0 1e-11'
  []
  [relperm_water]
    type = PorousFlowRelativePermeabilityCorey
    phase = 0
    n = 2
    s_res = 0.1
    sum_s_res = 0.2
  []
  [relperm_gas]
    type = PorousFlowRelativePermeabilityCorey
    phase = 1
    n = 2
    s_res = 0.1
    sum_s_res = 0.2
  []
  [diffusivity]
    type = PorousFlowDiffusivityConst
    diffusion_coeff = '2e-9 2e-9 2e-9 2e-9'
    tortuosity = '1 1'
  []
[]

[Preconditioning]
  active = basic
  [mumps_is_best_for_parallel_jobs]
    type = SMP
    full = true
    petsc_options_iname = '-pc_type -pc_factor_mat_solver_package'
    petsc_options_value = ' lu       mumps'
  []
  [basic]
    type = SMP
    full = true
    petsc_options_iname = '-ksp_type -pc_type -sub_pc_type -sub_pc_factor_shift_type -pc_asm_overlap'
    petsc_options_value = 'gmres      asm      lu           NONZERO                   2             '
  []
[]

[Executioner]
  type = Transient
  solve_type = NEWTON
  end_time = 1e6
  nl_max_its = 25
  l_max_its = 100
  dtmax = 1e4
  nl_abs_tol = 1e-6
  [TimeStepper]
    type = IterationAdaptiveDT
    dt = 100
    growth_factor = 2
    cutback_factor = 0.5
  []
[]

[Functions]
  [flux]
    type = ParsedFunction
    symbol_values = 'delta_xco2 dt'
    symbol_names = 'dx dt'
    expression = 'dx/dt'
  []
[]

[Postprocessors]
  [total_co2_in_gas]
    type = PorousFlowFluidMass
    phase = 1
    fluid_component = 1
  []
  [total_co2_in_liquid]
    type = PorousFlowFluidMass
    phase = 0
    fluid_component = 1
  []
  [numdofs]
    type = NumDOFs
  []
  [delta_xco2]
    type = ChangeOverTimePostprocessor
    postprocessor = total_co2_in_liquid
  []
  [dt]
    type = TimestepSize
  []
  [flux]
    type = FunctionValuePostprocessor
    function = flux
  []
[]

[Outputs]
  print_linear_residuals = false
  perf_graph = true
  exodus = true
  csv = true
[]

(modules/porous_flow/examples/lava_lamp/2phase_convection.i)

# Two phase density-driven convection of dissolved CO2 in brine
#
# Initially, the model has a gas phase at the top with a saturation of 0.29
# (which corresponds to an initial value of zi = 0.2).
# Diffusion of the dissolved CO2
# component from the saturated liquid to the unsaturated liquid below reduces the
# amount of CO2 in the gas phase. As the density of the CO2-saturated brine is greater
# than the unsaturated brine, a gravitational instability arises and density-driven
# convection of CO2-rich fingers descend into the unsaturated brine.
#
# The instability is seeded by a random perturbation to the porosity field.
# Mesh adaptivity is used to refine the mesh as the fingers form.
#
# Note: this model is computationally expensive, so should be run with multiple cores,
# preferably on a cluster.

[GlobalParams]
  PorousFlowDictator = 'dictator'
  gravity = '0 -9.81 0'
[]

[Adaptivity]
  max_h_level = 2
  marker = marker
  initial_marker = initial
  initial_steps = 2
  [Indicators]
    [indicator]
      type = GradientJumpIndicator
      variable = zi
    []
  []
  [Markers]
    [marker]
      type = ErrorFractionMarker
      indicator = indicator
      refine = 0.8
    []
    [initial]
      type = BoxMarker
      bottom_left = '0 1.95 0'
      top_right = '2 2 0'
      inside = REFINE
      outside = DO_NOTHING
    []
  []
[]

[Mesh]
  type = GeneratedMesh
  dim = 2
  ymax = 2
  xmax = 2
  ny = 40
  nx = 40
  bias_y = 0.95
[]

[Kernels]
  [mass0]
    type = PorousFlowMassTimeDerivative
    fluid_component = 0
    variable = pgas
  []
  [flux0]
    type = PorousFlowAdvectiveFlux
    fluid_component = 0
    variable = pgas
  []
  [diff0]
    type = PorousFlowDispersiveFlux
    fluid_component = 0
    variable = pgas
    disp_long = '0 0'
    disp_trans = '0 0'
  []
  [mass1]
    type = PorousFlowMassTimeDerivative
    fluid_component = 1
    variable = zi
  []
  [flux1]
    type = PorousFlowAdvectiveFlux
    fluid_component = 1
    variable = zi
  []
  [diff1]
    type = PorousFlowDispersiveFlux
    fluid_component = 1
    variable = zi
    disp_long = '0 0'
    disp_trans = '0 0'
  []
[]

[AuxVariables]
  [xnacl]
    initial_condition = 0.01
  []
  [saturation_gas]
    order = FIRST
    family = MONOMIAL
  []
  [xco2l]
    order = FIRST
    family = MONOMIAL
  []
  [density_liquid]
    order = FIRST
    family = MONOMIAL
  []
  [porosity]
    order = CONSTANT
    family = MONOMIAL
  []
[]

[AuxKernels]
  [saturation_gas]
    type = PorousFlowPropertyAux
    variable = saturation_gas
    property = saturation
    phase = 1
    execute_on = 'timestep_end'
  []
  [xco2l]
    type = PorousFlowPropertyAux
    variable = xco2l
    property = mass_fraction
    phase = 0
    fluid_component = 1
    execute_on = 'timestep_end'
  []
  [density_liquid]
    type = PorousFlowPropertyAux
    variable = density_liquid
    property = density
    phase = 0
    execute_on = 'timestep_end'
  []
[]

[Variables]
  [pgas]
  []
  [zi]
    scaling = 1e4
  []
[]

[ICs]
  [pressure]
    type = FunctionIC
    function = 10e6-9.81*1000*y
    variable = pgas
  []
  [zi]
    type = BoundingBoxIC
    variable = zi
    x1 = 0
    x2 = 2
    y1 = 1.95
    y2 = 2
    inside = 0.2
    outside = 0
  []
  [porosity]
    type = RandomIC
    variable = porosity
    min = 0.25
    max = 0.275
    seed = 0
  []
[]

[UserObjects]
  [dictator]
    type = PorousFlowDictator
    porous_flow_vars = 'pgas zi'
    number_fluid_phases = 2
    number_fluid_components = 2
  []
  [pc]
    type = PorousFlowCapillaryPressureConst
    pc = 0
  []
  [fs]
    type = PorousFlowBrineCO2
    brine_fp = brine
    co2_fp = co2
    capillary_pressure = pc
  []
[]

[FluidProperties]
  [co2sw]
    type = CO2FluidProperties
  []
  [co2]
    type = TabulatedBicubicFluidProperties
    fp = co2sw
  []
  [brine]
    type = BrineFluidProperties
  []
[]

[Materials]
  [temperature]
    type = PorousFlowTemperature
    temperature = '45'
  []
  [brineco2]
    type = PorousFlowFluidState
    gas_porepressure = 'pgas'
    z = 'zi'
    temperature_unit = Celsius
    xnacl = 'xnacl'
    capillary_pressure = pc
    fluid_state = fs
  []
  [porosity]
    type = PorousFlowPorosityConst
    porosity = porosity
  []
  [permeability]
    type = PorousFlowPermeabilityConst
    permeability = '1e-11 0 0 0 1e-11 0 0 0 1e-11'
  []
  [relperm_water]
    type = PorousFlowRelativePermeabilityCorey
    phase = 0
    n = 2
    s_res = 0.1
    sum_s_res = 0.2
  []
  [relperm_gas]
    type = PorousFlowRelativePermeabilityCorey
    phase = 1
    n = 2
    s_res = 0.1
    sum_s_res = 0.2
  []
  [diffusivity]
    type = PorousFlowDiffusivityConst
    diffusion_coeff = '2e-9 2e-9 2e-9 2e-9'
    tortuosity = '1 1'
  []
[]

[Preconditioning]
  active = basic
  [mumps_is_best_for_parallel_jobs]
    type = SMP
    full = true
    petsc_options_iname = '-pc_type -pc_factor_mat_solver_package'
    petsc_options_value = ' lu       mumps'
  []
  [basic]
    type = SMP
    full = true
    petsc_options_iname = '-ksp_type -pc_type -sub_pc_type -sub_pc_factor_shift_type -pc_asm_overlap'
    petsc_options_value = 'gmres      asm      lu           NONZERO                   2             '
  []
[]

[Executioner]
  type = Transient
  solve_type = NEWTON
  end_time = 1e6
  nl_max_its = 25
  l_max_its = 100
  dtmax = 1e4
  nl_abs_tol = 1e-6
  [TimeStepper]
    type = IterationAdaptiveDT
    dt = 10
    growth_factor = 2
    cutback_factor = 0.5
  []
[]

[Functions]
  [flux]
    type = ParsedFunction
    symbol_values = 'delta_xco2 dt'
    symbol_names = 'dx dt'
    expression = 'dx/dt'
  []
[]

[Postprocessors]
  [total_co2_in_gas]
    type = PorousFlowFluidMass
    phase = 1
    fluid_component = 1
  []
  [total_co2_in_liquid]
    type = PorousFlowFluidMass
    phase = 0
    fluid_component = 1
  []
  [numdofs]
    type = NumDOFs
  []
  [delta_xco2]
    type = ChangeOverTimePostprocessor
    postprocessor = total_co2_in_liquid
  []
  [dt]
    type = TimestepSize
  []
  [flux]
    type = FunctionValuePostprocessor
    function = flux
  []
[]

[Outputs]
  print_linear_residuals = false
  perf_graph = true
  exodus = true
  csv = true
[]

Properties of CO var element = document.getElementById("moose-equation-32f59c47-1162-4490-b613-99522aeca9f4");katex.render("_2", element, {displayMode:false,throwOnError:false,macros:{"\\eqc":"\\,,","\\eqp":"\\,.","\\pd":"\\frac{\\partial #1}{\\partial #2}","\\pr":"\\left(#1\\right)","\\ddt":"\\frac{d #1}{d t}"}});
Range of validity
Input Parameters
Input Files
References